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1. 发明申请

US20100273944A1 THERMOPLASTIC RESIN COMPOSITION, PRODUCTION METHOD THEREOF, AND MOLDED ARTICLE 有权
标题翻译：热塑性树脂组合物，其制造方法和模制品
公开(公告)号：US20100273944A1
公开(公告)日：2010-10-28
申请号：US12293697
申请日：2007-03-22
申请人： Sadayuki Kobayashi , Daisuke Sato , Masaru Akita , Hiroshi Jinnai , Takashi Inoue
发明人： Sadayuki Kobayashi , Daisuke Sato , Masaru Akita , Hiroshi Jinnai , Takashi Inoue
IPC分类号： C08L81/04 , C08L77/00 , C08L25/06 , C08L69/00
CPC分类号： C08J3/203 , B29C47/0021 , B29C47/38 , B29C47/402 , C08L51/06 , C08L77/00 , C08L77/02 , C08L101/00 , C08L101/02 , C08L2666/24
摘要： A thermoplastic resin composition includes a thermoplastic resin (A) and a reactive functional group-containing resin (B), which has a specific structure in the morphology of the resin composition observed by transmission electron microscopy tomography, and the relaxation time T1C of each carbon nucleus by the solid NMR measurement of the thermoplastic resin composition containing a polyamide resin is kept in a specific range. The composition is excellent in the balance between contradictory properties such as impact resistance and heat resistance, remarkably exhibits a peculiar viscoelastic behavior not observed in the conventional polymeric materials, and is remarkably excellent in impact energy absorbing performance and vibration energy absorbing performance at the time of high-speed deformation.
摘要翻译：热塑性树脂组合物包括热塑性树脂（A）和含有反应性官能团的树脂（B），其具有通过透射电子显微镜断层摄影观察到的树脂组合物的形态的特定结构，并且各碳的弛豫时间T1C 通过含有聚酰胺树脂的热塑性树脂组合物的固体NMR测定将核保持在特定范围内。该组合物在抗冲击性和耐热性等相互矛盾的性质之间的平衡优异，显着地表现出在常规聚合物材料中未观察到的特有的粘弹性行为，并且在冲击能量吸收性能和振动能量吸收性能方面显着优异高速变形。

2. 发明授权

US07960473B2 Thermoplastic resin composition, production method thereof, and molded article 有权
标题翻译：热塑性树脂组合物，其制造方法和成型体
公开(公告)号：US07960473B2
公开(公告)日：2011-06-14
申请号：US12293697
申请日：2007-03-22
申请人： Sadayuki Kobayashi , Daisuke Sato , Masaru Akita , Hiroshi Jinnai , Takashi Inoue
发明人： Sadayuki Kobayashi , Daisuke Sato , Masaru Akita , Hiroshi Jinnai , Takashi Inoue
IPC分类号： C08L67/00 , C08L71/02 , C08L77/00 , C08L81/04
CPC分类号： C08J3/203 , B29C47/0021 , B29C47/38 , B29C47/402 , C08L51/06 , C08L77/00 , C08L77/02 , C08L101/00 , C08L101/02 , C08L2666/24
摘要： A thermoplastic resin composition includes a thermoplastic resin (A) and a reactive functional group-containing resin (B), which has a specific structure in the morphology of the resin composition observed by transmission electron microscopy tomography, and the relaxation time T1C of each carbon nucleus by the solid NMR measurement of the thermoplastic resin composition containing a polyamide resin is kept in a specific range. The composition is excellent in the balance between contradictory properties such as impact resistance and heat resistance, remarkably exhibits a peculiar viscoelastic behavior not observed in the conventional polymeric materials, and is remarkably excellent in impact energy absorbing performance and vibration energy absorbing performance at the time of high-speed deformation.
摘要翻译：热塑性树脂组合物包括热塑性树脂（A）和含有反应性官能团的树脂（B），其具有通过透射电子显微镜断层摄影观察到的树脂组合物的形态的特定结构，并且各碳的弛豫时间T1C 通过含有聚酰胺树脂的热塑性树脂组合物的固体NMR测定将核保持在特定范围内。该组合物在抗冲击性和耐热性等相互矛盾的性质之间的平衡优异，显着地表现出在常规聚合物材料中未观察到的特有的粘弹性行为，并且在冲击能量吸收性能和振动能量吸收性能方面显着优异高速变形。

