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2. 发明申请

US20160107978A1 METHOD FOR PRODUCING A CONJUGATED Z-ALKEN-YN-YL ACETATE 审中-公开
标题翻译：用于生产连结的Z-阿EN N酸乙酯的方法
公开(公告)号：US20160107978A1
公开(公告)日：2016-04-21
申请号：US14984360
申请日：2015-12-30
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Miyoshi Yamashita , Takehiko Fukumoto , Takeshi Kinsho
IPC分类号： C07C67/10 , C07C17/263 , C07C45/42
CPC分类号： C07C67/10 , C07C17/2635 , C07C45/42 , C07C45/43 , C07C47/24 , C07C67/11 , C07C69/145 , C07C21/22
摘要： Provided is a method for industrially producing a conjugated Z-alken-yn-yl acetate such as Z-13-hexadecen-11-yn-yl acetate which is a sex pheromone component of a pine processionary moth, and an intermediate for the conjugated Z-alken-yn-yl acetate under mild conditions at a high yield. More specifically, provided is a method for producing a conjugated Z-alken-yn-yl acetate (5) comprising the steps of: reacting an ω-halo-2-alkynal (1) with an alkylidene triphenylphosphorane (3) through a Wittig reaction to obtain a conjugated Z-alken-yn-yl halide (4), and acetoxylating the conjugated Z-alken-yn-yl halide (4) into a conjugated Z-alken-yn-yl acetate (5).
摘要翻译：本发明提供了工业上制造Z-联烯基乙酸酯的共轭Z-烯酸乙酯的方法，例如作为松木酰蛾的性信息素成分的Z-13-十六碳烯-11-炔酸乙酯，和共轭Z - 烯酸乙酯在温和条件下以高产率。更具体地说，提供了一种制备共轭Z-烯酸乙酯（5）的方法，包括以下步骤：使ω-卤代-2-炔烃（1）与亚烷基三苯基正膦（3）通过维蒂希反应得到共轭的Z-烯烃基卤化物（4），并将共轭的Z-烯烃基卤化物（4）乙酰氧化成共轭的Z-烯酸乙酯（5）。

3. 发明申请

US20160107969A1 METHOD FOR PRODUCING AN OMEGA-HALO-2-ALKYNAL 审中-公开
标题翻译：生产欧米茄 - 草酸-2-烷基酯的方法
公开(公告)号：US20160107969A1
公开(公告)日：2016-04-21
申请号：US14984343
申请日：2015-12-30
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Miyoshi Yamashita , Takehiko Fukumoto , Takeshi Kinsho
IPC分类号： C07C45/43
CPC分类号： C07C67/10 , C07C17/2635 , C07C45/42 , C07C45/43 , C07C47/24 , C07C67/11 , C07C69/145 , C07C21/22
摘要： Provided is a method for industrially producing a conjugated Z-alken-yn-yl acetate such as Z-13-hexadecen-11-yn-yl acetate which is a sex pheromone component of a pine processionary moth, and an intermediate for the conjugated Z-alken-yn-yl acetate under mild conditions at a high yield. More specifically, provided is a method for producing a conjugated Z-alken-yn-yl acetate (5) comprising the steps of: reacting an ω-halo-2-alkynal (1) with an alkylidene triphenylphosphorane (3) through a Wittig reaction to obtain a conjugated Z-alken-yn-yl halide (4), and acetoxylating the conjugated Z-alken-yn-yl halide (4) into a conjugated Z-alken-yn-yl acetate (5).
摘要翻译：本发明提供了工业上制造Z-联烯基乙酸酯的共轭Z-烯酸乙酯的方法，例如作为松木酰蛾的性信息素成分的Z-13-十六碳烯-11-炔酸乙酯，和共轭Z - 烯酸乙酯在温和条件下以高产率。更具体地说，提供了一种制备共轭Z-烯酸乙酯（5）的方法，包括以下步骤：使ω-卤代-2-炔烃（1）与亚烷基三苯基正膦（3）通过维蒂希反应得到共轭的Z-烯烃基卤化物（4），并将共轭的Z-烯烃基卤化物（4）乙酰氧化成共轭的Z-烯酸乙酯（5）。

