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1. 发明授权

US10457755B2 Solid catalyst component for olefin polymerization, method for producing the same, olefin polymerization catalyst, and method for producing olefin polymer 有权
公开(公告)号：US10457755B2
公开(公告)日：2019-10-29
申请号：US15109611
申请日：2014-08-04
申请人： TOHO TITANIUM CO., LTD.
发明人： Toshihiko Sugano , Toshiya Uozumi , Motoki Hosaka
IPC分类号： C08F4/649 , C08F297/08 , C08F110/06
摘要： High stereoregularity, highly active catalytic performance, and good hydrogen response can be obtained by homopolymerizing propylene in the presence of a catalyst that includes a solid catalyst component including titanium, magnesium, a halogen, a carbonate compound represented by the following formula, and a diether compound. Excellent polymerization behavior can also be obtained when effecting random copolymerization or block copolymerization. R1—O—C(═O)—O—Z—O—R2 (1) wherein R1 and R2 are a hydrocarbon group or a substituted hydrocarbon group having 1 to 24 carbon atoms, or a heteroatom-containing group, provided that R1 and R2 are either identical or different, and Z is a linking group that links two oxygen atoms through a carbon atom or a carbon chain.

2. 发明授权

US09683059B2 Solid catalyst component for polymerization of olefins, catalyst for polymerization of olefins, and method for producing olefin polymer 有权
公开(公告)号：US09683059B2
公开(公告)日：2017-06-20
申请号：US14427099
申请日：2013-09-24
申请人： TOHO TITANIUM CO., LTD.
发明人： Motoki Hosaka , Hidetoshi Umebayashi , Toshihiko Sugano
IPC分类号： C08F110/06 , C08F210/06 , C08F299/02 , C08F210/16 , C08F297/08
CPC分类号： C08F110/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08F299/02 , C08F10/00 , C08F4/6548 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F4/6492 , C08F4/651 , C08F4/6465
摘要： A solid catalyst component for olefin polymerization makes it possible to polymerize an olefin with high polymerization activity when used for an olefin polymerization catalyst, and produce an olefin polymer having a low fine powder content, a low coarse powder content, and a low volatile organic compound (VOC) content in high yield. The solid catalyst component for olefin polymerization is produced by suspending (a) a dialkoxymagnesium, and (b) at least one alcohol selected from ethanol, n-propanol, n-butanol, isopropanol, isobutanol, and t-butanol, in an inert organic solvent so that the total amount of the alcohol is 0.5 to 1.5 parts by mass based on 100 parts by mass of the dialkoxymagnesium, to prepare a suspension, and bringing (c) an internal electron donor and (d) a titanium halide compound into contact with the suspension.

3. 发明申请

US20190185597A1 METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, OLEFIN POLYMERIZATION CATALYST, METHOD FOR PRODUCING OLEFIN POLYMERIZATION CATALYST, AND METHOD FOR PRODUCING OLEFIN POLYMER 审中-公开
公开(公告)号：US20190185597A1
公开(公告)日：2019-06-20
申请号：US15846789
申请日：2017-12-19
申请人： TOHO TITANIUM CO., LTD.
发明人： Motoki Hosaka , Toshihiko Sugano , Tsutomu Uzawa
IPC分类号： C08F110/06
摘要： A method for producing a solid catalyst component includes bringing a magnesium compound, a titanium halide compound, and one or more internal electron donor compounds into contact with each other to effect a reaction; washing the resulting product with a first inert organic wash solvent that does not have reactivity with the titanium halide compound, and has a solubility parameter (SP) of 8.0 to 9.0; washing the resulting intermediate product in the absence of the titanium halide compound with a second inert organic wash solvent that includes a hydrocarbon compound and does not have reactivity with the titanium halide compound, but has a solubility parameter (SP) of more than 9.0; and washing the resulting product in the absence of the titanium halide compound with a third inert organic wash solvent that does not have reactivity with the titanium halide compound, and has a solubility parameter (SP) of less than 8.0.

4. 发明授权

US10246530B2 Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization and a process for propylene polymerization 有权
公开(公告)号：US10246530B2
公开(公告)日：2019-04-02
申请号：US15634410
申请日：2017-06-27
申请人： TOHO TITANIUM CO., LTD.
发明人： Motoki Hosaka , Toshihiko Sugano , Tsutomu Uzawa
IPC分类号： C08F10/06 , C08F10/02
摘要： A method for producing a solid catalyst for olefin (co)polymerization includes bringing into contact with each other a magnesium compound, a tetravalent titanium halide compound, an organic compound represented the following general formula (1) R1k(C6H4-k)(COOR2)(COOR3) (1) and an organic compound represented the following general formula (2) R4R5C═C (COOR6)(COOR7) (2) wherein R1 is a halogen atom or an alkyl group, R2 and R3 are a linear alkyl group, R4 and R5 are independently an atom or group selected from a hydrogen atom, halogen, a linear alkyl group, a branched alkyl group a vinyl group, a linear or branched alkenyl group, a cycloalkenyl group, an aromatic hydrocarbon group, and R6 and R7 are independently a linear alkyl group, a branched alkyl group, a vinyl group, a linear or branched alkenyl group a cycloalkyl group, a cycloalkenyl group, or an aromatic hydrocarbon group.

