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1. 发明授权

US5306735A Polyurethane, process for producing the same, and process for producing polyurethane foam 失效
标题翻译：聚氨酯，其制造方法和聚氨酯泡沫的制造方法
公开(公告)号：US5306735A
公开(公告)日：1994-04-26
申请号：US32107
申请日：1993-03-17
申请人： Shoichiro Harada , Yasutoshi Isayama , Tetsuaki Fukushima , Masayoshi Morii , Hiroshi Kitagawa , Hiroshi Abe
发明人： Shoichiro Harada , Yasutoshi Isayama , Tetsuaki Fukushima , Masayoshi Morii , Hiroshi Kitagawa , Hiroshi Abe
IPC分类号： C08G18/18 , C08G18/28 , C08G18/32 , C08G18/50 , C08G18/66 , C08G18/14
CPC分类号： C08G18/3271 , C08G18/1825 , C08G18/2875 , C08G18/3275 , C08G18/5021 , C08G18/6688 , C08G2101/0008 , C08G2101/0025 , C08G2101/005 , C08G2101/0083
摘要： Processes for producing a polyurethane, a rigid polyurethane foam, a flexible polyurethane foam and a spray type rigid polyurethane foam are disclosed. In these processes, a specified tertiary aminoalcohol is used as a polyol component and a catalyst.
摘要翻译：公开了用于生产聚氨酯，硬质聚氨酯泡沫，柔性聚氨酯泡沫和喷雾型硬质聚氨酯泡沫的方法。在这些方法中，使用特定的叔氨基醇作为多元醇成分和催化剂。

2. 发明授权

US5315041A Tertiary aminoalcohol and process for producing the same, and, polyurethane and process for producing the same 失效
标题翻译：三氨基醇及其制备方法，以及聚氨酯及其制备方法
公开(公告)号：US5315041A
公开(公告)日：1994-05-24
申请号：US845594
申请日：1992-03-04
申请人： Hiroshi Abe , Tetsuaki Fukushima , Kohshiro Sotoya , Shoichiro Harada , Hiroshi Kitagawa , Masayoshi Morii , Yasutoshi Isayama
发明人： Hiroshi Abe , Tetsuaki Fukushima , Kohshiro Sotoya , Shoichiro Harada , Hiroshi Kitagawa , Masayoshi Morii , Yasutoshi Isayama
IPC分类号： C07C215/14 , C07C217/08 , C08G18/32 , C08G18/64 , C08G18/66 , C08G73/02 , C07C215/02
CPC分类号： C08G73/024 , C07C215/14 , C07C217/08 , C08G18/3275 , C08G18/6423 , C08G18/6688 , C08G73/02 , C08G73/0206 , C08G2101/00
摘要： A tertiary aminoalcohol having a tert-amino group(s) in the main chain and hydroxyl groups at the terminals. The use of this compound for purposes different from that of ordinary amines and amine derivatives is expected.A process for producing the tertiary aminoalcohol wherein a catalyst comprising copper, a transition metal element of the fourth period and a platinum group element of the group VIII, and further optionally containing an alkali metal or an alkaline earth metal is used.A process for producing polyurethane using the above-mentioned tertiary aminoalcohol which can solve the problems occurring in the production of a polyurethane using a tertiary amine which has a strong irritating odor and is highly irritant to the skin as a catalyst, for example, deteriorations of working atmosphere and sales appeal of the polyurethane.The chemical structure of the above-described tertiary aminoalcohol is as follows: ##STR1##
摘要翻译：在主链中具有叔氨基和末端具有羟基的叔氨基醇。期望使用该化合物用于与普通胺和胺衍生物不同的目的。一种制备叔氨基醇的方法，其中使用包含铜的催化剂，第四阶段的过渡金属元素和VIII族的铂族元素，以及进一步任选含有碱金属或碱土金属的催化剂。使用上述叔氨基醇制造聚氨酯的方法，其可以使用具有强烈刺激性气味并且对皮肤高度刺激性的叔胺作为催化剂来解决在制备聚氨酯中发生的问题，例如，劣化工作气氛和聚氨酯的销售吸引力。上述叔氨基醇的化学结构如下：（I）

3. 发明授权

US5223547A Polyurethane, process for producing the same, and process for producing polyurethane foam 失效
标题翻译：聚氨酯，其制造方法以及生产聚氨酯泡沫的方法
公开(公告)号：US5223547A
公开(公告)日：1993-06-29
申请号：US797350
申请日：1991-11-25
申请人： Shoichiro Harada , Yasutoshi Isayama , Tetsuaki Fukushima , Masayoshi Morii , Hiroshi Kitagawa , Hiroshi Abe
发明人： Shoichiro Harada , Yasutoshi Isayama , Tetsuaki Fukushima , Masayoshi Morii , Hiroshi Kitagawa , Hiroshi Abe
IPC分类号： C08G18/18 , C08G18/28 , C08G18/32 , C08G18/50 , C08G18/66
CPC分类号： C08G18/6688 , C08G18/1825 , C08G18/2875 , C08G18/3271 , C08G18/3275 , C08G18/5021 , C08G2101/0008 , C08G2101/0025 , C08G2101/005 , C08G2101/0083
摘要： Processes for producing a polyurethane, a rigid polyurethane foam, a flexible polyurethane foam and a spray type rigid polyurethane foam are disclosed.In these processes, a specified tertiary aminoalcohol is used as a polyol component and a catalyst.

