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    • 6. 发明授权
    • Methods and apparatus for producing and treating novel elastomer composites
    • 新型弹性体复合材料的生产和处理方法与装置
    • US07582689B2
    • 2009-09-01
    • US11203568
    • 2005-08-12
    • Bin ChungSusan W. GreenIvan Z. PodobnikJoseph Cianciolo
    • Bin ChungSusan W. GreenIvan Z. PodobnikJoseph Cianciolo
    • C09B67/00
    • B29B7/002B29B7/007B29B7/46B29B7/465B29B7/60B29B7/72B29B7/7495B29B15/04B29C47/761C08J3/22
    • Elastomer masterbatch is processed in a continuous compounder having multiple parallel elongate rotors axially oriented in an elongate processing chamber. Optionally, additional materials are compounded into the masterbatch, e.g., additives, other elastomeric compositions, etc. Preferably, the masterbatch then is further processed in an open mill. Excellent control of Mooney Viscosity is achieved.In certain preferred embodiments, elastomer composites are produced by novel continuous flow methods and apparatus in which fluid streams of particulate filler and elastomer latex are fed to the mixing zone of a coagulum reactor to form a coagulated mixture in semi-confined flow continuously from the mixing zone through a coagulum zone to a discharge end of the reactor. The particulate filler fluid is fed under high pressure to the mixing zone, such as to form a jet stream to entrain elastomer latex fluid sufficiently energetically to substantially completely coagulate the elastomer with the particulate filler prior to the discharge end without need of adding acid or salt solution or other coagulation step. The coagulated elastomer and particulate filler composite is fed into the aforesaid continuous compounder for processing and control of its moisture level and Mooney Viscosity. Novel elastomer composites are produced. Such novel elastomer composites combine material properties and characteristics, such as choice of filler, elastomer, level of filler loading, moisture level, Mooney Viscosity, balance between molecular weight and amount of bound rubber, and macro-dispersion not previously achieved.
    • 弹性体母料在具有在细长处理室中轴向取向的多个平行细长转子的连续混合器中加工。 任选地,将另外的材料混合到母料中,例如添加剂,其它弹性体组合物等。优选地,母料在开炼机中进一步加工。 实现门尼粘度的良好控制。 在某些优选实施方案中,通过新颖的连续流动方法和装置制备弹性体复合材料,其中颗粒填料和弹性体胶乳的流体流被输送到凝结物反应器的混合区,以从混合物连续形成半约束流中的凝结混合物 通过凝结区到达反应器的排放端。 颗粒状填充液在高压下进料到混合区,例如形成喷射流以充分力量地夹带弹性体胶乳流体,以在排出端之前用颗粒填料基本上完全凝固弹性体,而不需要加入酸或盐 溶液或其他凝结步骤。 将凝固的弹性体和颗粒填料复合物进料到上述连续混合器中,以加工和控制其水分含量和门尼粘度。 生产新型弹性体复合材料。 这种新型弹性体复合材料结合了材料性质和特性,例如填料,弹性体的选择,填料含量,水分含量,门尼粘度,分子量与结合橡胶量之间的平衡以及以前未达到的宏观分散。