3. 发明授权

US08188188B2 Process for producing thermoplastic resin composition 有权
标题翻译：热塑性树脂组合物的制造方法
公开(公告)号：US08188188B2
公开(公告)日：2012-05-29
申请号：US12934484
申请日：2009-03-25
申请人： Sadayuki Kobayashi , Hideo Matsuoka , Makiko Saito , Masaru Akita
发明人： Sadayuki Kobayashi , Hideo Matsuoka , Makiko Saito , Masaru Akita
IPC分类号： C08F8/00 , C08J3/00 , C08L23/00
CPC分类号： C08J3/20 , B29B7/42 , B29B7/7495 , B29C47/6056 , B29C47/6087 , B29C47/622 , B29C47/92 , B29C2947/92561 , B29C2947/92704 , B29C2947/92895 , C08J3/005 , C08J2300/00 , C08J2300/10 , C08J2377/00
摘要： A thermoplastic resin composition production method wherein melt-kneading is performed in a stretched flow when producing a thermoplastic resin composition as specified in the paragraph (I) or (II) below: (I) a thermoplastic resin composition comprising a Thermoplastic resin (A) and a Resin (B) with a reactive functional group; (II) a thermoplastic resin composition comprising a Thermoplastic resin (A), a Thermoplastic resin (C) that is different from the Thermoplastic resin (A), and a Compound (D) with a reactive functional group.
摘要翻译：（I）或（II）中规定的热塑性树脂组合物的制造时，在拉伸流动下进行熔融混炼的热塑性树脂组合物的制造方法：（I）含有热塑性树脂（A）的热塑性树脂组合物，和具有反应性官能团的树脂（B）; （II）包含热塑性树脂（A）的热塑性树脂组合物，与热塑性树脂（A）不同的热塑性树脂（C）和具有反应性官能团的化合物（D）。

4. 发明申请

US20110021707A1 PROCESS FOR PRODUCING THERMOPLASTIC RESIN COMPOSITION 有权
标题翻译：生产热塑性树脂组合物的方法
公开(公告)号：US20110021707A1
公开(公告)日：2011-01-27
申请号：US12934484
申请日：2009-03-25
申请人： Sadayuki Kobayashi , Hideo Matsuoka , Makiko Saito , Masaru Akita
发明人： Sadayuki Kobayashi , Hideo Matsuoka , Makiko Saito , Masaru Akita
IPC分类号： C08L23/08 , B29C47/38 , C08L77/12
CPC分类号： C08J3/20 , B29B7/42 , B29B7/7495 , B29C47/6056 , B29C47/6087 , B29C47/622 , B29C47/92 , B29C2947/92561 , B29C2947/92704 , B29C2947/92895 , C08J3/005 , C08J2300/00 , C08J2300/10 , C08J2377/00
摘要： A thermoplastic resin composition production method wherein melt-kneading is performed in a stretched flow when producing a thermoplastic resin composition as specified in the paragraph (I) or (II) below: (I) a thermoplastic resin composition comprising a Thermoplastic resin (A) and a Resin (B) with a reactive functional group; (II) a thermoplastic resin composition comprising a Thermoplastic resin (A), a Thermoplastic resin (C) that is different from the Thermoplastic resin (A), and a Compound (D) with a reactive functional group.
摘要翻译：（I）或（II）中规定的热塑性树脂组合物的制造时，在拉伸流动下进行熔融混炼的热塑性树脂组合物的制造方法：（I）含有热塑性树脂（A）的热塑性树脂组合物，和具有反应性官能团的树脂（B）; （II）包含热塑性树脂（A）的热塑性树脂组合物，与热塑性树脂（A）不同的热塑性树脂（C）和具有反应性官能团的化合物（D）。