4. 发明申请

US20120029211A1 Catalytic Wittig and Mitsunobu Reactions 有权
标题翻译：催化Wittig和Mitsunobu反应
公开(公告)号：US20120029211A1
公开(公告)日：2012-02-02
申请号：US13263224
申请日：2010-04-06
申请人： Christopher J. O'Brien
发明人： Christopher J. O'Brien
IPC分类号： C07D333/24 , C07C1/20 , C07C17/272 , C07C67/40 , C07C67/44 , C07C253/30
CPC分类号： C07C1/34 , C07B37/04 , C07B2200/09 , C07C17/2635 , C07C17/2637 , C07C45/68 , C07C45/72 , C07C67/343 , C07C201/12 , C07C253/30 , C07C2601/14 , C07D333/24 , C07D333/28 , C07F9/509 , C07F9/65683 , C07C205/56 , C07C255/31 , C07C255/34 , C07C255/07 , C07C205/57 , C07C22/08 , C07C69/618 , C07C69/65 , C07C69/533 , C07C69/75 , C07C69/587 , C07C49/796 , C07C15/52 , C07C69/76
摘要： A catalytic Wittig method utilizing a phosphine including the steps of providing a phosphine oxide precatalyst and reducing the phosphine oxide precatalyst to produce the phosphine; forming a phosphonium ylide precursor from the phosphine and a reactant; generating a phosphonium ylide from the phosphonium ylide precursor; reacting the phosphonium ylide precursor with the aldehyde, ketone, or ester to form the olefin and the phosphine oxide which then reenters the cycle. The invention is also directed to a Mitsunobu reaction catalytic in phosphine.
摘要翻译：一种利用磷化氢的催化Wittig方法，包括以下步骤：提供氧化膦预催化剂并还原氧化膦预催化剂以生产磷化氢; 从磷化氢和反应物形成鏻内鎓盐前体; 从onium叶立德前体产生onium叶立德; 使onium叶立德前体与醛，酮或酯反应，形成烯烃和氧化膦，然后再循环循环。本发明还涉及在膦中催化的Mitsunobu反应。

5. 发明申请

US20090179196A1 Pyrene-Based Organic Compound, Transistor Material and Light-Emitting Transistor Device 审中-公开
标题翻译：芘基有机化合物，晶体管材料和发光晶体管器件
公开(公告)号：US20090179196A1
公开(公告)日：2009-07-16
申请号：US12225370
申请日：2007-03-20
申请人： Chihaya Adachi , Takahito Oyamada , Hiroyuki Uchiuzou , Seiji Akiyama , Takayoshi Takahashi , Kumiko Takenouchi , Masaki Shimizu , Tamejiro Hiyama , Etsuya Okamoto
发明人： Chihaya Adachi , Takahito Oyamada , Hiroyuki Uchiuzou , Seiji Akiyama , Takayoshi Takahashi , Kumiko Takenouchi , Masaki Shimizu , Tamejiro Hiyama , Etsuya Okamoto
IPC分类号： H01L51/54 , C07D409/14 , C07D209/86 , C07D409/04 , C07C15/02 , C07C15/12 , C07C15/24 , C07C211/54 , C07D401/04 , C07D213/06 , C07D333/08 , C07D307/36
CPC分类号： C07C17/12 , C07C15/38 , C07C15/62 , C07C17/263 , C07C17/2635 , C07C22/08 , C07C25/24 , C07C45/00 , C07C2603/50 , C07F5/025 , C07F9/4056 , C07F15/0093 , C09K11/06 , C09K2211/1011 , C09K2211/1044 , C09K2211/1074 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H01L51/0054 , H01L51/0558 , H01L51/5012 , H01L51/52 , H01L51/5203 , H01L51/5296 , H05B33/14 , C07C25/22 , C07C47/546
摘要： The object is to provide a light-emitting transistor material which is high in both luminescent property and mobility when used as a light-emitting transistor device.A light-emitting transistor device is provided in which light emission of a specific pyrene-based organic compound is used for a light-emitting layer of a transistor device.
摘要翻译：本发明的目的是提供一种当用作发光晶体管器件时发光特性和迁移率高的发光晶体管材料。提供了一种发光晶体管器件，其中特定芘类有机化合物的发光用于晶体管器件的发光层。

