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    • 4. 发明授权
    • Oxygen engineered single-crystal REO template
    • 氧气工程单晶REO模板
    • US08636844B1
    • 2014-01-28
    • US13543093
    • 2012-07-06
    • Rytis DargisAndrew ClarkMichael Lebby
    • Rytis DargisAndrew ClarkMichael Lebby
    • C30B25/00
    • H01L21/02381H01L21/02433H01L21/02488H01L21/02502H01L21/02521
    • A method of forming a template on a silicon substrate includes epitaxially growing a template of single crystal ternary rare earth oxide on a silicon substrate and epitaxially growing a single crystal semiconductor active layer on the template. The active layer has either a cubic or a hexagonal crystal structure. During the epitaxial growth of the template, a partial pressure of oxygen is selected and a ratio of metals included in the ternary rare earth oxide is selected to match crystal spacing and structure of the template at a lower interface to the substrate and to match crystal spacing and structure of the template at an upper interface to crystal spacing and structure of the semiconductor active layer. A high oxygen partial pressure during growth of the template produces a stabilized cubic crystal structure and a low oxygen partial pressure produces a predominant peak with a hexagonal crystal structure.
    • 在硅衬底上形成模板的方法包括在硅衬底上外延生长单晶三元稀土氧化物的模板,并在模板上外延生长单晶半导体活性层。 有源层具有立方晶体或六方晶体结构。 在模板的外延生长期间,选择氧的分压,并且选择包含在三元稀土氧化物中的金属的比例以在与衬底的较低界面处的模板的晶体间距和结构相匹配并且匹配晶体间距 以及在半导体活性层的晶体间距和结构的上界面处的模板的结构。 模板生长期间的高氧分压产生稳定的立方晶体结构,低氧分压产生具有六方晶系结构的主峰。
    • 7. 发明授权
    • Thin film solar cell
    • 薄膜太阳能电池
    • US07928317B2
    • 2011-04-19
    • US11788153
    • 2007-04-18
    • Petar B. Atanackovic
    • Petar B. Atanackovic
    • H01L31/00
    • H01L31/06Y02E10/50
    • Optimal structures for high efficiency thin film silicon solar energy conversion devices and systems are disclosed. Thin film silicon active layer photoelectron conversion structures using ion implantation are disclosed. Thin film semiconductor devices optimized for exploiting the high energy and ultraviolet portion of the solar spectrum at the earths surface are also disclosed. Solar cell fabrication using high oxygen concentration single crystal silicon substrates formed using in preference the CZ method are used advantageously. Furthermore, the present invention discloses optical coatings for advantageous coupling of solar radiation into thin film solar cell devices via the use of rare-earth metal oxide (REOx), rare-earth metal oxynitride (REOxNy) and rare-earth metal oxy-phosphide (REOxPy) glasses and or crystalline material. The rare-earth metal is chosen from the group commonly known in the periodic table of elements as the lanthanide series.
    • 公开了用于高效薄膜硅太阳能转换装置和系统的最佳结构。 公开了使用离子注入的薄膜硅有源层光电转换结构。 还公开了为了利用地球表面的太阳光谱的高能量和紫外线部分而优化的薄膜半导体器件。 有利地使用使用优选CZ法形成的高氧浓度单晶硅衬底的太阳能电池制造。 此外,本发明公开了通过使用稀土金属氧化物(REOx),稀土金属氮氧化物(REOxNy)和稀土金属氧化磷(REOxNy)和稀土金属氧化物(REOxNy),将太阳辐射有效地耦合到薄膜太阳能电池器件中的光学涂层 REOxPy)玻璃和/或结晶材料。 稀土金属选自周期表中众所周知的元素作为镧系元素。