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1. 发明申请

US20140038000A1 Flow-Through Metal Battery with Ion Exchange Membrane 审中-公开
标题翻译：带离子交换膜的流通金属电池
公开(公告)号：US20140038000A1
公开(公告)日：2014-02-06
申请号：US14042264
申请日：2013-09-30
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Jong-Jan Lee , Hidayat Kisdarjono
IPC分类号： H01M4/36
CPC分类号： H01M4/364 , H01M8/188 , H01M8/20 , Y02E60/528
摘要： A metal flow-through battery is provided, with ion exchange membrane. The flow-through battery is primarily made up of an anode slurry, a cathode slurry, and a hydroxide (OH−) anion exchange membrane interposed between the anode slurry and the cathode slurry, The anode and cathode slurries are both aqueous slurries. The anode slurry includes a metal, and associated oxides, such as magnesium (Mg), aluminum (Al), iron (Fe), copper (Cu), or zinc (Zn). The cathode slurry includes a chemical agent such as nickel oxyhydroxide (NiOOH), nickel (II) hydroxide (Ni(OH)2), manganese oxide (MnO2), manganese (II) oxide (Mn2O3), iron (III) oxide (Fe2O3), iron (III) oxide (FeO), iron (III) hydroxide (Fe(OH)), or combinations of the above-referenced materials. A method is also provided for forming a voltage potential across a flow-through battery.
摘要翻译：提供了具有离子交换膜的金属流通电池。流通电池主要由置于阳极浆料和阴极浆料之间的阳极浆料，阴极浆料和氢氧化物（OH-）阴离子交换膜组成。阳极和阴极浆料均为水性浆料。阳极浆料包括金属和相关的氧化物，例如镁（Mg），铝（Al），铁（Fe），铜（Cu）或锌（Zn）。阴极浆料包括氢氧化镍（NiOOH），氢氧化镍（II）（Ni（OH）2），氧化锰（MnO 2），氧化锰（II），氧化铁（III）（Fe 2 O 3）），氧化铁（III）（FeO），氢氧化铁（III）（Fe（OH））或上述材料的组合。还提供了一种形成跨过电池的电压电势的方法。

2. 发明申请

US20160285098A1 Transition Metal Hexacyanoferrate Battery with Carbonaceous Anode 有权
标题翻译：碳酸阳极过渡金属六氰基铁酸盐电池
公开(公告)号：US20160285098A1
公开(公告)日：2016-09-29
申请号：US15173866
申请日：2016-06-06
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David Evans
IPC分类号： H01M4/58 , H01M4/62 , H01M10/054 , H01M10/0568
CPC分类号： H01M4/5825 , H01M4/136 , H01M4/58 , H01M4/625 , H01M10/054 , H01M10/0568 , H01M10/446 , H01M2004/028 , H02J7/0063 , H02J7/0068 , Y02E60/122
摘要： A transition metal hexacyanoferrate (TMH) cathode battery is provided. The battery has a AxMn[Fe(CN)6]y.zH2O cathode, where the A cations are either alkali or alkaline-earth cations, such as sodium or potassium, where x is in the range of 1 to 2, where y is in the range of 0.5 to 1, and where z is in the range of 0 to 3.5. The AxMn[Fe(CN)6]y.zH2O has a rhombohedral crystal structure with Mn2+/3+ and Fe2+/3+ having the same reduction/oxidation potential. The battery also has an electrolyte, and anode made of an A metal, an A composite, or a material that can host A atoms. The battery has a single plateau charging curve, where a single plateau charging curve is defined as a constant charging voltage slope between 15% and 85% battery charge capacity. Fabrication methods are also provided.
摘要翻译：提供了一种过渡金属六氰基铁酸盐（TMH）阴极电池。电池具有AxMn [Fe（CN）6] y.zH 2 O阴极，其中A阳离子是碱金属或碱土金属阳离子，如钠或钾，其中x在1至2的范围内，其中y是在0.5至1的范围内，其中z在0至3.5的范围内。 AxMn [Fe（CN）6] y.zH2O具有具有相同还原/氧化电位的Mn2 + / 3 +和Fe2 + / 3 +的菱方晶体结构。电池还具有电解质和由A金属，A复合材料或能够承载A原子的材料制成的阳极。电池具有单个平台充电曲线，其中单个平台充电曲线被定义为电池充电容量的15％至85％之间的恒定充电电压斜率。还提供制造方法。

