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    • 7. 发明授权
    • Polymerizable liquid crystal composition
    • 可聚合液晶组合物
    • US07560146B2
    • 2009-07-14
    • US11882110
    • 2007-07-30
    • Kazumi HagiharaSeiki MitaniRyushi Shundo
    • Kazumi HagiharaSeiki MitaniRyushi Shundo
    • C09K19/20C09K19/34C09K19/32C09K19/12C09K19/38G02B5/30
    • C09K19/582C09K19/3411C09K19/38C09K19/52C09K2019/0448C09K2019/323C09K2019/3416Y10T428/10
    • A polymerizable liquid crystal composition excellent in storage stability and UV curing property and a polymer thereof are provided. The polymerizable liquid crystal composition contains a compound represented by formula (1) as a component (A), an optically active compound represented by formula (2) as a component (B), and a mixture of a photopolymerization initiator and a photosensitizer as a component (C), and a ratio of the component (A) is from 77 to 98% by weight, a ratio of the component (B) is from 1 to 15% by weight, and a ratio of the component (C) is from 1 to 8% by weight, based on a total weight of the composition: wherein Z independently represents a single bond or alkylene having from 1 to 10 carbon atoms; Y1 independently represents a single bond or —O—; R1 represents methyl or ethyl; A1 and A2 each independently represents 1,4-phenylene or 4,4′-biphenylene; Y2 represents —COO— or —OCO—; Q represents a single bond or oxyalkylene having from 1 to 10 carbon atoms; and p represents 0 or 1.
    • 提供了保存稳定性和UV固化性优异的聚合性液晶组合物及其聚合物。 可聚合液晶组合物含有作为组分(A)的由式(1)表示的化合物,作为组分(B)的由式(2)表示的光学活性化合物,以及光聚合引发剂和光敏剂作为 成分(C),成分(A)的比例为77〜98重量%,成分(B)的比例为1〜15重量%,成分(C)的比例为 1至8重量%,基于组合物的总重量:其中Z独立地表示单键或具有1至10个碳原子的亚烷基; Y1独立地表示单键或-O-; R1代表甲基或乙基; A1和A2各自独立地表示1,4-亚苯基或4,4'-亚联苯; Y2表示-COO-或-OCO-; Q表示具有1至10个碳原子的单键或氧化烯; p表示0或1。
    • 8. 发明授权
    • Polymerizable liquid crystal composition and optically anisotropic thin film
    • 可聚合液晶组合物和光学各向异性薄膜
    • US07378135B2
    • 2008-05-27
    • US11391194
    • 2006-03-29
    • Kazuhiko SaigusaMaiko ItoRyushi Shundo
    • Kazuhiko SaigusaMaiko ItoRyushi Shundo
    • C09K19/32C09K19/20C09K19/38
    • C09K19/32C09K19/3861C09K2019/0448C09K2219/03G02B5/3016Y10T428/10Y10T428/1036Y10T428/1041
    • In order to obtain such a liquid crystal thin film having optical anisotropy that suffers less change in optical characteristics thereof under heating to 200° C., the following polymerizable liquid crystal composition is provided as a raw material therefor. The composition contains Compound (1) and at least one of Compound (2) and Compound (3), with a proportion of Compound (1) being from 50 to 99% by weight, a proportion of Compound (2) being from 0 to 50% by weight, and a proportion of Compound (3) being from 0 to 50% by weight: wherein R is alkyl; each of W1 and W2 is independently hydrogen, chlorine, fluorine or —CH3; each of W3 and W4 is independently hydrogen, chlorine, fluorine, —CH3 or —CF3; W5 is alkyl having, alkoxy, chlorine, fluorine, —CN or —OCF3; X is a single bond, —CH═CH— or —CH2CH2—; Z is a single bond, —COO—, —OCO— or —CH2CH2—; and q is an integer of from 1 to 20.
    • 为了得到这样的具有光学各向异性的液晶薄膜,在加热至200℃时光学特性变化较小,提供以下可聚合液晶组合物作为原料。 组合物含有化合物(1)和化合物(2)和化合物(3)中的至少一种,化合物(1)的比例为50-99重量%,化合物(2)的比例为0〜 50重量%,化合物(3)的比例为0〜50重量%:其中R为烷基; W 1和W 2各自独立地是氢,氯,氟或-CH 3; W 3和W 4中的每一个独立地是氢,氯,氟,-CH 3或-CF 3 ; W 5是具有烷氧基,氯,氟,-CN或-OCF 3 N的烷基; X是单键,-CH-CH-或-CH 2 CH 2 - 。 Z是单键,-COO - , - OCO-或-CH 2 CH 2 - 。 q为1〜20的整数。
    • 10. 发明申请
    • Polymerizable liquid crystal composition
    • 可聚合液晶组合物
    • US20080029734A1
    • 2008-02-07
    • US11882110
    • 2007-07-30
    • Kazumi HagiharaSeiki MitaniRyushi Shundo
    • Kazumi HagiharaSeiki MitaniRyushi Shundo
    • C09K19/52
    • C09K19/582C09K19/3411C09K19/38C09K19/52C09K2019/0448C09K2019/323C09K2019/3416Y10T428/10
    • A polymerizable liquid crystal composition excellent in storage stability and UV curing property and a polymer thereof are provided. The polymerizable liquid crystal composition contains a compound represented by formula (1) as a component (A), an optically active compound represented by formula (2) as a component (B), and a mixture of a photopolymerization initiator and a photosensitizer as a component (C), and a ratio of the component (A) is from 77 to 98% by weight, a ratio of the component (B) is from 1 to 15% by weight, and a ratio of the component (C) is from 1 to 8% by weight, based on a total weight of the composition: wherein Z independently represents a single bond or alkylene having from 1 to 10 carbon atoms; Y1 independently represents a single bond or —O—; R1 represents methyl or ethyl; A1 and A2 each independently represents 1,4-phenylene or 4,4′-biphenylene; Y2 represents —COO— or —OCO—; Q represents a single bond or oxyalkylene having from 1 to 10 carbon atoms; and p represents 0 or 1.
    • 提供了保存稳定性和UV固化性优异的聚合性液晶组合物及其聚合物。 可聚合液晶组合物含有作为组分(A)的由式(1)表示的化合物,作为组分(B)的由式(2)表示的光学活性化合物,以及光聚合引发剂和光敏剂作为 成分(C),成分(A)的比例为77〜98重量%,成分(B)的比例为1〜15重量%,成分(C)的比例为 1至8重量%,基于组合物的总重量:其中Z独立地表示单键或具有1至10个碳原子的亚烷基; Y 1独立地表示单键或-O-; R 1表示甲基或乙基; A 1和A 2各自独立地表示1,4-亚苯基或4,4'-亚联苯; Y 2表示-COO-或-OCO-; Q表示具有1至10个碳原子的单键或氧化烯; p表示0或1。