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1. 发明授权

US09725535B2 Multi-metallic Ziegler-Natta procatalysts and catalysts prepared therefrom for olefin polymerizations 有权
公开(公告)号：US09725535B2
公开(公告)日：2017-08-08
申请号：US14981021
申请日：2015-12-28
申请人： Dow Global Technologies LLC
发明人： Sylvie Desjardins , Mehmet Demirors , Ellen Donkers , Philip P. Fontaine , Cristina Serrat
IPC分类号： C08F210/16 , C08F210/02 , C08F110/02 , C08F10/02 , C08F4/685 , C08J5/18 , D01F6/04
CPC分类号： C08F110/02 , C08F4/685 , C08F10/02 , C08F210/16 , C08F2410/03 , C08J5/18 , C08J2323/06 , D01F6/04 , C08F4/6341 , C08F4/6385 , C08F4/6374 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/26 , C08F4/6357
摘要： Novel catalyst compositions comprising three or more transition metals are effective in increasing catalyst efficiency, reducing polydispersity, and increasing uniformity in molecular weight distribution when used in olefin, and particularly, linear low density polyethylene (LLDPE), polymerizations. The resulting polymers may be used to form differentiated products including, for example, films that may exhibit improved optical and mechanical properties.

2. 发明授权

US09255160B2 Multi-metallic ziegler-natta procatalysts and cataysts prepared therefrom for olefin polymerizations 有权
标题翻译：多金属齐格勒 - 纳塔催化剂及其制备用于烯烃聚合的催化剂
公开(公告)号：US09255160B2
公开(公告)日：2016-02-09
申请号：US14116070
申请日：2012-05-23
申请人： Sylvie Desjardins , Mehmet Demirors , Ellen Donkers , Philip P. Fontaine , Cristina Serrat
发明人： Sylvie Desjardins , Mehmet Demirors , Ellen Donkers , Philip P. Fontaine , Cristina Serrat
IPC分类号： C08F4/685 , C08F10/02 , C08F210/16
CPC分类号： C08F110/02 , C08F4/685 , C08F10/02 , C08F210/16 , C08F2410/03 , C08J5/18 , C08J2323/06 , D01F6/04 , C08F4/6341 , C08F4/6385 , C08F4/6374 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/26 , C08F4/6357
摘要： Novel catalyst compositions comprising three or more transition metals are effective in increasing catalyst efficiency, reducing polydispersity, and increasing uniformity in molecular weight distribution when used in olefin, and particularly, linear low density polyethylene (LLDPE), polymerizations. The resulting polymers may be used to form differentiated products including, for example, films that may exhibit improved optical and mechanical properties.
摘要翻译：包含三种或更多种过渡金属的新型催化剂组合物在用于烯烃，特别是线性低密度聚乙烯（LLDPE））聚合中时，有效地提高催化剂效率，降低多分散性和增加分子量分布的均匀性。所得聚合物可用于形成分化产物，包括例如可能表现出改善的光学和机械性能的膜。

3. 发明申请

US20130158215A1 MODIFIED ZIEGLER-NATTA CATALYST SYSTEMS 审中-公开
标题翻译：改性ZIEGLER-NATTA催化剂体系
公开(公告)号：US20130158215A1
公开(公告)日：2013-06-20
申请号：US13698025
申请日：2011-05-19
申请人： Elsa Martigny , Vincent Monteil , Roger Spitz , Aurélien Vantomme
发明人： Elsa Martigny , Vincent Monteil , Roger Spitz , Aurélien Vantomme
IPC分类号： C08F4/685 , C08F210/16 , C08F10/02 , C08F4/646 , C08F4/68
CPC分类号： C08F4/685 , C08F4/646 , C08F4/68 , C08F10/00 , C08F10/02 , C08F210/16 , C08F210/14 , C08F2500/23 , C08F4/02 , C08F4/657
摘要： This invention relates to modified Ziegler-Natta catalyst systems that have an excellent activity in homo- or co-polymerisation of ethylene and alpha-olefins and are able to produce polymers having reduced molecular weight distribution and improved incorporation of hexene with respect to conventional Ziegler-Natta catalyst systems.
摘要翻译：本发明涉及在乙烯和α-烯烃的均聚或共聚合中具有优异活性的改性齐格勒 - 纳塔催化剂体系，并且能够生产具有降低的分子量分布和改进己烯掺入的聚合物相对于常规的齐格勒 - 纳塔催化剂体系。

