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1. 发明申请

US20130115469A1 CURABLE RESIN COMPOSITION FOR HARD COAT LAYER, METHOD FOR PRODUCING HARD COAT FILM, HARD COAT FILM, POLARIZING PLATE AND DISPLAY PANEL 审中-公开
标题翻译：用于硬涂层的可固化树脂组合物，用于生产硬涂膜的方法，硬涂膜，偏光板和显示面板
公开(公告)号：US20130115469A1
公开(公告)日：2013-05-09
申请号：US13809959
申请日：2011-08-04
申请人： Yusuke Hayashi , Tomoyuki Horio , Seiji Shinohara
发明人： Yusuke Hayashi , Tomoyuki Horio , Seiji Shinohara
IPC分类号： C09D7/12 , B32B23/08 , G02B5/30
CPC分类号： G02B5/30 , B32B23/08 , C08J7/047 , C08J2301/12 , C09D7/61 , C09D7/68 , G02B5/3033
摘要： Disclosed is a hard coat film having high hardness, sufficient anti-blocking property, low haze, and high total light transmittance. A curable resin composition for a hard coat layer comprises: (A) reactive silica particle with a photocurable group on the surface and average primary particle diameter of 10 to 100 nm, (B) slipping agent with average primary particle diameter of 100 to 300 nm, (C) secondary particle containing agent (B) with average secondary particle diameter of 500 to 2,000 nm, (D) multifunctional monomer with molecular weight of 1,000 or less having, in a molecule, two or more reactive functional groups crosslinkable with the photocurable group of particle (A), and (E) solvent, the composition containing no secondary particle with average secondary particle diameter more than 2,000 nm, and 0.2 to 8% by mass of agent (B) to the total mass of particle (A) and monomer (D).
摘要翻译：公开了具有高硬度，足够的防粘连性，低雾度和高总透光率的硬涂膜。硬涂层用固化性树脂组合物包括：（A）表面具有光固化性基团的反应性二氧化硅粒子，平均一次粒径为10〜100nm，（B）平均一次粒径为100〜300nm的滑爽剂，（C）平均二次粒径为500〜2000nm的二次粒子容纳剂（B），（D）分子量为1000以下的多官能单体，分子中具有与光固化性交联的2个以上的反应性官能团粒子（A）和（E）溶剂组合，不含不饱和二次粒子直径大于2000nm的二次粒子，和（B）粒子相对于粒子总量的比例为0.2〜8质量％和单体（D）。

2. 发明授权

US10073195B2 Optical layered body, polarizer and image display device 有权
公开(公告)号：US10073195B2
公开(公告)日：2018-09-11
申请号：US13876952
申请日：2011-09-21
申请人： Tomoyuki Horio
发明人： Tomoyuki Horio
IPC分类号： G02B1/14 , G02B1/18 , G02B1/10 , G02B27/00
CPC分类号： G02B1/14 , G02B1/10 , G02B1/105 , G02B1/18 , G02B27/0006 , G02B2207/101 , Y10T428/259
摘要： An optical layered body has a light-transmitting substrate and a hard coat layer formed on the light-transmitting substrate. The hard coat layer contains reactive irregularly shaped silica fine particles and a binder resin. The reactive irregularly shaped silica fine particles are unevenly distributed at the side of the light-transmitting substrate in the hard coat layer. The hard coat layer can be divided in its thickness direction into three equal regions (1)-(3), in an order from the interface on the side of the light-transmitting substrate. Ratios of reactive irregularly shaped silica fine particles in the regions (1)-(3) are 30 to 90% in area, 25 to 80% in area, and 10 to 35% in area, respectively. The ratios satisfy the following relationship: the ratio of the region (1)>the ratio of the region (2)>the ratio of the region (3).

