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    • 7. 发明授权
    • Method of making shaped ceramic composites with the use of a barrier
    • 使用屏障制造成型陶瓷复合材料的方法
    • US4923832A
    • 1990-05-08
    • US861024
    • 1986-05-08
    • Marc S. NewkirkRobert C. Kantner
    • Marc S. NewkirkRobert C. Kantner
    • C04B35/10B29C43/10C04B35/565C04B35/622C04B35/65C04B35/71C04B35/80
    • B29C43/10C04B35/652C04B35/71C04B35/80B29C2043/3652B29L2031/7096
    • In the present invention, there is provided a method for producing a self-supporting ceramic or ceramic composite body by the oxidation of a parent metal to form a polycrystalline ceramic material comprising the oxidation reaction product of said parent metal with an oxidant, including a vapor-phase oxidant, and optionally one or more metallic constituents dispersed throughout the polycrystalline ceramic material. The method comprises the steps of providing at least a portion of said parent metal with a barrier means at least partially spaced from said parent metal for establishing at least one surface of the ceramic body, and heating said parent metal to a temperature above its melting point but below the melting point of the oxidation reaction product to form a body of molten metal. At that temperature, the molten metal is reacted with the oxidant, thus forming the oxidation reaction product. At least a portion of the oxidation reaction product is maintained in contact with and between the molten metal and oxidant to transport the molten metal through the oxidation reaction product toward the barrier means and into contact with fresh oxidant so that the oxidation reaction product continues to form at and interface between the oxidant and previously formed oxidation reaction product. The reaction is continued until the oxidation reaction product contacts the barrier means to produce a ceramic body having the surface established by the barrier means. A shaped ceramic composite is formed by superimposing a barrier means either a loose mass of filler material such as a preform to, and infiltrating the mass of filler or preform with the polycrystalline ceramic matrix, which grows until it contacts the barrier means.
    • 在本发明中,提供了一种通过母体金属的氧化制造自支撑陶瓷或陶瓷复合体的方法,以形成多晶陶瓷材料,该多晶陶瓷材料包括所述母体金属的氧化反应产物与氧化剂,包括蒸汽 相氧化剂和任选的一种或多种分散在整个多晶陶瓷材料中的金属成分。 该方法包括以下步骤:使所述母体金属的至少一部分具有与所述母体金属至少部分间隔开的阻挡装置,用于建立陶瓷体的至少一个表面,并将所述母体金属加热到高于其熔点的温度 但低于氧化反应产物的熔点以形成熔融金属体。 在该温度下,熔融金属与氧化剂反应,形成氧化反应产物。 氧化反应产物的至少一部分保持与熔融金属和氧化剂接触并且在熔融金属和氧化剂之间传输熔融金属通过氧化反应产物朝向阻挡装置并与新鲜的氧化剂接触,使得氧化反应产物继续形成 在氧化剂和预先形成的氧化反应产物之间和界面。 反应继续进行,直到氧化反应产物与阻挡装置接触以产生具有通过阻挡装置建立的表面的陶瓷体。 成形陶瓷复合材料通过将阻挡装置或诸如预成型体之类的填充材料的松散材料叠加在多孔陶瓷基体上并将多孔陶瓷基体浸入填料或预成型体中而形成,该多晶陶瓷基体生长直到与阻挡装置接触。