4. 发明授权

US5444099A Tertiary aminoalcohol ane process for producing the same, and, polyurethane and process for producing the same 失效
标题翻译：用于制备其的三氨基醇肛门方法，以及聚氨酯及其制备方法
公开(公告)号：US5444099A
公开(公告)日：1995-08-22
申请号：US123165
申请日：1993-09-20
申请人： Hiroshi Abe , Tetsuaki Fukushima , Kohshiro Sotoya , Shoichiro Harada , Hiroshi Kitagawa , Masayoshi Morii , Yasutoshi Isayama
发明人： Hiroshi Abe , Tetsuaki Fukushima , Kohshiro Sotoya , Shoichiro Harada , Hiroshi Kitagawa , Masayoshi Morii , Yasutoshi Isayama
IPC分类号： C07C215/14 , C07C217/08 , C08G18/32 , C08G18/64 , C08G18/66 , C08G73/02 , C07C215/02 , C08G18/00
CPC分类号： C08G73/024 , C07C215/14 , C07C217/08 , C08G18/3275 , C08G18/6423 , C08G18/6688 , C08G73/02 , C08G73/0206 , C08G2101/00
摘要： A tertiary aminoalcohol having a tert-amino group(s) in the main chain and hydroxyl groups at the terminals. The use of this compound for purposes different from that of ordinary amines and amine derivatives is expected.A process for producing the tertiary aminoalcohol wherein a catalyst comprising copper, a transition metal element of the fourth period and a platinum group element of the group VIII, and further optionally containing an alkali metal or an alkaline earth metal is used.A process for producing polyurethane using the above-mentioned tertiary aminoalcohol which can solve the problems occurring in the production of a polyurethane using a tertiary amine which has a strong irritating odor and is highly irritant to the skin as a catalyst, for example, deteriorations of working atmosphere and sales appeal of the polyurethane.The chemical structure of the above-described tertiary aminoalcohol is as follows: ##STR1##
摘要翻译：在主链中具有叔氨基和末端具有羟基的叔氨基醇。期望使用该化合物用于与普通胺和胺衍生物不同的目的。一种制备叔氨基醇的方法，其中使用包含铜的催化剂，第四阶段的过渡金属元素和VIII族的铂族元素，以及进一步任选含有碱金属或碱土金属的催化剂。使用上述叔氨基醇制造聚氨酯的方法，其可以使用具有强烈刺激性气味并且对皮肤高度刺激性的叔胺作为催化剂来解决在制备聚氨酯中发生的问题，例如，劣化工作气氛和聚氨酯的销售吸引力。上述叔氨基醇的化学结构如下：（I）

5. 发明授权

US06410608B1 Process for producing polyurethane foam 有权
标题翻译：生产聚氨酯泡沫的方法
公开(公告)号：US06410608B1
公开(公告)日：2002-06-25
申请号：US09744917
申请日：2001-04-27
申请人： Mitsuru Sakai , Atsushi Ishikawa , Masayoshi Morii
发明人： Mitsuru Sakai , Atsushi Ishikawa , Masayoshi Morii
IPC分类号： C08G1814
CPC分类号： C08G18/482 , C08G18/18 , C08G18/1825 , C08G2101/00 , C08G2101/0025 , C08G2101/005
摘要： A process for producing a polyurethane foam comprising reacting a polyol component with an isocyanate component in the presence of a catalyst comprising a compound represented by the formula (I): wherein p is an integer of 4 to 8, and a compound having a primary amino group and a tertiary amino group in its molecule, a blowing agent and a surfactant. The polyurethane foam obtained by the process of the present invention can be suitably used for heat insulating materials for construction materials, electric refrigerators, refrigerated warehouses, baths and the like, interior materials for automobiles, and the like.
摘要翻译：一种制备聚氨酯泡沫的方法，包括在催化剂存在下使多元醇组分与异氰酸酯组分反应，所述催化剂包含由式（I）表示的化合物：其中p为4-8的整数，并且具有伯氨基基团和叔氨基，发泡剂和表面活性剂。通过本发明的方法获得的聚氨酯泡沫可以适用于建筑材料，电冰箱，冷藏仓库，浴室等的隔热材料，汽车用内饰材料等。

