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    • 6. 发明申请
    • URETHANE (METH) ACRYLATE COMPOUND
    • URETHANE(METH)丙烯酸酯化合物
    • US20150361035A1
    • 2015-12-17
    • US14763645
    • 2014-01-15
    • Japan U-Pica Company, Ltd.
    • Tetsuji MOROIWANozomi ISHINEHiroshi HAYASHI
    • C07C271/08C08L75/16C08L63/10C07C269/02C08G71/04
    • C07C271/08C07C269/02C08F290/068C08G18/672C08G71/04C08J5/042C08J2375/16C08L63/10C08L75/16C08L2312/04
    • The present invention provides a thermosetting resin which enables the production of a carbon fiber reinforced plastic having a good workability and excellent mechanical properties by hand lay up (HUP) molding, resin transfer molding (RTM) or vacuum assisted resin transfer molding (VaRTM). The urethane (meth) acrylate compound (A) according to the present invention is an urethane (meth) acrylate produced by reacting a compound having two or more isocyanate groups with a monoalcohol compound containing ethylenically unsaturated groups or by reacting a compound having two or more isocyanate groups with a monoalcohol compound containing ethylenically unsaturated groups and an alcohol compound having two or more hydroxyl groups, said urethane (meth) acrylate compound (A) being characterized by having an isocyanate group and ethylenically unsaturated groups.
    • 本发明提供一种热固性树脂,其能够通过手工铺板(HUP)模塑,树脂传递模塑(RTM)或真空辅助树脂传递模塑(VaRTM)生产具有良好可加工性和优异机械性能的碳纤维增强塑料。 根据本发明的氨基甲酸酯(甲基)丙烯酸酯化合物(A)是通过使具有两个或多个异氰酸酯基的化合物与含有烯键式不饱和基团的一元醇化合物反应或通过使具有两个或多个 含有烯键式不饱和基团的一元醇化合物和具有两个或多个羟基的醇化合物的异氰酸酯基团,所述氨基甲酸酯(甲基)丙烯酸酯化合物(A)的特征在于具有异氰酸酯基和烯属不饱和基团。
    • 7. 发明授权
    • Catalysts for reaction between an isocyanate and an alcohol
    • 异氰酸酯与醇反应的催化剂
    • US09102780B2
    • 2015-08-11
    • US13123981
    • 2009-10-12
    • Christian MaliverneyLaurent Saint-Jalmes
    • Christian MaliverneyLaurent Saint-Jalmes
    • C08G18/18C08G18/30C08G18/42C07C269/02C08J9/08C08G18/08C08G18/28C08G18/48
    • C08G18/1816C07C269/02C08G18/14C08G18/1808C08G18/1858C08G18/2815C08G18/42C08G18/4825C08J9/08
    • Processes are described for preparing polyurethane polymers by reacting an isocyanate with an alcohol using a non-tin based catalyst having the formula where R1, which are identical or different, are a fluoroalkyl, monovalent alkyl, cycloalkyl, (cycloalkyl)alkyl, or the ring of the cycloalkyl group that optionally comprises at least one heteroatom, R2 represents a hydrogen atom, an aromatic, arylalkyl, fluoroalkyl, alkylamine, alkylguanidine, monovalent alkyl, cycloalkyl or an alkyl group substituted by an optionally substituted ring, which optionally comprises at least one heteroatom, and R3 represents an arylalkyl, fluoroalkyl, alkylamine, alkylguanidine, monovalent alkyl, cylcoalkyl, or alkyl group substituted by an optionally substituted ring which optionally comprises at least one heteroatom, when the R2 radical is not a hydrogen atom, the R2 and R3 radicals optionally being linked to form a 3 to 7 membered optionally substituted aliphatic ring, and the R1, R2 and R3 radicals do not comprise a silicon atom.
    • 描述了通过使用具有下式的非锡基催化剂使异氰酸酯与醇反应制备聚氨酯聚合物的方法,其中相同或不同的R 1是氟烷基,一价烷基,环烷基,(环烷基)烷基或环 任选地包含至少一个杂原子的环烷基,R 2表示氢原子,芳族,芳基烷基,氟烷基,烷基胺,烷基胍,一价烷基,环烷基或被任选取代的环取代的烷基,其任选地包含至少一个 并且R 3表示芳基烷基,氟代烷基,烷基胺,烷基胍,一价烷基,环烷基或任意取代的环取代的烷基,其任选地包含至少一个杂原子,当R 2基团不是氢原子时,R 2和R 3 可任意连接的基团形成3至7元任选取代的脂族环,并且R 1,R 2和R 3基团为n 其包含硅原子。
    • 10. 发明申请
    • PROCESS FOR PRODUCING EPOXY (METHA)ACRYLATE
    • 制备环氧(METHA)丙烯酸酯的方法
    • US20110071307A1
    • 2011-03-24
    • US12922193
    • 2009-03-12
    • Fumihiko IshiyamaTakeshi HizawaHideki Watanabe
    • Fumihiko IshiyamaTakeshi HizawaHideki Watanabe
    • C07D303/16
    • C07C269/02C07C271/28
    • An object of the present invention is to provide a process for producing an epoxy (meth)acrylate safely with good productivity, and the invention provides a process for continuously producing an epoxy (meth)acrylate, containing causing a mixed liquid of a compound (A) having a carboxyl group and a (meth)acryloyl group and a compound (B) having an epoxy group to pass continuously and densely through a tubular microchannel formed in a heat-conducting reaction device, and reacting the carboxyl group of the compound (A) with the epoxy group of the compound (B), in which the tubular microchannel in the reaction device has a space size making a fluid cross-sectional area, through which the mixed liquid passes densely, of from 0.1 to 4.0 mm2, and the process contains heating the heat-conducting reaction device to a temperature of from 150 to 260° C., reacting the mixed liquid to provide a Reynolds number of a reaction liquid passing through the tubular microchannel in a range of from 0.4 to 100, and after completing reaction, cooling continuously a reaction product discharged from the heat-conducting reaction device.
    • 本发明的目的在于提供一种以高生产率安全地生产环氧(甲基)丙烯酸酯的方法,本发明提供一种连续制备环氧(甲基)丙烯酸酯的方法,该方法含有使化合物(A) )具有羧基和(甲基)丙烯酰基的化合物(B)和具有环氧基的化合物(B)连续密集地通过形成在导热反应装置中的管状微通道,并使化合物(A )与化合物(B)的环氧基的反应,其中反应装置中的管状微通道具有使混合液体密集通过的流体截面积为0.1〜4.0mm 2的空间尺寸, 该方法包括将导热反应装置加热至150-260℃的温度,使混合液体反应,以提供穿过管状微通道的反应液体的雷诺数在0.4至 100,反应完成后,连续冷却从导热反应装置排出的反应物。