5. 发明申请

US20140142219A1 THERMOPLASTIC RESIN COMPOSITION FOR IMPACT ABSORBING MEMBER AND METHOD FOR PRODUCING SAME 有权
标题翻译：用于冲击吸收构件的热塑性树脂组合物及其制造方法
公开(公告)号：US20140142219A1
公开(公告)日：2014-05-22
申请号：US14234868
申请日：2012-07-11
申请人： Masaru Akita , Shingo Nishida , Hideo Matsuoka , Shigemitsu Suzuki , Yasufumi Morita
发明人： Masaru Akita , Shingo Nishida , Hideo Matsuoka , Shigemitsu Suzuki , Yasufumi Morita
IPC分类号： C08L77/02 , C08L77/06 , C08L67/02 , C08J3/20 , C08L67/04 , C08L71/12 , C08L81/04 , C08L23/12 , B29C47/00 , C08L69/00
CPC分类号： C12N5/166 , B29C47/0004 , C08J3/20 , C08J5/042 , C08J5/043 , C08J2377/00 , C08J2400/202 , C08J2433/06 , C08K3/013 , C08K5/092 , C08K7/14 , C08L15/00 , C08L21/00 , C08L23/12 , C08L33/068 , C08L67/02 , C08L67/04 , C08L69/00 , C08L71/12 , C08L77/02 , C08L77/06 , C08L81/04 , C08L101/00 , C08L101/005 , C08L101/02 , C12N5/0691 , C12N5/16 , C12N2500/46 , C12N2501/06 , C12N2501/11 , C12N2501/115 , C12N2501/73 , C12N2501/998 , C12N2506/00 , C12N2506/30 , C08K3/0033
摘要： A thermoplastic resin composition includes 1 to 200 parts by weight of an inorganic filler (C) blended with 50 to 80 parts by weight of a thermoplastic resin (A) and 20 to 50 parts by weight of a rubbery polymer having a reactive functional group (B) which together account for 100 parts by weight; wherein the thermoplastic resin (A) and the rubbery polymer having a reactive functional group (B) form a continuous phase and a dispersed phase, respectively, while the inorganic filler (C) is dispersed in the continuous phase and/or the dispersed phase; and the dispersed phase of the rubbery polymer contains fine particles with a diameter of 1 to 100 nm of a compound resulting from a reaction between the thermoplastic resin (A) and the rubbery polymer; and an area occupied by the fine particles account for 10% or more of the dispersed phase.
摘要翻译：热塑性树脂组合物包含1〜200重量份与50〜80重量份热塑性树脂（A）共混的无机填料（C）和20〜50重量份具有反应性官能团的橡胶状聚合物（ B）共计100重量份; 其中所述热塑性树脂（A）和具有反应性官能团（B）的橡胶状聚合物分别形成连续相和分散相，而无机填料（C）分散在连续相和/或分散相中; 并且橡胶状聚合物的分散相含有由热塑性树脂（A）和橡胶状聚合物之间的反应得到的化合物的直径为1〜100nm的细微粒子; 并且微粒占据的面积占分散相的10％以上。

6. 发明申请

US20120028047A1 Fiber reinforced resin composition, molding material, and method for producing fiber reinforced resin composition 有权
标题翻译：纤维增强树脂组合物，成型材料以及纤维增强树脂组合物的制造方法
公开(公告)号：US20120028047A1
公开(公告)日：2012-02-02
申请号：US13138658
申请日：2010-03-16
申请人： Naokichi Imai , Masato Honma , Takayuki Fujiwara , Takashi Fujioka , Masaru Akita , Makiko Saito
发明人： Naokichi Imai , Masato Honma , Takayuki Fujiwara , Takashi Fujioka , Masaru Akita , Makiko Saito
IPC分类号： B32B5/16 , C08L23/12 , C08L63/00 , C08L67/04 , C08L71/12 , B29C45/14 , C08L77/06 , C08L81/04 , C08L33/10 , C08K7/06 , C08K13/04 , C08L51/06 , C08L67/02
CPC分类号： C08J5/24 , B29C47/6037 , B29C47/6056 , B29C47/6087 , C08J5/04 , C08J5/042 , C08J2300/22 , C08J2300/24 , C08J2363/00 , C08J2400/22 , C08J2423/28 , C08L23/10 , C08L101/02 , Y10T428/2991
摘要： The invention provides a fiber reinforced resin composition comprising a melt-kneaded product (A) prepared by melt-kneading a first resin (A1) and a second resin (A2) that has reactive functional group as well as a third resin (B) and a fibrous filler (C), wherein, with respect to the contents of the components, the first resin (A1), the second resin with a reactive functional group (A2), and the third resin (B) account for 0.1 to 75 wt %, 0.1 to 15 wt %, and 10 to 99.8 wt %, respectively, to form a resin composition while said fibrous filler (C) accounts for 0.1 to 300 parts by weight per 100 parts by weight of said resin composition, said first resin (A1) and said third resin (B) forming a matrix resin, said second resin (A2) being dispersed as particles in said matrix resin, and said particles having a number average particle diameter of 10 to 1,000 nm. The invention relates to a fiber reinforced resin composition having rigidity and impact resistance in a good balance, a molding material, and a production method thereof.
摘要翻译：本发明提供一种纤维增强树脂组合物，其包含通过熔融捏合第一树脂（A1）和具有反应性官能团的第二树脂（A2）以及第三树脂（B）制备的熔融捏合产物（A）和纤维状填料（C），其中，相对于成分的含量，第一树脂（A1），具有反应性官能团（A2）的第二树脂和第三树脂（B）占0.1〜75重量％％，0.1〜15重量％，10〜99.8重量％，形成树脂组合物，同时所述纤维填料（C）相对于所述树脂组合物为100重量份为0.1〜300重量份，所述第一树脂（A1）和所述第三树脂（B）形成基质树脂，所述第二树脂（A2）作为颗粒分散在所述基质树脂中，所述颗粒的数均粒径为10〜1000nm。本发明涉及具有良好平衡的刚性和耐冲击性的纤维增强树脂组合物，成型材料及其制造方法。