6. 发明授权

US06767929B2 Process for producing polyurethane 失效
标题翻译：生产聚氨酯的方法
公开(公告)号：US06767929B2
公开(公告)日：2004-07-27
申请号：US10168077
申请日：2002-06-17
申请人： Atsushi Ishikawa , Mitsuru Sakai , Masayoshi Morii
发明人： Atsushi Ishikawa , Mitsuru Sakai , Masayoshi Morii
IPC分类号： C08J904
CPC分类号： C08G18/6688 , C08G18/1825 , C08G2101/00 , C08G2101/0016 , C08G2101/0083
摘要： A catalyst for producing a polyurethane, comprising a dialkylaminoalkyl alcohol represented by the formula (I): R1R2N—X—OH (I) wherein each of R1 and R2 is independently an alkyl group having 1 to 4 carbon atoms; and X is a branched alkylene group having 4 to 8 carbon atoms; a process for producing a polyurethane, comprising reacting a polyol component with an isocyanate component in the presence of the above-mentioned catalyst for producing a polyurethane; and a process for producing a polyurethane foam, comprising reacting a polyol component with an isocyanate component in the presence of the above-mentioned catalyst for producing a polyurethane, and a compound having a primary amino group and a tertiary amino group in its molecule, and a blowing agent. The polyurethane can be used as heat insulating materials for construction materials, electric refrigerators, refrigerated warehouses, baths and the like, interior materials for automobiles, furnishings, cushioning materials for beddings, various sealing materials and the like.
摘要翻译：一种制备聚氨酯的催化剂，其包含由式（I）表示的二烷基氨基烷基醇：其中R 1和R 2各自独立地为具有1至4个碳原子的烷基; X为碳原子数为4〜8的支链亚烷基。一种制备聚氨酯的方法，包括在上述用于制备聚氨酯的催化剂的存在下使多元醇组分与异氰酸酯组分反应; 和聚氨酯泡沫体的制造方法，其特征在于，在上述制造聚氨酯的催化剂的存在下，使多元醇成分与异氰酸酯成分反应，分子中具有伯氨基和叔氨基的化合物，以及发泡剂。聚氨酯可以用作建筑材料，电冰箱，冷藏仓库，浴室等的隔热材料，汽车用内饰材料，家具，用于床上用品的缓冲材料，各种密封材料等。

7. 发明授权

US06306918B1 Semi-rigid polyurethane foam 有权
标题翻译：半刚性聚氨酯泡沫
公开(公告)号：US06306918B1
公开(公告)日：2001-10-23
申请号：US09386138
申请日：1999-08-31
申请人： Mitsuru Sakai , Atsushi Ishikawa , Masayoshi Morii
发明人： Mitsuru Sakai , Atsushi Ishikawa , Masayoshi Morii
IPC分类号： C08J904
CPC分类号： C08G18/6688 , C08G2101/0016 , C08G2101/0083 , C08G2290/00 , C08J2205/08
摘要： A semi-rigid polyurethane foam having a strength retention of not less than 70% when allowing it to stand at 120° C. for 24 hours, and a Haze value of not more than 2 as determined by Fogging test, prepared by mixing a polyol mixture comprising a polyol, water and a catalyst with a polyisocyanate, and foaming the resulting mixture, and a process for preparing the same. The semi-rigid polyurethane foam would not cause fogging under high-temperature conditions, and can be suitably used for interior materials of automobiles such as headrests and armrests.
摘要翻译：一种半硬质聚氨酯泡沫，当其在120℃下静置24小时时，其强度保持率不低于70％，通过将多元醇混合制备的通过雾化试验测定的雾度值不大于2 混合物，其包含多元醇，水和催化剂与多异氰酸酯，并使所得混合物发泡，以及其制备方法。半硬质聚氨酯泡沫在高温条件下不会引起起雾，可适用于头枕，扶手等汽车内饰材料。

8. 发明授权

US4714719A Catalyst for preparation of polyurethane and process for the preparation 失效
标题翻译：用于制备聚氨酯的催化剂及其制备方法
公开(公告)号：US4714719A
公开(公告)日：1987-12-22
申请号：US927287
申请日：1986-11-04
申请人： Harumasa Yamasaki , Masayoshi Morii , Yukinaga Yokota , Akira Mamada , Yoshiyuki Nabata
发明人： Harumasa Yamasaki , Masayoshi Morii , Yukinaga Yokota , Akira Mamada , Yoshiyuki Nabata
IPC分类号： B01J31/38 , B01J37/00 , C08F4/60 , C08F4/64 , C08F4/642 , C08F10/00 , C08F10/06 , C08G18/18
CPC分类号： C08G18/1825
摘要： A polyurethane is prepared with use of a catalyst comprising a compound having the formula: ##STR1## in which n is an integer of 2 to 12, A is a hydrogen or a group of --CH.sub.2 CHRCH.sub.2 NH.sub.2 and R is hdyrogen or methyl, provided that n is 6 when A is hydrogen. The compound scarcely smells and does not elute out of the polyurethane article. The process is easy to control.
摘要翻译：使用包含具有下式的化合物的催化剂制备聚氨酯：其中n为2至12的整数，A为氢或-CH 2 CHRCH 2 NH 2基团，R为氢或甲基，条件是n 当A为氢时为6。该化合物几乎没有气味，不会从聚氨酯制品中洗脱出来。该过程易于控制。

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