3. 发明授权

US09291745B2 Optical laminated body 有权
标题翻译：光学层压体
公开(公告)号：US09291745B2
公开(公告)日：2016-03-22
申请号：US12294706
申请日：2007-03-28
申请人： Masataka Nakashima , Yoko Kinoshita , Tomoyuki Horio
发明人： Masataka Nakashima , Yoko Kinoshita , Tomoyuki Horio
IPC分类号： G02B27/28 , B32B3/00 , G02B1/10 , B32B3/30 , B32B27/28 , G02B1/11 , G02F1/1335
CPC分类号： G02B1/16 , B32B3/30 , B32B27/28 , G02B1/10 , G02B1/11 , G02F1/133502 , G02F2202/22 , Y10T428/24612
摘要： The present invention discloses an antistatic optical laminate. The optical laminate comprises a light transparent base material and at least an antistatic layer provided on the light transparent base material, where the antistatic layer comprises an electroconductive polymer as an antistatic agent. Further, the surface of the antistatic layer has a concavoconvex shape, and the height of convexes in the antistatic layer are not less than 40 nm and not more than 300 nm.
摘要翻译：本发明公开了一种抗静电光学层叠体。光学层叠体包括透光基材和至少设置在透光基材上的抗静电层，其中抗静电层包含作为抗静电剂的导电聚合物。此外，抗静电层的表面具有凹凸形状，并且抗静电层中的凸起的高度不小于40nm且不大于300nm。

4. 发明授权

US09284426B2 Hard coat film and curable resin composition for hard coat layer 有权
标题翻译：用于硬涂层的硬涂膜和可固化树脂组合物
公开(公告)号：US09284426B2
公开(公告)日：2016-03-15
申请号：US12580406
申请日：2009-10-16
申请人： Tomoyuki Horio , Takashi Kuroda , Emi Shimano , Kana Yamamoto , Yoshiko Kiyohara , Keiko Tasaki
发明人： Tomoyuki Horio , Takashi Kuroda , Emi Shimano , Kana Yamamoto , Yoshiko Kiyohara , Keiko Tasaki
IPC分类号： B32B5/16 , C08K3/34 , C08J7/04
CPC分类号： C08J7/047 , C08J2301/12 , C08J2433/00 , Y10T428/259
摘要： A curable resin composition for a hard coat layer capable of forming a hard coat layer having high hardness even with thin thickness and/or excellent in abrasion resistance and hardness, and a hard coat film using the curable resin composition.
摘要翻译：能够形成硬度均匀且硬度高，耐磨耗性和硬度优异的硬涂层的硬涂层用固化性树脂组合物和使用该固化性树脂组合物的硬涂膜。

5. 发明申请

US20130273354A1 OPTICAL LAYERED BODY, POLARIZER AND IMAGE DISPLAY DEVICE 审中-公开
标题翻译：光学层状物体，偏振片和图像显示装置
公开(公告)号：US20130273354A1
公开(公告)日：2013-10-17
申请号：US13876952
申请日：2011-09-21
申请人： Tomoyuki Horio
发明人： Tomoyuki Horio
IPC分类号： G02B1/10
CPC分类号： G02B1/14 , G02B1/10 , G02B1/105 , G02B1/18 , G02B27/0006 , G02B2207/101 , Y10T428/259
摘要： The present invention provides an optical layered body which has a hard coat layer with a high hardness, which can sufficiently exert the properties owing to addition of a small amount of an antifouling agent and the like, and which leads to, in the case that an optically functional layer such as a low refractive index layer is laminated on the upper surface of the hard coat layer, excellent adhesion between the optically functional layer and the hard coat layer. The optical layered body comprises a light-transmitting substrate and a hard coat layer formed on the substrate. The hard coat layer contains reactive irregularly shaped silica fine particles and a binder resin. The reactive irregularly shaped silica fine particles are unevenly distributed at the side of the light-transmitting substrate in the hard coat layer. The hard coat layer is divided in its thickness direction into three equal regions, a region (1), a region (2), and a region (3) in the order from the interface on the side of the light-transmitting substrate. The reactive irregularly shaped silica fine particles in the region (1) exhibits a ratio of 30 to 90% in area; the reactive irregularly shaped silica fine particles in the region (2) exhibits a ratio of 25 to 80% in area; and the reactive irregularly shaped silica fine particles in the region (3) exhibits a ratio of 10 to 35% in ratio. The regions (1), (2), and (3) satisfy the following relationship: the ratio in area of the reactive irregularly shaped silica fine particles in the region (1)≧ the ratio in area of the reactive irregularly shaped silica fine particles in the region (2)> the ratio in area of the reactive irregularly shaped silica fine particles in the region (3).
摘要翻译：本发明提供一种光学层叠体，其具有硬度高的硬涂层，由于添加少量防污剂等，能够充分发挥其特性，导致在诸如低折射率层的光学功能层层压在硬涂层的上表面上，光学功能层和硬涂层之间的粘合性优异。光学层叠体包括透光性基板和形成在基板上的硬涂层。硬涂层含有反应性不规则形状的二氧化硅细颗粒和粘合剂树脂。反应性不规则形状的二氧化硅细颗粒在硬涂层中的透光性基板侧不均匀地分布。硬涂层的厚度方向从透光性基板一侧的界面依次分割为3个相等的区域（1），区域（2）和区域（3）。区域（1）中的反应性不规则形状的二氧化硅细颗粒的面积比例为30至90％; 区域（2）中的反应性不规则形状的二氧化硅细颗粒的面积比例为25至80％; 区域（3）中的反应性不规则形状的二氧化硅细颗粒的比例为10〜35％。区域（1），（2）和（3）满足以下关系：区域（1）中的反应性不规则形状的二氧化硅细颗粒的面积比=反应性不规则形状的二氧化硅的面积比区域（2）中的颗粒>区域（3）中的反应性不规则形状的二氧化硅细颗粒的面积比。