4. 发明授权

US5783645A Non-sticky prepolymerized catalyst, and use thereof in production of non-sticky resin 失效
标题翻译：非粘性预聚合催化剂及其在生产非粘性树脂中的应用
公开(公告)号：US5783645A
公开(公告)日：1998-07-21
申请号：US666641
申请日：1996-06-18
申请人： Edgar Chapman Baker , Jose Fernando Cevallos-Candau , Eric Allan Lucas , John Gregory Victor , Allan Noshay
发明人： Edgar Chapman Baker , Jose Fernando Cevallos-Candau , Eric Allan Lucas , John Gregory Victor , Allan Noshay
IPC分类号： C08F2/34 , C08F4/60 , C08F4/631 , C08F4/64 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F4/685 , C08F8/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F255/00 , C08F255/02
CPC分类号： C08F255/02 , C08F10/00 , C08F210/16 , C08F255/00 , C08F210/18 , Y10S525/902 , Y10S526/901 , Y10S526/904 , Y10S526/905 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998
摘要： A colorable resin particle having an outer shell of a non-sticky polymer and an inner core of a sticky polymer produced in a gas phase fluidized bed reactor at or above the sticking temperature of the sticky polymer using a non-sticky prepolymerized catalyst and processes for producing the colorable resin and the non-sticky prepolymerized catalyst.
摘要翻译：一种可着色的树脂颗粒，其具有非粘性聚合物的外壳和在气相流化床反应器中产生的粘性聚合物的内芯，其粘度聚合物的粘合温度高于或高于使用非粘性预聚合催化剂的方法制造可着色树脂和非粘性预聚合催化剂。

5. 发明授权

US5369193A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US5369193A
公开(公告)日：1994-11-29
申请号：US967556
申请日：1992-10-27
申请人： Akira Sano , Takeichi Shiraishi , Kunihiro Suzuki , Mitsuo Okamoto , Kazuo Matsuura
发明人： Akira Sano , Takeichi Shiraishi , Kunihiro Suzuki , Mitsuo Okamoto , Kazuo Matsuura
IPC分类号： C08F4/60 , C08F4/657 , C08F4/658 , C08F4/685 , C08F10/00
CPC分类号： C08F10/00
摘要： Polyolefins exhibiting better particle properties are prepared by polymerizing an olefin or olefins in the presence of a catalyst comprising a solid catalyst component and an organometallic compound, the solid catalyst component being prepared by reacting the following components [I] and [II] at first and then reacting the reaction product thus obtained with the following component [III]:[I] a reaction product obtained by reacting:(1) a silicon oxide and/or an aluminum oxide, and(2) a titanium compound, or a titanium compound and a vanadium compound,[II] a reaction product obtained by the reaction of:(1) a magnesium halide,(2) a compound represented by the general formula Me(OR).sub.n X.sub.z-n wherein Me represents an element of J Groups I to IV in the Periodic Table, z represents the valence of the element Me, n is 0
摘要翻译：通过在包含固体催化剂组分和有机金属化合物的催化剂存在下聚合烯烃或烯烃制备出具有更好颗粒性能的聚烯烃，该固体催化剂组分通过首先使下列成分[I]和[II]反应而制备，然后将所得反应产物与以下组分[III]反应：[I]通过使（1）氧化硅和/或氧化铝反应获得的反应产物，和（2）钛化合物或钛化合物和钒化合物，[II]通过以下反应获得的反应产物：（1）卤化镁，（2）由通式Me（OR）n Xz-n表示的化合物，其中Me表示J组I 至IV元素，z表示元素Me的化合价，n为0