6. 发明申请

US20090062558A1 Process for preparing Estrogen-antagonistic 11 beta-Fluoro-17alpha-alkylestra-1,3,5(10)-triene-3,17-diols having a 7alpha-(xi-Alkylamino-omega-perfluoroalkyl)alkyl side chain and alpha-Alkyl(amino)-omega-perfluoro(alkyl)alkanes and Processes for their Preparation 审中-公开
标题翻译：制备具有7α-（xi-烷基氨基 - ω-全氟烷基）烷基侧链的雌激素 - 拮抗性11β-氟-17α-烷基雌-1,3,5（10） - 三烯-3,17-二醇的方法，烷基（氨基） - 全 - 全氟（烷基）烷烃及其制备方法
公开(公告)号：US20090062558A1
公开(公告)日：2009-03-05
申请号：US12201043
申请日：2008-08-29
申请人： Michael SANDER , Danja Grossbach , Christian Dinter , Jorma Hassfeld , David Voigtlaender
发明人： Michael SANDER , Danja Grossbach , Christian Dinter , Jorma Hassfeld , David Voigtlaender
IPC分类号： C07J1/00 , C07F9/02 , C07C19/08 , C07C211/00
CPC分类号： C07C211/15 , C07C17/208 , C07C17/2635 , C07C21/18 , C07C33/423 , C07C45/29 , C07C45/292 , C07C211/24 , C07C211/29 , C07C309/73 , C07F9/5407 , C07F9/5442 , C07J41/0044 , C07C47/14
摘要： The present invention relates to a new process for preparing estrogen-antagonistic 11β-fluoro-17α-alkylestra-1,3,5(10)-triene-3,17-diols of the general formula I having a 7α-(ξ-alkylamino-ω-perfluoroalkyl)alkyl side chain and to α-alkyl(amino)-ω-perfluoro(alkyl)alkanes of the general formula II, to processes for their preparation and to the intermediates required for this purpose.
摘要翻译：本发明涉及一种制备通式Ⅰ的雌激素 - 拮抗性11β-氟-17α-烷基雌-1,3,5（10） - 三烯-3,17-二醇的新方法，其具有7α-（N-烷基氨基 - 全 - 全氟烷基）烷基侧链和通式II的α-烷基（氨基） - 全 - （全氟（烷基）烷烃），以进行其制备及其所需的中间体。

7. 发明申请

US20050133763A1 Phenylcyclohexanes and a liquid-crystalline medium 失效
公开(公告)号：US20050133763A1
公开(公告)日：2005-06-23
申请号：US11038170
申请日：2005-01-21
申请人： Andreas Wachtler , Reinhard Hittich , Eike Poetsch , Herbert Plach , David Coates , Bernhard Rieger , Joachim Krause
发明人： Andreas Wachtler , Reinhard Hittich , Eike Poetsch , Herbert Plach , David Coates , Bernhard Rieger , Joachim Krause
IPC分类号： C07C17/26 , C07C22/08 , C07C25/13 , C07C25/24 , C07C25/28 , C07C43/225 , C07C255/50 , C09K19/30 , C09K19/42 , G02F1/13 , C09K19/12
CPC分类号： C07C17/2635 , C07C22/08 , C07C25/24 , C07C25/28 , C07C43/225 , C07C255/50 , C07C2601/14 , C09K19/3003 , C09K2019/0444 , Y10T428/10
摘要： Novel phenylcyclohexanes of the formula I in which n is 0 to 7, Q1 and Q2 are H, or one of these radicals is alternatively CH3, r is 0, 1, 2, 3, 4 or 5, A is trans-1,4-cyclohexylene, 1,4-phenylene, 3-fluoro-1,4-phenylene or a single bond, X is F, Cl, —CF3, —CN, —OCF3 or —OCHF2, and Y and Z are each, independently of one another, H or F, with the proviso that, in the case where A is a single bond, Q1=Q2=H and simultaneously X=CN, Y and/or Z are F.

