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    • 3. 发明申请
    • Vinylhydrogenpolysiloxane Adhesive Composition
    • 乙烯基聚硅氧烷粘合剂组合物
    • US20120045629A1
    • 2012-02-23
    • US13318747
    • 2010-04-06
    • Nathan GreerMarilyn ShopeMichitaka SutoBianxiao ZhongBizhong Zhu
    • Nathan GreerMarilyn ShopeMichitaka SutoBianxiao ZhongBizhong Zhu
    • B32B3/00C09J183/07
    • C08G77/20B32B17/10B32B27/28B32B2383/00C08G77/12Y10T428/24802
    • Vinylhydrogenpolysiloxanes are provided. The vinylhydrogenpolysiloxanes comprise organopolysiloxanes having at least two silicon-bonded hydrogen atoms and at least two silicon-bonded vinyl groups. As a fraction of the total number of silicon atoms in the vinylhydrogenpolysiloxanes, about 25% to about 90% of the silicon atoms are bonded to a hydrogen atom and about 10% to about 45% are bonded to a vinyl group. The ratio of the number of silicon-bonded hydrogen groups to the number of silicon-bonded vinyl groups is about 1.3 to about 6. Also provided are silicone compositions comprising at least one vinylhydrogenpolysiloxane and a hydrosilylation catalyst; silicone adhesives comprising a cured product of at least one vinylhydrogenpolysiloxane; and laminates comprising at least one such silicone adhesive. When subjected to high temperatures or direct flame, the vinylhydrogenpolysiloxanes form chars that retain adhesion to various substrates.
    • 提供乙烯基聚硅氧烷。 乙烯基氢聚硅氧烷包括具有至少两个与硅键合的氢原子和至少两个与硅键合的乙烯基的有机聚硅氧烷。 作为乙烯基氢聚硅氧烷中硅原子总数的一部分,约25%至约90%的硅原子与氢原子结合,约10%至约45%与乙烯基结合。 与硅键合的乙烯基基团的数量的比例为约1.3至约6.还提供了包含至少一种乙烯基氢聚硅氧烷和氢化硅烷化催化剂的硅氧烷组合物; 包含至少一种乙烯基氢聚硅氧烷的固化产物的硅氧烷粘合剂; 以及包含至少一种这种硅氧烷粘合剂的层压材料。 当经受高温或直接火焰时,乙烯基氢聚硅氧烷形成保留对各种基材的粘合性的炭。
    • 4. 发明授权
    • Nanoporous silicone resins having low dielectric constants and method for preparation
    • 具有低介电常数的纳米多孔硅树脂及其制备方法
    • US06313045B1
    • 2001-11-06
    • US09459331
    • 1999-12-13
    • Bianxiao ZhongRussell Keith KingKyuha ChungShizhong Zhang
    • Bianxiao ZhongRussell Keith KingKyuha ChungShizhong Zhang
    • H01L2131
    • C08G77/02C08G77/12C09D183/04Y10S977/70Y10S977/831Y10S977/891
    • Nanoporous silicone resins and silicone resin films having low dielectric constants and a method for preparing such nanoporous silicone resins. The silicone resin comprises the reaction product of a mixture comprising (A) 15-70 mol % of a tetraalkoxysilane described by formula Si(OR1)4,  where each R1 is an independently selected alkyl group comprising 1 to about 6 carbon atoms, (B) 12 to 60 mol % of an organosilane described by formula R4SiX3,  where R4 is selected from the group consisting of alkyl groups comprising 1 to about 6 carbon atoms and phenyl and each X is an independently selected hydrolyzable substituent, (C) 15 to 70 mol % of an organotrialkoxysilane described by formula R2Si(OR3)3,  where R2 is a hydrocarbon group comprising about 8 to 24 carbon atoms or a substituted hydrocarbon group comprising a hydrocarbon chain having about 8 to 24 carbon atoms and each R3 is an independently selected alkyl group comprising 1 to about 6 carbon atoms; in the presence of (D) water, (E) hydrolysis catalyst, and (F) organic solvent for the reaction product. The silicone resin is cured and heated in preferably an inert atmosphere at a temperature sufficient to effect thermolysis of carbon-carbon bonds of the R2 groups thereby forming a nanoporous silicone resin.