6. 发明授权

US4987111A Catalyst component and catalyst for the polymerization of ethylene and the copolymerization of ethylene with alpha-olefins 失效
标题翻译：用于乙烯聚合的催化剂组分和催化剂以及乙烯与α-烯烃的共聚合
公开(公告)号：US4987111A
公开(公告)日：1991-01-22
申请号：US403681
申请日：1989-09-06
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
IPC分类号： C08F4/60 , C08F4/639 , C08F4/646 , C08F4/685 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02
摘要： A solid catalyst component for the polymerization of ethylene and the copolymerization of ethylene with C.sub.3 -C.sub.10 alpha-olefins, contains titanium, vanadium and chlorine, is substantially definable by the formula (in atomic proportions):V (1), Ti (n), Cl (4n)where n varies from 1 to 3, and is prepared by reacting titanium tetrachloride with a vanadium arene [V.degree.(arene).sub.2 ] (arene=benzene or mono-, di- or tri-alkyl substituted benzene) in accordance with the equation:V.degree.(arene).sub.2 +nTiCl.sub.4 .fwdarw.VTi.sub.n Cl.sub.4n +2 arenepossibly followed by treatment with an alkyl aluminum chloride. This catalyst component, when associated with a trialkyl aluminium, is highly active in the production of ethylene polymers and copolymers by low temperature, low pressure methods in suspension, or by high temperature, high pressure methods conducted in a tubular reactor or pressure vessel, or by high temperature methods conducted in solution.

7. 发明申请

US20110263801A1 MULTI-STAGE PROCESS FOR PRODUCING MULTI-MODAL LINEAR LOW DENSITY POLYETHYLENE 有权
标题翻译：用于生产多模式线性低密度聚乙烯的多级方法
公开(公告)号：US20110263801A1
公开(公告)日：2011-10-27
申请号：US13126496
申请日：2010-02-22
申请人： Thomas Garoff , Päivi Waldvogel , Kalle Kallio , Virginie Eriksson , Aki Aittola , Esa Kokko
发明人： Thomas Garoff , Päivi Waldvogel , Kalle Kallio , Virginie Eriksson , Aki Aittola , Esa Kokko
IPC分类号： C08F10/02 , C08F4/685 , C08F2/34 , C08F2/12
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/03 , Y10T428/139 , C08F4/6357 , C08F4/685 , C08F2/001 , C08F2500/07 , C08F2500/12 , C08F2500/05 , C08F2500/18 , C08F210/14 , C08F2500/08
摘要： Multi-stage polymerization process for the production of a multi-modal linear low density polyethylene in at least two staged reactors connected in series comprising at least (i) polymerizing in a first slurry phase stage ethylene monomers and optionally one or more alpha-olefin comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a first polyethylene fraction component (A) (ii) polymerizing in a second gas or slurry phase stage ethylene monomers and one or more alpha-olefine comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a second polyethylene fraction component (B), whereby the Ziegler-Natta polymerization catalyst system comprises: 1) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate complex of the formula (I): Mg(OR1)2-n(R1)n, wherein each R1 independently represents a C1-C20 hydrocarbyl group and 0
摘要翻译：用于在至少两个串联反应器中连续串联生产多模式线性低密度聚乙烯的多级聚合方法，包括至少（i）在第一浆料相阶段聚合乙烯单体和任选的一种或多种α-烯烃共聚单体在齐格勒 - 纳塔聚合催化剂体系存在下，得到第一聚乙烯级分组分（A）（ⅱ）在第二种气相或淤浆相阶段中聚合乙烯单体和一种或多种α-烯烃共聚单体，在齐格勒 - 纳塔聚合催化剂体系，以获得第二聚乙烯部分组分（B），由此齐格勒 - 纳塔聚合催化剂体系包括：1）通过使至少与下式接触形成的固体前催化剂：a）式）：Mg（OR 1）2-n（R 1）n，其中每个R 1独立地表示C 1 -C 20烃基且0

8. 发明授权

US06911506B2 Catalyst composition and olefin polymerization using same 失效
公开(公告)号：US06911506B2
公开(公告)日：2005-06-28
申请号：US10013144
申请日：2001-12-10
申请人： Brooke L. Small , Angel Jose Marcucci
发明人： Brooke L. Small , Angel Jose Marcucci
IPC分类号： C07F11/00 , C08F4/60 , C08F4/62 , C08F4/6392 , C08F4/659 , C08F4/68 , C08F4/685 , C08F4/69 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/44 , B01J31/23
CPC分类号： B01J31/18 , B01J31/1815 , B01J31/2204 , B01J31/24 , B01J2231/122 , B01J2231/20 , B01J2531/56 , B01J2531/62 , B01J2531/72 , C07F11/005 , C08F4/63912 , C08F4/6392 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/02 , C08F4/63904 , C08F2500/02 , C08F2500/23 , C08F210/14 , C08F4/69224 , C08F10/00 , C08F4/69232
摘要： Novel metal complexes, particularly chromium complexes, which contain at least one tridentate ligand are disclosed and prepared. Olefins, particularly ethylene, can be reacted to form butene and/or other homo- or co-oligomers and/or polymers with high α-olefin concentrations by contacting a metal catalyst which contains a transition metal, particularly chromium, complexes having per metal atom at least one tridentate ligand with N, O, or N and O coordinating sites.