6. 发明授权

US07947341B2 Optical laminated body 有权
标题翻译：光学层压体
公开(公告)号：US07947341B2
公开(公告)日：2011-05-24
申请号：US11885715
申请日：2006-03-15
申请人： Norinaga Nakamura , Tomoyuki Horio
发明人： Norinaga Nakamura , Tomoyuki Horio
IPC分类号： C09K19/00
CPC分类号： G02B1/11 , B32B27/00 , G02B1/10 , G02B1/105 , G02B1/14 , Y10T428/10
摘要： An optical laminate is provided which effectively prevents the occurrence of interface reflection and interference infringes by eliminating the interface between a light transparent base material and a hard coat layer. The optical laminate includes a light transparent base material, and an optical modulating layer and a hard coat layer provided on the light transparent base material, in that order. The optical modulating layer includes a component constituting the light transparent base material and a component constituting the hard coat layer.
摘要翻译：提供了一种光学层压板，其通过消除光透明基材和硬涂层之间的界面而有效地防止了界面反射和干涉的发生。光学层叠体依次具有透光性基材，光透过性基材上的光学调制层和硬涂层。光调制层包括构成透光性基材的成分和构成硬涂层的成分。

7. 发明授权

US09046645B2 Antireflection film, method for producing antireflection film, polarizer and image display device 有权
标题翻译：防反射膜，防反射膜的制造方法，偏振片和图像显示装置
公开(公告)号：US09046645B2
公开(公告)日：2015-06-02
申请号：US13979572
申请日：2012-01-16
申请人： Mariko Hayashi , Tomoyuki Horio , Yoshihiro Nishimura , Yuya Inomata , Hiroshi Nakamura , Mayu Youki
发明人： Mariko Hayashi , Tomoyuki Horio , Yoshihiro Nishimura , Yuya Inomata , Hiroshi Nakamura , Mayu Youki
IPC分类号： G02B27/00 , G02B5/30 , C09K19/00 , C08J7/18 , G02F1/1335 , G02B1/04 , C08J5/24 , C03C21/00 , C08L63/00 , C08L1/10 , C08K5/523 , C08J5/18
CPC分类号： G02B1/111 , C03C21/002 , C08J5/18 , C08J5/24 , C08J2300/20 , C08J2333/08 , C08K5/523 , C08L1/10 , C08L63/00 , C08L2205/02 , G02B1/04 , G02B5/3033 , G02B5/305 , G02B27/0006 , G02F1/1335 , G02F1/133502
摘要： The claimed invention provides an antireflection film including a light-transmitting substrate, a hard coat layer, and a low-refractive-index layer, the hard coat layer and the low-refractive-index layer being formed on the light-transmitting substrate, the low-refractive-index layer including a (meth)acrylic resin, hollow silica particles, reactive silica particles, and two kinds of antifouling agents, the hollow silica particles having an average particle size of 40 to 80 nm and a blending ratio to the (meth)acrylic resin, represented by a ratio: Amount of hollow silica particles/Amount of (meth)acrylic resin, of 0.9 to 1.4, the amount of the reactive silica particles being 5 to 60 parts by mass based on 100 parts by mass of the (meth) acrylic resin, the antifouling agents including an antifouling agent that contains a fluorine compound and an antifouling agent that contains a fluoro-silicone compound.
