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1. 发明申请

US20150005464A1 Metalloporphyrin Polymer Functionalized Substrate 有权
标题翻译：金属卟啉聚合物官能化基材
公开(公告)号：US20150005464A1
公开(公告)日：2015-01-01
申请号：US13952535
申请日：2013-07-26
申请人： Sharp Laboratories of America, Inc.
发明人： Sean Andrew Vail , David R. Evans , Jong-Jan Lee
IPC分类号： C08G79/00
CPC分类号： C08G79/00 , C08G73/0273 , C08G73/0611 , C08G2261/314 , C08G2261/91 , H01L51/0077 , Y02E10/549
摘要： A method is provided for fabricating a metalloporphyrin polymer on a substrate. The method creates a functionalized substrate by attaching an anchor group of a linker, including a terminal alkyne group, to a substrate surface. The functionalized substrate is then exposed to metalloporphyrin monomers, where each metalloporphyrin monomer includes at least two terminal alkyne groups. A plurality of metalloporphyrin monomers (e.g., zinc porphyrin monomers) are thus linked via the metalloporphyrin monomer terminal alkyne groups, forming a metalloporphyrin polymer attached to the substrate. In one aspect, linking the plurality of metalloporphyrin monomers via the metalloporphyrin monomer terminal alkyne groups includes forming butadiyne groups between adjacent metalloporphyrins. Then, forming the metalloporphyrin polymer attached to the substrate includes attaching the metalloporphyrin polymer, via a metalloporphyrin monomer terminal alkyne group, to the terminal alkyne group of an associated linker. Alternatively stated, the metalloporphyrin polymer is attached to the substrate via a polyalkyne group.
摘要翻译：提供了一种在基底上制造金属卟啉聚合物的方法。该方法通过将包含末端炔基的连接体的锚定基团连接到基底表面来产生功能化底物。然后将官能化底物暴露于金属卟啉单体，其中每个金属卟啉单体包括至少两个末端炔基。金属卟啉单体（例如锌卟啉单体）由此通过金属卟啉单体末端炔基连接，形成附着在基材上的金属卟啉聚合物。一方面，通过金属卟啉单体末端炔基连接多个金属卟啉单体包括在相邻的金属卟啉之间形成泛二炔基。然后，形成附着在基材上的金属卟啉聚合物包括通过金属卟啉单体末端炔基将金属卟啉聚合物连接到相关连接体的末端炔基上。或者说，金属卟啉聚合物通过聚炔基连接到基底上。

2. 发明申请

US20160268622A1 Alkali/Oxidant Battery 审中-公开
标题翻译：碱/氧化物电池
公开(公告)号：US20160268622A1
公开(公告)日：2016-09-15
申请号：US15146071
申请日：2016-05-04
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David R. Evans
IPC分类号： H01M8/18 , H01M4/38 , H01M4/24 , H01M10/0568 , H01M4/50 , H01M10/26 , H01M10/30 , H01M10/0525 , H01M4/32 , H01M4/52
CPC分类号： H01M8/188 , H01M2/14 , H01M4/24 , H01M4/248 , H01M4/32 , H01M4/382 , H01M4/50 , H01M4/52 , H01M4/521 , H01M4/523 , H01M8/184 , H01M8/20 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/26 , H01M10/30 , H01M10/44 , H01M12/08 , H01M2004/027 , H01M2004/028 , H01M2300/0014 , H01M2300/0025 , Y02E60/128 , Y10T29/49108
摘要： An alkali/oxidant battery is provided with an associated method of creating battery capacity. The battery is made from an anode including a reduced first alkali metal such as lithium (Li), sodium (Na), and potassium (K), when the battery is charged. The battery's catholyte includes an element, in the battery charged state, such as nickel oxyhydroxide (NiOOH), manganese(IV) (oxide Mn( 4+)O2), or iron(III) oxyhydroxide Fe(3+)(OH)3), with the alkali metal hydroxide. An alkali metal ion permeable separator is interposed between the anolyte and the catholyte. For example, if the catholyte includes nickel(II) hydroxide (Ni(OH)2) in a battery discharged state, then it includes NiOOH in a battery charged state. To continue the example, the anolyte may include dissolved lithium ions (Li+) in a discharged state, with solid phase reduced Li formed on the anode in the battery charged state.
摘要翻译：碱/氧化剂电池具有产生电池容量的相关方法。当电池充电时，电池由包括还原的第一碱金属如锂（Li），钠（Na）和钾（K）的阳极制成。电池的阴极电解液包括电池充电状态的元素，例如氢氧化正镍（NiOOH），锰（IV）（氧化物Mn（4+）O 2）或氢氧化铁（III）（3 +）（OH）3 ），与碱金属氢氧化物反应。在阳极电解液和阴极电解液之间插入碱金属离子可渗透分离器。例如，如果阴极电解液包含处于电池放电状态的镍（II）氢氧化物（Ni（OH）2），则其包括处于电池充电状态的NiOOH。为了继续该实施例，阳极电解液可以包括处于放电状态的溶解的锂离子（Li +），在电池充电状态下在阳极上形成固相Li。

3. 发明授权

US10411286B2 Alkali/oxidant battery 有权
公开(公告)号：US10411286B2
公开(公告)日：2019-09-10
申请号：US15146071
申请日：2016-05-04
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David R. Evans
IPC分类号： H01M8/18 , H01M4/52 , H01M10/44 , H01M8/20 , H01M10/05 , H01M12/08 , H01M4/24 , H01M4/32 , H01M4/38 , H01M4/50 , H01M10/26 , H01M10/30 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M2/14 , H01M4/02
摘要： An alkali/oxidant battery is provided with an associated method of creating battery capacity. The battery is made from an anode including a reduced first alkali metal such as lithium (Li), sodium (Na), and potassium (K), when the battery is charged. The battery's catholyte includes an element, in the battery charged state, such as nickel oxyhydroxide (NiOOH), manganese(IV) (oxide Mn(4+)O2), or iron(III) oxyhydroxide Fe(3+)(OH)3), with the alkali metal hydroxide. An alkali metal ion permeable separator is interposed between the anolyte and the catholyte. For example, if the catholyte includes nickel(II) hydroxide (Ni(OH)2) in a battery discharged state, then it includes NiOOH in a battery charged state. To continue the example, the anolyte may include dissolved lithium ions (Li+) in a discharged state, with solid phase reduced Li formed on the anode in the battery charged state.