3. 发明授权

US09385370B2 Transition metal hexacyanoferrate battery with single plateau charge/discharge curve 有权
标题翻译：过渡金属六氰基铁铵电池具有单一平台充放电曲线
公开(公告)号：US09385370B2
公开(公告)日：2016-07-05
申请号：US14744476
申请日：2015-06-19
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David Evans
IPC分类号： H01M4/58 , H01M4/136 , H02J7/00 , H01M10/054 , H01M10/0568 , H01M10/44 , H01M4/02
CPC分类号： H01M4/5825 , H01M4/136 , H01M4/58 , H01M4/625 , H01M10/054 , H01M10/0568 , H01M10/446 , H01M2004/028 , H02J7/0063 , H02J7/0068 , Y02E60/122
摘要： A transition metal hexacyanoferrate (TMH) cathode battery is provided. The battery has a AxMn[Fe(CN)6]y.zH2O cathode, where the A cations are either alkali or alkaline-earth cations, such as sodium or potassium, where x is in the range of 1 to 2, where y is in the range of 0.5 to 1, and where z is in the range of 0 to 3.5. The AxMn[Fe(CN)6]y.zH2O has a rhombohedral crystal structure with Mn2+/3+ and Fe2+/3+ having the same reduction/oxidation potential. The battery also has an electrolyte, and anode made of an A metal, an A composite, or a material that can host A atoms. The battery has a single plateau charging curve, where a single plateau charging curve is defined as a constant charging voltage slope between 15% and 85% battery charge capacity. Fabrication methods are also provided.
摘要翻译：提供了一种过渡金属六氰基铁酸盐（TMH）阴极电池。电池具有AxMn [Fe（CN）6] y.zH 2 O阴极，其中A阳离子是碱金属或碱土金属阳离子，如钠或钾，其中x在1至2的范围内，其中y为在0.5至1的范围内，其中z在0至3.5的范围内。 AxMn [Fe（CN）6] y.zH2O具有具有相同还原/氧化电位的Mn2 + / 3 +和Fe2 + / 3 +的菱方晶体结构。电池还具有电解质和由A金属，A复合材料或能够承载A原子的材料制成的阳极。电池具有单个平台充电曲线，其中单个平台充电曲线被定义为电池充电容量的15％至85％之间的恒定充电电压斜率。还提供制造方法。

4. 发明申请

US20160268622A1 Alkali/Oxidant Battery 审中-公开
标题翻译：碱/氧化物电池
公开(公告)号：US20160268622A1
公开(公告)日：2016-09-15
申请号：US15146071
申请日：2016-05-04
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David R. Evans
IPC分类号： H01M8/18 , H01M4/38 , H01M4/24 , H01M10/0568 , H01M4/50 , H01M10/26 , H01M10/30 , H01M10/0525 , H01M4/32 , H01M4/52
CPC分类号： H01M8/188 , H01M2/14 , H01M4/24 , H01M4/248 , H01M4/32 , H01M4/382 , H01M4/50 , H01M4/52 , H01M4/521 , H01M4/523 , H01M8/184 , H01M8/20 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/26 , H01M10/30 , H01M10/44 , H01M12/08 , H01M2004/027 , H01M2004/028 , H01M2300/0014 , H01M2300/0025 , Y02E60/128 , Y10T29/49108
摘要： An alkali/oxidant battery is provided with an associated method of creating battery capacity. The battery is made from an anode including a reduced first alkali metal such as lithium (Li), sodium (Na), and potassium (K), when the battery is charged. The battery's catholyte includes an element, in the battery charged state, such as nickel oxyhydroxide (NiOOH), manganese(IV) (oxide Mn( 4+)O2), or iron(III) oxyhydroxide Fe(3+)(OH)3), with the alkali metal hydroxide. An alkali metal ion permeable separator is interposed between the anolyte and the catholyte. For example, if the catholyte includes nickel(II) hydroxide (Ni(OH)2) in a battery discharged state, then it includes NiOOH in a battery charged state. To continue the example, the anolyte may include dissolved lithium ions (Li+) in a discharged state, with solid phase reduced Li formed on the anode in the battery charged state.
摘要翻译：碱/氧化剂电池具有产生电池容量的相关方法。当电池充电时，电池由包括还原的第一碱金属如锂（Li），钠（Na）和钾（K）的阳极制成。电池的阴极电解液包括电池充电状态的元素，例如氢氧化正镍（NiOOH），锰（IV）（氧化物Mn（4+）O 2）或氢氧化铁（III）（3 +）（OH）3 ），与碱金属氢氧化物反应。在阳极电解液和阴极电解液之间插入碱金属离子可渗透分离器。例如，如果阴极电解液包含处于电池放电状态的镍（II）氢氧化物（Ni（OH）2），则其包括处于电池充电状态的NiOOH。为了继续该实施例，阳极电解液可以包括处于放电状态的溶解的锂离子（Li +），在电池充电状态下在阳极上形成固相Li。