摘要翻译：所要求保护的发明提供了一种抗反射膜，其包括透光基板，硬涂层和低折射率层，硬涂层和低折射率层形成在透光基板上，包含（甲基）丙烯酸树脂，中空二氧化硅颗粒，反应性二氧化硅颗粒和两种防污剂的低折射率层，平均粒径为40至80nm的中空二氧化硅颗粒和与（甲基）丙烯酸树脂，以中空二氧化硅颗粒的量/（甲基）丙烯酸树脂的量为0.9〜1.4，相对于100质量份的反应性二氧化硅颗粒的量为5〜60质量份（甲基）丙烯酸树脂，防污剂包括含氟化合物的防污剂和含氟硅氧烷化合物的防污剂。

8. 发明申请

US20100167068A1 OPTICAL LAYERED BODY, METHOD OF PRODUCING THE SAME, POLARIZER AND IMAGE DISPLAY DEVICE 有权
标题翻译：光学层状物体，其制造方法，偏振片和图像显示装置
公开(公告)号：US20100167068A1
公开(公告)日：2010-07-01
申请号：US12553271
申请日：2009-09-03
申请人： Tomoyuki Horio
发明人： Tomoyuki Horio
IPC分类号： B32B9/04 , B05D5/06
CPC分类号： G02B1/04 , G02B5/3041
摘要： It is an object of the present invention to provide an optical layered body, which has a high hardness and a fine external appearance without an interference fringe, and is excellent in optical properties and in an adhesion property between a substrate and a hard coat layer.An optical layered body comprising: a light-transmitting substrate; and a hard coat layer, wherein the light-transmitting substrate is made of triacetyl cellulose, the hard coat layer is a resin layer formed with a composition for forming a hard coat layer containing colloidal silica, a solvent, and pentaerythritol tri(meth)acrylate and/or dipentaerythritol hexa(meth)acrylate, an amount of the pentaerythritol tri(meth)acrylate and/or dipentaerythritol hexa(meth)acrylate is 25% by mass or more in 100% by mass of a resin solid content in the composition for forming a hard coat layer, an amount of the colloidal silica is 30 to 70% by mass in 100% by mass of a total of the colloidal silica and the resin solid content in the composition for forming a hard coat layer, and the solvent consists of solvents impermeable to the light-transmitting substrate.
摘要翻译：本发明的目的是提供一种光学层叠体，其具有高硬度和外观细腻而没有干涉条纹，并且具有优异的光学性能和基材与硬涂层之间的粘合性能。一种光学层叠体，包括：透光基板; 和硬涂层，其中透光性基材由三乙酰纤维素制成，硬涂层是由用于形成含有胶体二氧化硅，溶剂和季戊四醇三（甲基）丙烯酸酯的硬涂层的组合物形成的树脂层和/或二季戊四醇六（甲基）丙烯酸酯，所述季戊四醇三（甲基）丙烯酸酯和/或二季戊四醇六（甲基）丙烯酸酯的含量相对于100质量％的树脂固含量为25质量％形成硬涂层时，胶体二氧化硅的量相对于形成硬涂层的组合物中的胶体二氧化硅总量的100质量％和树脂固体成分为30〜70质量％，溶剂为的透光基底不可渗透的溶剂。

