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    • 8. 发明申请
    • Process Of Purifying Ruthenium Precursors
    • 净化钌前体的方法
    • US20100116738A1
    • 2010-05-13
    • US12437224
    • 2009-05-07
    • Bin XiaZhiwen WanAshutosh MisraOlivier Letessier
    • Bin XiaZhiwen WanAshutosh MisraOlivier Letessier
    • B01D15/04
    • B01D15/00C07C41/44C07C43/12C07C43/126
    • The present invention provides for two separate processes for removing impurities from an organic solvent based ruthenium precursor. The first process comprises the steps of contacting the organic solvent based ruthenium precursor with one or more drying agents under an inert gas blanket for a sufficient period of time to allow at least a portion of the impurities in the organic solvent based ruthenium precursor to be adsorbed by the one or more drying agents; and separating the one or more drying agents which have at least a portion of the impurities adsorbed thereon from the organic solvent based ruthenium precursor. The second process comprises the steps of providing a column that contains one or more drying agents and is equipped with a filtration unit; passing the organic solvent based ruthenium precursor through the column in order to allow at least a portion of the impurities in the solvent based ruthenium precursor to be adsorbed by the one or more drying agents, said passing of the solvent based ruthenium precursor taking place under a blanket of inert gas; and further passing the ruthenium precursor through the filtration unit in order ro remove any residual particles that may result from the passage of the ruthenium precursor through the column containing the one or more drying agents in order to obtain a purified ruthenium precursor.
    • 本发明提供了用于从有机溶剂型钌前体中除去杂质的两种分开的方法。 第一种方法包括以下步骤:使有机溶剂基钌前体与一种或多种干燥剂在惰性气体覆盖下接触足够的时间,以允许有机溶剂型钌前体中的至少一部分杂质被吸附 由一种或多种干燥剂; 以及从有机溶剂型钌前体分离其中吸附有至少一部分杂质的一种或多种干燥剂。 第二种方法包括提供含有一种或多种干燥剂并装有过滤装置的柱子的步骤; 使有机溶剂基钌前体通过柱,以使至少一部分溶剂型钌前体中的杂质被一种或多种干燥剂吸附,所述溶剂型钌前体在 惰性气体毯; 并且进一步使钌前体通过过滤单元以顺序去除可能由钌前体通过含有一种或多种干燥剂的柱而导致的残余颗粒,以获得纯化的钌前体。