5. 发明申请

US20150287991A1 Transition Metal Hexacyanoferrate Battery with Single Plateau Charge/Discharge Curve 有权
标题翻译：过渡金属六氰酸铁电池，具有单高原充放电曲线
公开(公告)号：US20150287991A1
公开(公告)日：2015-10-08
申请号：US14744476
申请日：2015-06-19
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David Evans
IPC分类号： H01M4/58 , H01M10/054
CPC分类号： H01M4/5825 , H01M4/136 , H01M4/58 , H01M4/625 , H01M10/054 , H01M10/0568 , H01M10/446 , H01M2004/028 , H02J7/0063 , H02J7/0068 , Y02E60/122
摘要： A transition metal hexacyanoferrate (TMH) cathode battery is provided. The battery has a AxMn[Fe(CN)6]y.zH2O cathode, where the A cations are either alkali or alkaline-earth cations, such as sodium or potassium, where x is in the range of 1 to 2, where y is in the range of 0.5 to 1, and where z is in the range of 0 to 3.5. The AxMn[Fe(CN)6]y.zH2O has a rhombohedral crystal structure with Mn2+/3+ and Fe2+/3+ having the same reduction/oxidation potential. The battery also has an electrolyte, and anode made of an A metal, an A composite, or a material that can host A atoms. The battery has a single plateau charging curve, where a single plateau charging curve is defined as a constant charging voltage slope between 15% and 85% battery charge capacity. Fabrication methods are also provided.
摘要翻译：提供了一种过渡金属六氰基铁酸盐（TMH）阴极电池。电池具有AxMn [Fe（CN）6] y.zH 2 O阴极，其中A阳离子是碱金属或碱土金属阳离子，如钠或钾，其中x在1至2的范围内，其中y为在0.5至1的范围内，其中z在0至3.5的范围内。 AxMn [Fe（CN）6] y.zH2O具有具有相同还原/氧化电位的Mn2 + / 3 +和Fe2 + / 3 +的菱方晶体结构。电池还具有电解质和由A金属，A复合材料或能够承载A原子的材料制成的阳极。电池具有单个平台充电曲线，其中单个平台充电曲线被定义为电池充电容量的15％至85％之间的恒定充电电压斜率。还提供制造方法。

6. 发明授权

US10411286B2 Alkali/oxidant battery 有权
公开(公告)号：US10411286B2
公开(公告)日：2019-09-10
申请号：US15146071
申请日：2016-05-04
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David R. Evans
IPC分类号： H01M8/18 , H01M4/52 , H01M10/44 , H01M8/20 , H01M10/05 , H01M12/08 , H01M4/24 , H01M4/32 , H01M4/38 , H01M4/50 , H01M10/26 , H01M10/30 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M2/14 , H01M4/02
摘要： An alkali/oxidant battery is provided with an associated method of creating battery capacity. The battery is made from an anode including a reduced first alkali metal such as lithium (Li), sodium (Na), and potassium (K), when the battery is charged. The battery's catholyte includes an element, in the battery charged state, such as nickel oxyhydroxide (NiOOH), manganese(IV) (oxide Mn(4+)O2), or iron(III) oxyhydroxide Fe(3+)(OH)3), with the alkali metal hydroxide. An alkali metal ion permeable separator is interposed between the anolyte and the catholyte. For example, if the catholyte includes nickel(II) hydroxide (Ni(OH)2) in a battery discharged state, then it includes NiOOH in a battery charged state. To continue the example, the anolyte may include dissolved lithium ions (Li+) in a discharged state, with solid phase reduced Li formed on the anode in the battery charged state.