8. 发明申请

US20040260128A1 Solvent-free mechanochemical preparation of phosphonium salts, phosphorus ylides, and olefins 失效
标题翻译：无溶剂的鏻盐，磷内鎓盐和烯烃的机械化学制备
公开(公告)号：US20040260128A1
公开(公告)日：2004-12-23
申请号：US10744932
申请日：2003-12-22
申请人： Iowa State University Research Foundation, Inc.
发明人： Vitalij K. Pecharsky , Viktor P. Balema , Jerzy W. Wiench , Marek Pruski
IPC分类号： C07C005/09 , C07C015/40
CPC分类号： C07C17/2635 , C07C1/34 , C07F9/5352 , C07F9/54 , C07C25/24
摘要： The present invention provides a method of preparing a phosphonium salt of the formula nullR1R2R3PnullCR4R5R6nullX, comprising ball-milling a phosphine of the formula R1R2R3P with a compound of the formula XCR4R5R6; a method of preparing a phosphorus ylide of the formula R1R2R3PnullCR4R5, comprising ball-milling a phosphonium salt of the formula nullR1R2R3PnullHCR4R5nullX in the presence of a base; and a method of preparing an olefin of the formula R4R5CnullCR7H or R4R5CnullCR7R8, comprising ball-milling a phosphorus ylide of the formula R1R2R3PnullCR4R5 with a compound of the formula R7C(O)H or R7C(O)R8. The inventive method produces phosphonium salts and phosphorus ylides by mechanical processing solid reagents under solvent-free conditions. The advantages of the present invention over conventional solution methods, include: (1) extremely high selectivity; (2) high yields; (3) low processing temperatures; (4) simple and scalable reactions using commercially available equipment; and (5) the complete elimination of solvents from the reaction.
摘要翻译：本发明提供了制备式[R 1 R 2 R 3 P-CR 4 R 5 R 6] X的鏻盐的方法，包括将磷化氢式R 1 R 2 R 3与式XCR 4 R 5 R 6的化合物反应; 制备式R 1 R 2 R 3 P = CR 4 R 5的磷叶立德的方法，包括球磨研磨式[R 1 R' 2> R 3 P-HCR 4 R 5] X存在下，以及制备式R 4 R 5 C = CR 7 H或R 4 R 5 C = CR 7 R 8的烯烃的方法，包括球磨a 具有式R 7 C（O）H或R 7 C（O）的化合物的式R 1 R 2 R 3 P = CR 4 R 5的磷叶立德）R 8。本发明的方法通过在无溶剂条件下机械处理固体试剂产生鏻盐和磷内鎓盐。本发明优于常规溶液方法的优点包括：（1）极高的选择性; （2）高收益; （3）加工温度低; （4）使用市售设备的简单且可伸缩的反应; 和（5）从反应中完全消除溶剂。

9. 发明申请

US20020043646A1 Phenylcyclohexanes and a liquid-crystalline medium 失效
标题翻译：苯基环己烷和液晶介质
公开(公告)号：US20020043646A1
公开(公告)日：2002-04-18
申请号：US09964650
申请日：2001-09-28
申请人： MERCK KGAA
发明人： Andreas Wachtler , Reinhard Hittich , Eike Poetsch , Herbert Plach , David Coates , Bernhard Rieger , Joachim Krause
IPC分类号： C09K019/30 , C09K019/12 , C07C025/13
CPC分类号： C07C17/2635 , C07C22/08 , C07C25/24 , C07C25/28 , C07C43/225 , C07C255/50 , C07C2601/14 , C09K19/3003 , C09K2019/0444 , Y10T428/10
摘要： Novel phenylcyclohexanes of the formula I 1 in which n is 0 to 7, Q1 and Q2 are H, or one of these radicals is alternatively CH3, r is 0, 1, 2, 3, 4 or 5, A is trans-1,4-cyclohexylene, 1,4-phenylene, 3-fluoro-1,4-phenylene or a single bond, X is F, Cl, nullCF3, nullCN, nullOCF3 or nullOCHFz1 and Y and Z are each, independently of one another, T or F, with the proviso that, in the case where A is a single bond, Q1nullQ2nullH and simultaneously XnullCN, Y and/or Z are F.
摘要翻译：式I的新型苯基环己烷，其中n为0至7，Q1和Q2为H，或这些基团中的一个为CH 3，r为0,1,2,3,4或5，A为反式-1,4 - 环己烯，1,4-亚苯基，3-氟-1,4-亚苯基或单键，X为F，Cl，-CF 3，-CN，-OCF 3或-OCHFz1，Y和Z各自独立地为另一个T或F，条件是在A为单键的情况下，Q1 = Q2 = H，同时X = CN，Y和/或Z为F.