9. 发明申请

US20100067109A1 Optical layered body, polarizer and image display device 有权
标题翻译：光学层叠体，偏振片和图像显示装置
公开(公告)号：US20100067109A1
公开(公告)日：2010-03-18
申请号：US12585135
申请日：2009-09-04
申请人： Tomoyuki Horio , Markio Hayashi , Kiyotaka Matsui
发明人： Tomoyuki Horio , Markio Hayashi , Kiyotaka Matsui
IPC分类号： G02B1/08 , G02B5/30 , B32B5/16
CPC分类号： G02B1/111 , G02B5/3033 , Y10T428/249987 , Y10T428/259 , Y10T428/3154
摘要： The present invention has its object to provide an optical layered body having sufficient hardness and an even surface, including a low refractive index layer having a sufficiently low refractive index, and having excellent antireflection properties.An optical layered body of the present invention comprises: at least a low refractive index layer on a light-transmitting substrate, wherein said low refractive index layer is formed by using a composition for a low refractive index layer, said composition comprising a hollow silica fine particle and an organic binder, said organic binder containing: a fluorine atom-free polyfunctional monomer having three or more reactive functional groups in one molecule; a fluorine atom-containing monomer; and a fluorine atom-containing polymer.
摘要翻译：本发明的目的是提供一种具有足够的硬度和均匀的表面的光学层叠体，包括具有足够低的折射率的低折射率层，并且具有优异的抗反射性能。本发明的光学层叠体包括：至少在透光性基板上的低折射率层，其中通过使用低折射率层组合物形成所述低折射率层，所述组合物包含中空二氧化硅细所述有机粘合剂含有：在一个分子中具有三个或更多个反应性官能团的无氟原子的多官能单体; 含氟原子的单体; 和含氟原子的聚合物。

10. 发明申请

US20100020398A1 OPTICAL LAMINATE COMPRISING LOW-REFRACTIVE INDEX LAYER 有权
标题翻译：包含低折射指数层的光学层压板
公开(公告)号：US20100020398A1
公开(公告)日：2010-01-28
申请号：US12294694
申请日：2007-03-28
申请人： Tomoyuki Horio , Hiroaki Omori
发明人： Tomoyuki Horio , Hiroaki Omori
IPC分类号： G02B1/11 , B32B9/00
CPC分类号： G02B1/18 , C08J7/042 , C08J2301/12 , C08J2467/07 , C08J2475/16 , G02B1/11 , G02B1/14 , G02B1/16 , G02B27/0006 , G02F1/133528 , G02F2001/133311 , G02F2201/50 , Y10T428/31504 , Y10T428/31511 , Y10T428/31533 , Y10T428/31551 , Y10T428/31663 , Y10T428/31667 , Y10T428/31935
摘要： The present invention discloses an optical laminate comprising a light-transparent base material and a low-refractive index layer provided on the light-transparent base material, the low-refractive index layer simultaneously having both contamination preventive properties and slipperiness. The optical laminate comprises a light-transparent base material, and a hard coat layer and a low-refractive index layer provided in that order on the light-transparent base material, wherein the low-refractive index layer contains a contamination preventive agent and/or a slipperiness imparting agent, and contamination preventive agent and/or slipperiness imparting agent are added so that the concentrations of the contamination preventive agent and/or slipperiness imparting agent have a concentration gradient from the surface of the hard coat layer toward the surface of the low-refractive index layer.
摘要翻译：本发明公开了一种光学层叠体，其包含透光基材和设置在透光性基材上的低折射率层，低折射率层同时具有防污性和光滑性。所述光学层叠体包含透光性基材，以及依次设置在所述透光性基材上的硬涂层和低折射率层，其中，所述低折射率层含有防污染剂和/或添加润滑剂赋予剂，污染防止剂和/或滑爽性赋予剂，使得防污剂和/或滑爽性赋予剂的浓度从硬涂层的表面朝向低表面的浓度梯度折射率层。

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