4. 发明授权

US09090743B2 Metalloporphyrin polymer functionalized substrate 有权
标题翻译：金属卟啉聚合物官能化底物
公开(公告)号：US09090743B2
公开(公告)日：2015-07-28
申请号：US13952535
申请日：2013-07-26
申请人： Sharp Laboratories of America, Inc.
发明人： Sean Andrew Vail , David R. Evans , Jong-Jan Lee
IPC分类号： C08G18/00 , C08G79/00 , H01L51/00
CPC分类号： C08G79/00 , C08G73/0273 , C08G73/0611 , C08G2261/314 , C08G2261/91 , H01L51/0077 , Y02E10/549
摘要： A method is provided for fabricating a metalloporphyrin polymer on a substrate. The method creates a functionalized substrate by attaching an anchor group of a linker, including a terminal alkyne group, to a substrate surface. The functionalized substrate is then exposed to metalloporphyrin monomers, where each metalloporphyrin monomer includes at least two terminal alkyne groups. A plurality of metalloporphyrin monomers (e.g., zinc porphyrin monomers) are thus linked via the metalloporphyrin monomer terminal alkyne groups, forming a metalloporphyrin polymer attached to the substrate. In one aspect, linking the plurality of metalloporphyrin monomers via the metalloporphyrin monomer terminal alkyne groups includes forming butadiyne groups between adjacent metalloporphyrins. Then, forming the metalloporphyrin polymer attached to the substrate includes attaching the metalloporphyrin polymer, via a metalloporphyrin monomer terminal alkyne group, to the terminal alkyne group of an associated linker. Alternatively stated, the metalloporphyrin polymer is attached to the substrate via a polyalkyne group.
摘要翻译：提供了一种在基底上制造金属卟啉聚合物的方法。该方法通过将包含末端炔基的连接体的锚定基团连接到基底表面来产生功能化底物。然后将官能化底物暴露于金属卟啉单体，其中每个金属卟啉单体包括至少两个末端炔基。金属卟啉单体（例如锌卟啉单体）由此通过金属卟啉单体末端炔基连接，形成附着在基材上的金属卟啉聚合物。一方面，通过金属卟啉单体末端炔基连接多个金属卟啉单体包括在相邻的金属卟啉之间形成泛二炔基。然后，形成附着在基材上的金属卟啉聚合物包括通过金属卟啉单体末端炔基将金属卟啉聚合物连接到相关连接体的末端炔基上。或者说，金属卟啉聚合物通过聚炔基连接到基底上。

5. 发明申请

US20140075745A1 High Capacity Alkali/Oxidant Battery 审中-公开
标题翻译：大容量碱/氧化物电池
公开(公告)号：US20140075745A1
公开(公告)日：2014-03-20
申请号：US14092048
申请日：2013-11-27
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David R. Evans
IPC分类号： H01M4/52 , H01M10/44
CPC分类号： H01M8/188 , H01M2/14 , H01M4/24 , H01M4/248 , H01M4/32 , H01M4/382 , H01M4/50 , H01M4/52 , H01M4/521 , H01M4/523 , H01M8/184 , H01M8/20 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/26 , H01M10/30 , H01M10/44 , H01M12/08 , H01M2004/027 , H01M2004/028 , H01M2300/0014 , H01M2300/0025 , Y02E60/128 , Y10T29/49108
摘要： An alkali/oxidant battery is provided with an associated method of creating battery capacity. The battery is made from an anode including a reduced first alkali metal such as lithium (Li), sodium (Na), and potassium (K), when the battery is charged. The battery's catholyte includes an element, in the battery charged state, such as nickel oxyhydroxide (NiOOH), magnesium(IV) (oxide Mn(4+)O2), or iron(III) oxyhydroxide (Fe(3+)(OH)3), with the alkali metal hydroxide. An alkali metal ion permeable separator is interposed between the anolyte and the catholyte. For example, if the catholyte includes nickel(II) hydroxide (Ni(OH)2) in a battery discharged state, then it includes NiOOH in a battery charged state. To continue the example, the anolyte may include dissolved lithium ions (Li+) in a discharged state, with solid phase reduced Li formed on the anode in the battery charged state.
摘要翻译：碱/氧化剂电池具有产生电池容量的相关方法。当电池充电时，电池由包括还原的第一碱金属如锂（Li），钠（Na）和钾（K）的阳极制成。电池的阴极电解液包括电池充电状态的元素，例如氢氧化正镍（NiOOH），镁（IV）（氧化物Mn（4+）O 2）或氢氧化铁（III）（Fe（3 +）（OH） 3），用碱金属氢氧化物。在阳极电解液和阴极电解液之间插入碱金属离子可渗透分离器。例如，如果阴极电解液包含处于电池放电状态的镍（II）氢氧化物（Ni（OH）2），则其包括处于电池充电状态的NiOOH。为了继续该实施例，阳极电解液可以包括处于放电状态的溶解的锂离子（Li +），在电池充电状态下在阳极上形成固相Li。

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