10. 发明授权

US06254941B1 Fluoroalkylated liquid-crystal compounds, liquid-crystal compositions, and liquid-crystal display elements 有权
标题翻译：氟烷基化液晶化合物，液晶组合物和液晶显示元件
公开(公告)号：US06254941B1
公开(公告)日：2001-07-03
申请号：US09269286
申请日：1999-03-25
申请人： Tomoyuki Kondou , Shuichi Matsui , Kazutoshi Miyazawa , Hiroyuki Takeuchi , Yasuhiro Kubo , Fusayuki Takeshita , Etsuo Nakagawa
发明人： Tomoyuki Kondou , Shuichi Matsui , Kazutoshi Miyazawa , Hiroyuki Takeuchi , Yasuhiro Kubo , Fusayuki Takeshita , Etsuo Nakagawa
IPC分类号： C09K1912
CPC分类号： C07C17/12 , C07C17/263 , C07C17/2635 , C07C17/361 , C07C25/18 , C07C43/174 , C07C43/225 , C09K19/12 , C09K19/14 , C09K19/20 , C09K2019/124 , Y10T428/10 , C07C25/13
摘要： The present invention provides liquid crystalline compounds having a very high voltage holding ratio, very little variation of these properties depending on temperature, high &Dgr;n, and good compatibility in the other liquid crystal materials particularly under a low temperature, liquid crystal compositions containing these crystalline compounds, and liquid crystal display devices constituted by using the liquid crystal compositions. The liquid crystalline compounds are represented by general formula (1): wherein R represents an alkyl, alkoxy or alkoxyalkyl group of 2-20 carbon atoms, and in each group, any 1-3 hydrogen atoms may be replaced by fluorine atoms; X shows an halogen atom or an alkyl group of 1-20 carbon atoms, any methylene groups (—CH2—) not adjacent each other in the alkyl group may be replaced by oxygen atoms, and any one or more hydrogen atoms in the alkyl group may be replaced by fluorine atoms; Z1, Z2 and Z3, each independently, represents —(CH2)2—, —(CH2)4—, —CH2O—, —OCH2—, —(CH2)3O—, —O(CH2)3— or a covalent bond; Y1-Y16 each independently represent hydrogen atoms or fluorine atoms, but at least two represent fluorine atoms; m represents 0 or 1, and any atom constituting the compound may be replaced by an isotope thereof.
摘要翻译：本发明提供了具有非常高的电压保持率的液晶化合物，这些性质随温度变化很小，DELTAn高，在其它液晶材料中特别是在低温下具有良好的相容性，含有这些结晶化合物的液晶组合物，以及使用液晶组合物构成的液晶显示装置。液晶化合物由通式（1）表示：其中R表示2-20个碳原子的烷基，烷氧基或烷氧基烷基，并且在每一组中，任何1-3个氢原子可被氟原子取代; X表示卤素原子或1-20个碳原子的烷基，烷基中不相邻的任何亚甲基（-CH 2 - ）可以被氧原子取代，并且烷基中的任何一个或多个氢原子可以被氟原子取代; Z 2，Z 2和Z 3各自独立地表示 - （CH 2）2 - ， - （CH 2）4 - ， - CH 2 O - ， - OCH 2 - ， - （CH 2）3 O-，-O ; Y1-Y16各自独立地表示氢原子或氟原子，但至少两个表示氟原子; m表示0或1，构成化合物的任何原子可以被其同位素代替。

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