7. 发明授权

US09680152B2 Transition metal hexacyanoferrate battery with carbonaceous anode 有权
公开(公告)号：US09680152B2
公开(公告)日：2017-06-13
申请号：US15173866
申请日：2016-06-06
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David Evans
IPC分类号： H01M4/58 , H01M4/136 , H02J7/00 , H01M10/054 , H01M10/0568 , H01M10/44 , H01M4/62 , H01M4/02
CPC分类号： H01M4/5825 , H01M4/136 , H01M4/58 , H01M4/625 , H01M10/054 , H01M10/0568 , H01M10/446 , H01M2004/028 , H02J7/0063 , H02J7/0068 , Y02E60/122
摘要： A transition metal hexacyanoferrate (TMH) cathode battery is provided. The battery has a AxMn[Fe(CN)6]y.zH2O cathode, where the A cations are either alkali or alkaline-earth cations, such as sodium or potassium, where x is in the range of 1 to 2, where y is in the range of 0.5 to 1, and where z is in the range of 0 to 3.5. The AxMn[Fe(CN)6]y.zH2O has a rhombohedral crystal structure with Mn2+/3+ and Fe2+/3+ having the same reduction/oxidation potential. The battery also has an electrolyte, and anode made of an A metal, an A composite, or a material that can host A atoms. The battery has a single plateau charging curve, where a single plateau charging curve is defined as a constant charging voltage slope between 15% and 85% battery charge capacity. Fabrication methods are also provided.

8. 发明申请

US20140075745A1 High Capacity Alkali/Oxidant Battery 审中-公开
标题翻译：大容量碱/氧化物电池
公开(公告)号：US20140075745A1
公开(公告)日：2014-03-20
申请号：US14092048
申请日：2013-11-27
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Hidayat Kisdarjono , Jong-Jan Lee , David R. Evans
IPC分类号： H01M4/52 , H01M10/44
CPC分类号： H01M8/188 , H01M2/14 , H01M4/24 , H01M4/248 , H01M4/32 , H01M4/382 , H01M4/50 , H01M4/52 , H01M4/521 , H01M4/523 , H01M8/184 , H01M8/20 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/26 , H01M10/30 , H01M10/44 , H01M12/08 , H01M2004/027 , H01M2004/028 , H01M2300/0014 , H01M2300/0025 , Y02E60/128 , Y10T29/49108
摘要： An alkali/oxidant battery is provided with an associated method of creating battery capacity. The battery is made from an anode including a reduced first alkali metal such as lithium (Li), sodium (Na), and potassium (K), when the battery is charged. The battery's catholyte includes an element, in the battery charged state, such as nickel oxyhydroxide (NiOOH), magnesium(IV) (oxide Mn(4+)O2), or iron(III) oxyhydroxide (Fe(3+)(OH)3), with the alkali metal hydroxide. An alkali metal ion permeable separator is interposed between the anolyte and the catholyte. For example, if the catholyte includes nickel(II) hydroxide (Ni(OH)2) in a battery discharged state, then it includes NiOOH in a battery charged state. To continue the example, the anolyte may include dissolved lithium ions (Li+) in a discharged state, with solid phase reduced Li formed on the anode in the battery charged state.
摘要翻译：碱/氧化剂电池具有产生电池容量的相关方法。当电池充电时，电池由包括还原的第一碱金属如锂（Li），钠（Na）和钾（K）的阳极制成。电池的阴极电解液包括电池充电状态的元素，例如氢氧化正镍（NiOOH），镁（IV）（氧化物Mn（4+）O 2）或氢氧化铁（III）（Fe（3 +）（OH） 3），用碱金属氢氧化物。在阳极电解液和阴极电解液之间插入碱金属离子可渗透分离器。例如，如果阴极电解液包含处于电池放电状态的镍（II）氢氧化物（Ni（OH）2），则其包括处于电池充电状态的NiOOH。为了继续该实施例，阳极电解液可以包括处于放电状态的溶解的锂离子（Li +），在电池充电状态下在阳极上形成固相Li。

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