5. 发明授权

US10011669B2 Method for producing propylene block copolymer 有权
公开(公告)号：US10011669B2
公开(公告)日：2018-07-03
申请号：US14770974
申请日：2014-02-05
申请人： TOHO TITANIUM CO., LTD.
发明人： Toshihiko Sugano , Motoki Hosaka , Toshiya Uozumi
IPC分类号： C08F210/06 , C08F297/08
CPC分类号： C08F210/06 , C08F297/08 , C08F210/16 , C08F2500/12 , C08F10/00 , C08F4/651 , C08F2/001 , C08F4/6492 , C08F4/6465
摘要： A method for producing a propylene-based block copolymer ensures excellent olefin polymerization activity and activity with respect to hydrogen (hydrogen response) during polymerization, and produces a propylene-based block copolymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes copolymerizing propylene and an α-olefin in the presence of a catalyst that includes (I) a solid catalyst component that includes titanium, magnesium, a halogen, and a compound represented by R1O—C(═O)—O—Z—OR2, and (II) a compound represented by R3pAlQ3-p, to obtain a propylene-based block copolymer.

6. 发明申请

US20150240001A1 SOLID CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINS, CATALYST FOR POLYMERIZATION OF OLEFINS, AND METHOD FOR PRODUCING OLEFIN POLYMER 有权
标题翻译：用于烯烃聚合的固体催化剂组分，用于烯烃聚合的催化剂和用于生产烯烃聚合物的方法
公开(公告)号：US20150240001A1
公开(公告)日：2015-08-27
申请号：US14427099
申请日：2013-09-24
申请人： TOHO TITANIUM CO., LTD.
发明人： Motoki Hosaka , Hidetoshi Umebayashi , Toshihiko Sugano
IPC分类号： C08F110/06 , C08F210/06 , C08F299/02
CPC分类号： C08F110/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08F299/02 , C08F10/00 , C08F4/6548 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F4/6492 , C08F4/651 , C08F4/6465
摘要： A solid catalyst component for olefin polymerization makes it possible to polymerize an olefin with high polymerization activity when used for an olefin polymerization catalyst, and produce an olefin polymer having a low fine powder content, a low coarse powder content, and a low volatile organic compound (VOC) content in high yield. The solid catalyst component for olefin polymerization is produced by suspending (a) a dialkoxymagnesium, and (b) at least one alcohol selected from ethanol, n-propanol, n-butanol, isopropanol, isobutanol, and t-butanol, in an inert organic solvent so that the total amount of the alcohol is 0.5 to 1.5 parts by mass based on 100 parts by mass of the dialkoxymagnesium, to prepare a suspension, and bringing (c) an internal electron donor and (d) a titanium halide compound into contact with the suspension.
摘要翻译：用于烯烃聚合的固体催化剂组分使得可以在用于烯烃聚合催化剂时聚合具有高聚合活性的烯烃，并且制备具有低细粉末含量，低粗粉末含量和低挥发性有机化合物的烯烃聚合物（VOC）含量高产。用于烯烃聚合的固体催化剂组分通过将（a）二烷氧基镁和（b）至少一种选自乙醇，正丙醇，正丁醇，异丙醇，异丁醇和叔丁醇的醇悬浮在惰性有机物中来制备溶剂，使得相对于100质量份的二烷氧基镁，醇的总量为0.5〜1.5质量份，制备悬浮液，并使（c）内电子给体和（d）卤化钛化合物接触与暂停。

7. 发明申请

US20150166693A1 METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR USE IN POLYMERIZATION OF OLEFIN, CATALYST FOR USE IN POLYMERIZATION OF OLEFIN, AND METHOD FOR PRODUCING OLEFIN POLYMER 有权
标题翻译：用于生产用于烯烃聚合的固体催化剂组分的方法，用于烯烃聚合的催化剂的方法和用于生产烯烃聚合物的方法
公开(公告)号：US20150166693A1
公开(公告)日：2015-06-18
申请号：US14407184
申请日：2013-07-10
申请人： TOHO TITANIUM CO., LTD.
发明人： Motoki Hosaka , Noriaki Nakamura , Toshihiko Sugano
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F110/06 , C08F4/654 , C08F4/6465 , C08F2500/12 , C08F2500/15 , C08F210/06 , C08F210/16 , C08F2/001
摘要： A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds selected from specific aromatic dicarboxylic diesters into contact with each other to effect a reaction, followed by washing, a second step that brings a tetravalent titanium halide compound and one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction, followed by washing, and a third step that brings one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.
摘要翻译：一种用于烯烃聚合的固体催化剂组分的制备方法产生用于烯烃聚合的新型固体催化剂组分，其在聚合过程中实现优异的烯烃聚合活性和相对于氢的活性，并且可以制备出显示出高MFR，高立构规整性的烯烃聚合物，刚性好。该方法包括使镁化合物，四价卤化钛化合物和选自特定芳族二羧酸二酯的一种或多种第一内电子给体化合物彼此接触以进行反应，随后进行洗涤的第一步骤，第二步骤其将四价卤化钛化合物和一种或多种第二内电子给体化合物与通过第一步获得的产物接触以进行反应，随后进行洗涤，以及第三步，将一种或多种第三内电子给体化合物引入与通过第二步获得的产物接触以进行反应。