    • 具有低介电常数的纳米多孔有机硅树脂和有机硅树脂薄膜以及这种纳米多孔硅树脂的制备方法。 硅氧烷树脂包括含有(A)15-70mol%四烷氧基硅烷的混合物的反应产物,其中R1是独立选择的含有1至约6个碳原子的烷基,(B)12至60mol% 的式中R 4选自包含1至约6个碳原子的烷基和苯基,并且每个X是独立选择的可水解取代基的有机硅烷,(C)15至70mol%由式(I)表示的有机基三烷氧基硅烷 其中R 2是包含约8至24个碳原子的烃基或包含具有约8至24个碳原子的烃链的取代烃基,并且每个R 3是独立选择的包含1至约6个碳原子的烷基; 在(D)水,(E)水解催化剂和(F)反应产物的(F)有机溶剂的存在下)。有机硅树脂在优选惰性气氛中在足以实现碳 - 碳键热解的温度下固化和加热 的R2基团,从而形成纳米多孔硅树脂。
    • 7. 发明授权
    • Nanoporous silicone resins having low dielectric constants
    • 具有低介电常数的纳米多孔硅树脂
    • US06541107B1
    • 2003-04-01
    • US09425901
    • 1999-10-25
    • Bianxiao ZhongRussell Keith KingKyuha ChungShizhong Zhang
    • Bianxiao ZhongRussell Keith KingKyuha ChungShizhong Zhang
    • B32B326
    • C08G77/12C08G77/02C09D183/04Y10T428/249969Y10T428/249978Y10T428/249979Y10T428/24999
    • Nanoporous silicone resins and silicone resin films having low dielectric constants and a method for preparing such nanoporous silicone resins. The silicone resin comprises the reaction product of a mixture comprising (A) 15-70 mol % of a tetraalkoxysilane described by formula Si(OR1)4,  where each R1 is an independently selected alkyl group comprising 1 to about 6 carbon atoms, (B) 12 to 60 mol % of a hydrosilane described by formula HSiX3,  where each X is an independently selected hydrolyzable substituent, (C) 15 to 70 mole percent of an organotrialkoxysilane described by formula R2Si(OR3)3,  where R2 is a hydrocarbon group comprising about 8 to 24 carbon atoms or a substituted hydrocarbon group comprising a hydrocarbon chain having about 8 to 24 carbon atoms and each R3 is an independently selected alkyl group comprising 1 to about 6 carbon atoms; in the presence of (D) water, (E) hydrolysis catalyst, and (F) organic solvent for the reaction product. The silicone resin is cured and heated in an inert atmosphere at a temperature sufficient to effect thermolysis of carbon-carbon bonds of the R2 groups thereby forming a nanoporous silicone resin.
    • 具有低介电常数的纳米多孔有机硅树脂和有机硅树脂薄膜以及这种纳米多孔硅树脂的制备方法。 硅氧烷树脂包括含有(A)15-70mol%四烷氧基硅烷的混合物的反应产物,其中R1是独立选择的含有1至约6个碳原子的烷基,(B)12至60mol% 的式中其中每个X是独立选择的可水解取代基的氢硅烷,(C)15至70摩尔%的由下式描述的有机基三烷氧基硅烷:其中R 2是包含约8至24个碳原子的烃基或包含 具有约8至24个碳原子的烃链,并且每个R 3是独立选择的包含1至约6个碳原子的烷基; 在(D)水,(E)水解催化剂和(F)反应产物的(F)有机溶剂的存在下,硅氧烷树脂固化并在惰性气氛中加热,温度足以使碳 - 碳键热解 由此形成纳米多孔硅树脂。
    • 10. 发明授权
    • Silicone resin compositions having good solution solubility and stability
    • 具有良好溶液溶解性和稳定性的硅酮树脂组合物
    • US06359096B1
    • 2002-03-19
    • US09425306
    • 1999-10-25
    • Bianxiao ZhongRussell Keith KingKyuha ChungShizhong Zhang
    • Bianxiao ZhongRussell Keith KingKyuha ChungShizhong Zhang
    • C08G7712
    • C08G77/12C08G77/02C09D183/04
    • Soluble silicone resin compositions having good solution stability and a method for their preparation. The silicone resin comprises the reaction product of a mixture comprising (A) 15-70 mol % of a tetraalkoxysilane described by formula Si(OR1)4, where each R1 is an independently selected alkyl group comprising 1 to about 6 carbon atoms, (B) 12 to 60 mol % of a hydrosilane described by formula HSiX3, where each X is an independently selected hydrolyzable substituent, (C) 15 to 70 mole percent of an organotrialkoxysilane described by formula R2Si(OR3)3, where R2 is a hydrocarbon group comprising about 8 to 24 carbon atoms or a substituted hydrocarbon group comprising a hydrocarbon chain having about 8 to 24 carbon atoms and each R3 is an independently selected alkyl group comprising 1 to about 6 carbon atoms; in the presence of (D) water, (E) hydrolysis catalyst, and (F) organic solvent for the reaction product.
    • 具有良好溶液稳定性的可溶性有机硅树脂组合物及其制备方法。 有机硅树脂包括由(A)15-70mol%的四烷氧基硅烷所组成的混合物的反应产物,每个R 1是独立选择的含有1至约6个碳原子的烷基,(B)12至60mol% 由式X表示的氢硅烷,每个X是独立选择的可水解取代基,(C)15-70摩尔%的由通式R 2表示的有机三烷氧基硅烷是包含约8至24个碳原子的烃基或包含烃链的取代烃基, 约8至24个碳原子,并且每个R 3是独立选择的包含1至约6个碳原子的烷基; 在(D)水,(E)水解催化剂和(F)反应产物的有机溶剂的存在下。