9. 发明授权

US5644008A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US5644008A
公开(公告)日：1997-07-01
申请号：US546824
申请日：1995-10-23
申请人： Akira Sano , Takeichi Shiraishi , Hiroyuki Shimizu , Kunihiro Suzuki , Kazuo Matsuura
发明人： Akira Sano , Takeichi Shiraishi , Hiroyuki Shimizu , Kunihiro Suzuki , Kazuo Matsuura
IPC分类号： C08F4/658 , C08F4/60 , C08F4/654 , C08F4/656 , C08F4/685 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16
摘要： Olefin is polymerized using a catalyst comprising a solid catalyst component and an organometallic compound, the solid catalyst component being prepared by reacting 1 a reaction product obtained by reacting the reaction product of Si oxide and/or Al oxide and Ti compound or both Ti compound and V compound (Ti.V component) with organic Al compound, with 2 a reaction product obtained by the reaction of Mg halide, a compound of the general formula Me(OR).sub.n X.sub.z-n and Ti.V component (optional component), and further reacting the reaction product of the above 1 and 2 with 3 a compound of the general formula R.sub.p Si(OR).sub.q X.sub.4-p-q.
摘要翻译：烯烃使用包含固体催化剂组分和有机金属化合物的催化剂聚合，所述固体催化剂组分通过使+ E，crc 1 + EE与Si氧化物和/或氧化铝的反应产物和Ti 化合物或Ti化合物和V化合物（Ti.V组分）与有机Al化合物，+ E，crc 2 + EE反应产物，通过卤化镁，通式Me（OR）nXz- n和Ti.V组分（任选组分），并进一步使上述+ E，crc 1 + EE和+ E，crc 2 + EE与+ E，crc 3 + EE的反应产物与通式RpSi （OR）qX4-pq。

10. 发明授权

US5502125A Process for preparing ethylene copolymers 失效
标题翻译：制备乙烯共聚物的方法
公开(公告)号：US5502125A
公开(公告)日：1996-03-26
申请号：US401975
申请日：1995-03-10
申请人： Radu Bordeianu , Christoph Theis
发明人： Radu Bordeianu , Christoph Theis
IPC分类号： C08F210/02 , C08F2/04 , C08F2/06 , C08F4/60 , C08F4/639 , C08F4/68 , C08F10/00 , C08F210/00 , C08F210/18 , C08F4/685
CPC分类号： C08F10/00
摘要： An olefin copolymer is prepared by copolymerizing ethylene, an .alpha.-olefin and, optionally a diene having non-conjugated double bonds by solution polymerization in the presence of:(a) an organoaluminum compound,(b) a vanadium compound in the oxidation state from +3 to +5, and(c) an activator in a molar ratio of from 0.5 to 100 relative to vanadium of said vanadium compound, and an activator of a 2-halomalonic ester substituted by an aromatic group and having the formula ##STR1## wherein X=F, Cl, Br or I, Ar is an aromatic radical which is unsubstituted, monosubstituted or polysubstituted by alkyl or alkoxy groups and which is bound to the central carbon atom either directly or by an intervening carbonyl group; and R.sub.1 and R.sub.2 are hydrocarbon radicals having from 1 to 20 carbon atoms.
摘要翻译：烯烃共聚物通过在以下存在下共聚合乙烯，α-烯烃和任选具有非共轭双键的二烯：（a）有机铝化合物，（b）氧化态的钒化合物， +3至+5，和（c）相对于所述钒化合物的钒，摩尔比为0.5至100的活化剂和由芳基取代的具有下式的化合物的2-卤代马来酸酯的活化剂：其中X = F，Cl，Br或I，Ar是未被取代的，被烷基或烷氧基单取代或多取代并且直接或通过中间羰基结合到中心碳原子上的芳族基团; 并且R 1和R 2是具有1至20个碳原子的烃基。

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