8. 发明授权

US10590211B2 Method for producing solid catalyst component for olefin polymerization, olefin polymerization catalyst, method for producing olefin polymerization catalyst, and method for producing olefin polymer 有权
公开(公告)号：US10590211B2
公开(公告)日：2020-03-17
申请号：US15846789
申请日：2017-12-19
申请人： TOHO TITANIUM CO., LTD.
发明人： Motoki Hosaka , Toshihiko Sugano , Tsutomu Uzawa
IPC分类号： C08F110/06
摘要： A method for producing a solid catalyst component includes bringing a magnesium compound, a titanium halide compound, and one or more internal electron donor compounds into contact with each other to effect a reaction; washing the resulting product with a first inert organic wash solvent that does not have reactivity with the titanium halide compound, and has a solubility parameter (SP) of 8.0 to 9.0; washing the resulting intermediate product in the absence of the titanium halide compound with a second inert organic wash solvent that includes a hydrocarbon compound and does not have reactivity with the titanium halide compound, but has a solubility parameter (SP) of more than 9.0; and washing the resulting product in the absence of the titanium halide compound with a third inert organic wash solvent that does not have reactivity with the titanium halide compound, and has a solubility parameter (SP) of less than 8.0.

9. 发明授权

US10113014B1 Method for producing solid catalyst component containing vanadium compound for olefin polymerization, olefin polymerization catalyst, and method for producing olefin polymer 有权
公开(公告)号：US10113014B1
公开(公告)日：2018-10-30
申请号：US15634338
申请日：2017-06-27
申请人： TOHO TITANIUM CO., LTD.
发明人： Motoki Hosaka , Toshihiko Sugano , Tsutomu Uzawa
IPC分类号： C08F4/685 , C08F10/00 , C08K5/10 , C08F4/14
摘要： A solid catalyst component for olefin polymerization, an olefin polymerization catalyst, and a method for producing an olefin polymer, are disclosed. A solid catalyst component for olefin polymerization includes magnesium, a halogen, titanium, vanadium, and an internal electron donor compound selected by organic acid diester. An olefin polymerization catalyst includes the disclosed solid catalyst component for olefin polymerization, an organoaluminum promoter, and an optional external electron donor A method for producing an olefin copolymer includes copolymerizing ethylene and propylene using the disclosed olefin polymerization catalyst.

10. 发明授权

US09587050B2 Production method for solid catalyst component for polymerizing olefins, catalyst for polymerizing olefins, and production method for polymerized olefins 有权
标题翻译：用于聚合烯烃的固体催化剂组分的制备方法，用于聚合烯烃的催化剂和聚合烯烃的制备方法
公开(公告)号：US09587050B2
公开(公告)日：2017-03-07
申请号：US14427143
申请日：2014-02-13
申请人： TOHO TITANIUM CO., LTD.
发明人： Motoki Hosaka , Noriaki Nakamura , Shingo Yamada , Toshihiko Sugano
IPC分类号： C08F110/06 , C08F210/06 , C08F299/02 , C08F10/00
CPC分类号： C08F110/06 , C08F10/00 , C08F210/06 , C08F297/083 , C08F299/02 , C08F4/651 , C08F210/16 , C08F2500/12 , C08F2500/15 , C08F10/06 , C08F2/001 , C08F4/6492
摘要： A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds excluding an aromatic dicarboxylic acid diester into contact with each other to effect a reaction, followed by washing; a second step that brings a tetravalent titanium halide compound and one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction, followed by washing; and a third step that brings one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.
摘要翻译：一种用于烯烃聚合的固体催化剂组分的制备方法产生用于烯烃聚合的新型固体催化剂组分，其在聚合过程中实现优异的烯烃聚合活性和相对于氢的活性，并且可以制备出显示出高MFR，高立构规整性的烯烃聚合物，刚性好。该方法包括使镁化合物，四价卤化钛化合物和除芳香族二羧酸二酯以外的一种以上的第一内部电子给体化合物接触进行反应，然后进行洗涤的第一工序; 第二步骤，使四价卤化钛化合物和一种或多种第二内电子给体化合物与通过第一步获得的产物接触以进行反应，随后进行洗涤; 以及第三步骤，其使一个或多个第三内部电子给体化合物与通过第二步获得的产物接触以进行反应。

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