7. 发明申请

US20110105683A1 POLYAMIDE RESIN, COMPOSITION CONTAINING THE POLYAMIDE RESIN, AND MOLDED ARTICLES OF THE POLYAMIDE RESIN AND THE COMPOSITION 审中-公开
标题翻译：聚酰胺树脂，含有聚酰胺树脂的组合物和聚酰胺树脂和组合物的成型品
公开(公告)号：US20110105683A1
公开(公告)日：2011-05-05
申请号：US13001791
申请日：2009-06-29
申请人： Koya Kato , Masaru Akita , Hideo Matsuoka
发明人： Koya Kato , Masaru Akita , Hideo Matsuoka
IPC分类号： C08G69/26 , C08L77/06
CPC分类号： C08G69/265 , C08G69/36 , C08K7/28 , C08L77/06
摘要： Disclosed is a polyamide resin which is produced by the polycondensation of (A) pentamethylenediamin, (B) terephthalic acid and/or a derivative thereof, and (C) at least one member selected from adipic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, isophthalic acid, 1,9-diaminononane, 1,10-diaminodecane, 1,12-diaminododecane, caprolactam, undecalactam, laurolactam, aminocaproic acid, 11-aminoundecanoic acid, 12-aminododecanoic acid, and derivatives of these compounds. In the polyamide resin, the ratio of a repeating unit derived from the component (C) is 10 to 50 wt % (inclusive) relative to the total weight of the polymer. A solution of the polyamide resin in 98% sulfuric acid, which contains the polyamide resin at a concentration of 0.01 g/ml, has a relative viscosity of 1.5 to 4.5 at 25° C.
摘要翻译：公开了通过（A）五亚甲基二胺，（B）对苯二甲酸和/或其衍生物的缩聚制备的聚酰胺树脂，（C）选自己二酸，癸二酸，十一烷二酸，十二烷二酸间苯二甲酸，1,9-二氨基壬烷，1,10-二氨基十二烷，1,12-二氨基十二烷，己内酰胺，十一内酰胺，月桂内酰胺，氨基己酸，11-氨基十一烷酸，12-氨基十二烷酸和这些化合物的衍生物。在聚酰胺树脂中，衍生自（C）成分的重复单元的比例相对于聚合物的总重量为10〜50重量％（以下）。聚酰胺树脂在含有浓度为0.01g / ml的聚酰胺树脂的98％硫酸中的溶液在25℃下的相对粘度为1.5〜4.5。

8. 发明授权

US09334482B2 Thermoplastic resin composition for impact absorbing member and method for producing same 有权
标题翻译：用于冲击吸收件的热塑性树脂组合物及其制造方法
公开(公告)号：US09334482B2
公开(公告)日：2016-05-10
申请号：US14234868
申请日：2012-07-11
申请人： Masaru Akita , Shingo Nishida , Hideo Matsuoka , Shigemitsu Suzuki , Yasufumi Morita
发明人： Masaru Akita , Shingo Nishida , Hideo Matsuoka , Shigemitsu Suzuki , Yasufumi Morita
IPC分类号： B29C47/00 , C08J3/20 , C08K5/09 , C08K7/04 , C08K7/14 , C08L23/12 , C08L67/02 , C08L67/04 , C08L69/00 , C08L71/12 , C08L77/02 , C08L77/06 , C08L81/04 , C08L101/00 , C08L15/00 , C08L21/00 , C12N5/26 , C12N5/16 , C12N5/071
CPC分类号： C12N5/166 , B29C47/0004 , C08J3/20 , C08J5/042 , C08J5/043 , C08J2377/00 , C08J2400/202 , C08J2433/06 , C08K3/013 , C08K5/092 , C08K7/14 , C08L15/00 , C08L21/00 , C08L23/12 , C08L33/068 , C08L67/02 , C08L67/04 , C08L69/00 , C08L71/12 , C08L77/02 , C08L77/06 , C08L81/04 , C08L101/00 , C08L101/005 , C08L101/02 , C12N5/0691 , C12N5/16 , C12N2500/46 , C12N2501/06 , C12N2501/11 , C12N2501/115 , C12N2501/73 , C12N2501/998 , C12N2506/00 , C12N2506/30 , C08K3/0033
摘要： A thermoplastic resin composition includes 1 to 200 parts by weight of an inorganic filler (C) blended with 50 to 80 parts by weight of a thermoplastic resin (A) and 20 to 50 parts by weight of a rubbery polymer having a reactive functional group (B) which together account for 100 parts by weight; wherein the thermoplastic resin (A) and the rubbery polymer having a reactive functional group (B) form a continuous phase and a dispersed phase, respectively, while the inorganic filler (C) is dispersed in the continuous phase and/or the dispersed phase; and the dispersed phase of the rubbery polymer contains fine particles with a diameter of 1 to 100 nm of a compound resulting from a reaction between the thermoplastic resin (A) and the rubbery polymer; and an area occupied by the fine particles account for 10% or more of the dispersed phase.
摘要翻译：热塑性树脂组合物包含1〜200重量份与50〜80重量份热塑性树脂（A）共混的无机填料（C）和20〜50重量份具有反应性官能团的橡胶状聚合物（ B）共计100重量份; 其中所述热塑性树脂（A）和具有反应性官能团（B）的橡胶状聚合物分别形成连续相和分散相，而无机填料（C）分散在连续相和/或分散相中; 并且橡胶状聚合物的分散相含有由热塑性树脂（A）和橡胶状聚合物之间的反应得到的化合物的直径为1〜100nm的细微粒子; 并且微粒占据的面积占分散相的10％以上。

9. 发明授权

US08685537B2 Fiber reinforced resin composition, molding material, and method for producing fiber reinforced resin composition 有权
标题翻译：纤维增强树脂组合物，成型材料以及纤维增强树脂组合物的制造方法
公开(公告)号：US08685537B2
公开(公告)日：2014-04-01
申请号：US13138658
申请日：2010-03-16
申请人： Naokichi Imai , Masato Honma , Takayuki Fujiwara , Takashi Fujioka , Masaru Akita , Makiko Saito
发明人： Naokichi Imai , Masato Honma , Takayuki Fujiwara , Takashi Fujioka , Masaru Akita , Makiko Saito
IPC分类号： B29C45/14 , C08L77/06 , C08K7/06
CPC分类号： C08J5/24 , B29C47/6037 , B29C47/6056 , B29C47/6087 , C08J5/04 , C08J5/042 , C08J2300/22 , C08J2300/24 , C08J2363/00 , C08J2400/22 , C08J2423/28 , C08L23/10 , C08L101/02 , Y10T428/2991
摘要： The invention provides a fiber reinforced resin composition comprising a melt-kneaded product (A) prepared by melt-kneading a first resin (A1) and a second resin (A2) that has a reactive functional group as well as a third resin (B) and a fibrous filler (C), wherein, with respect to the contents of the components, the first resin (A1), the second resin with a reactive functional group (A2), and the third resin (B) account for 0.1 to 75 wt %, 0.1 to 15 wt %, and 10 to 99.8 wt %, respectively, to form a resin composition while said fibrous filler (C) accounts for 0.1 to 300 parts by weight per 100 parts by weight of said resin composition, said first resin (A1) and said third resin (B) forming a matrix resin, said second resin (A2) being dispersed as particles in said matrix resin, and said particles having a number average particle diameter of 10 to 1,000 nm. The invention relates to a fiber reinforced resin composition having rigidity and impact resistance in a good balance, a molding material, and a production method thereof.
摘要翻译：本发明提供一种纤维增强树脂组合物，其包含通过熔融捏合第一树脂（A1）和具有反应性官能团的第二树脂（A2）以及第三树脂（B）制备的熔融捏合产物（A）和纤维状填料（C），其中，相对于成分的含量，第一树脂（A1），具有反应性官能团（A2）的第二树脂和第三树脂（B）占0.1〜75 重量％，0.1〜15重量％，10〜99.8重量％，形成树脂组合物，同时所述纤维填料（C）相对于100重量份所述树脂组合物为0.1〜300重量份，树脂（A1）和形成基质树脂的所述第三树脂（B），所述第二树脂（A2）作为颗粒分散在所述基体树脂中，所述颗粒的数均粒径为10〜1000nm。本发明涉及具有良好平衡的刚性和耐冲击性的纤维增强树脂组合物，成型材料及其制造方法。

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