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1. 发明申请

US20180170852A1 Process for the Hydrodechlorination of a Feed Comprising Dichloroacetic Acid 审中-公开
公开(公告)号：US20180170852A1
公开(公告)日：2018-06-21
申请号：US15579892
申请日：2016-06-09
申请人： Akzo Nobel Chemicals International B.V.
发明人： Lars Magnus Tollin , Cornelis Kooijman
IPC分类号： C07C51/377
CPC分类号： C07C51/377 , C07C53/16
摘要： The present invention is directed to a process for catalytic hydrodechlorination of dichloroacetic acid, wherein hydrogen gas is contacted with a liquid feed comprising dichloroacetic acid and monochloroacetic acid to form a product stream comprising monochloroacetic acid and an off gas stream comprising hydrogen chloride and hydrogen, and wherein the product stream is contacted with nitrogen gas so as to remove hydrogen gas present in the product stream.

2. 发明申请

US20140357881A1 Transvinylation as a First Stage of Coupling Production of Vinyl Esters and Acetic Acid or Propionic Acid Reaction Products 有权
标题翻译：作为乙烯基酯和乙酸或丙酸反应产物的偶联生产的第一阶段的转乙烯化
公开(公告)号：US20140357881A1
公开(公告)日：2014-12-04
申请号：US14372235
申请日：2013-01-18
申请人： Oxea GmbH
发明人： Leif Johnen , Heinz Strutz
IPC分类号： C07C67/333
CPC分类号： C07C67/333 , C07C29/149 , C07C51/02 , C07C51/09 , C07C51/363 , C07C67/055 , C07C67/08 , C07C67/10 , C07C67/54 , C07C69/01 , C07C69/24 , C07C69/78 , C07C53/16 , C07C53/19 , C07C69/15 , C07C31/08 , C07C31/10 , C07C53/40 , C07C53/42 , C07C53/12 , C07C53/122 , C07C53/08 , C07C69/14
摘要： Process for coproduction of a vinyl ester of the formula R—C(O)O—CH═CH by transvinylation reaction of a carboxylic acid of the formula R—C(O)OH with a transvinylating reagent of the formula R1—C(O)O CH═CH2, characterized in that (a) the transvinylation reaction is conducted continuously at a temperature of 90 to 160° C. and at a pressure of 0.5 to 15 MPa without withdrawal of a reactant in the presence of a transition meta/catalyst containing at least one transition metal selected from the group of ruthenium, osmium, rhodium, iridium, palladium and platinum; (b) the resulting reaction mixture is separated into its constituents and the vinyl ester of the formula R—C(O)O—CH═CH2 and the carboxylic acid of the formula R1—C(O)—OH are removed; and (c) the carboxylic acid obtained after step (b) is converted to a derivative of the formula R1—C(O)—X, R1—CH2—OH or R6—C(O)—OH in which X is vinyloxy, O—CH—CH2, halogen, alkoxy of the formula OR2 in which R2 is a substituted or unsubstituted hydrocarbyl radical having 1 to 10 carbon atoms, amino of the formula NR3R4 in which R3 and R4 are each independently hydrogen or a substituted or unsubstituted hydrocarbyl radical having 1 to 10 carbon atoms, or carboxyl of the formula O—C(O)—R5 in which R5 is hydrogen or a substituted or unsubstituted hydrocarbyl radical having 1 to 10 carbon atoms, and R6 is the partly or fully halogen-substituted R1 radical.
摘要翻译：通过式R-C（O）OH的羧酸与式R1-C（O）的转乙烯化试剂的反缩合反应共同制备式R-C（O）O-CH = CH的乙烯基酯的方法）O CH = CH 2，其特征在于：（a）在90至160℃的温度和0.5至15MPa的压力下连续进行转化反应，而不会在转移间/ 含有选自钌，锇，铑，铱，钯和铂中的至少一种过渡金属的催化剂; （b）将所得反应混合物分离成其组分，并且除去式R-C（O）O-CH = CH 2的乙烯基酯和式R 1 -C（O）-OH的羧酸; 和（c）将步骤（b）后获得的羧酸转化为其中X为乙烯氧基的式R 1 -C（O）-X，R 1 -CH 2 -OH或R 6 -C（O）-OH的衍生物， O-CH-CH 2，卤素，式OR 2的烷氧基，其中R 2是具有1至10个碳原子的取代或未取代的烃基，式NR 3 R 4的氨基，其中R 3和R 4各自独立地为氢或取代或未取代的烃基具有1-10个碳原子的基团，或其中R 5是氢的式O-C（O）-R 5的羧基或具有1至10个碳原子的取代或未取代的烃基，R 6是部分或完全卤素取代的 R1激进。

3. 发明申请

US20140275625A1 PROCESS FOR THE PURIFICATION OF A LIQUID FEED COMPRISING MCA AND DCA 有权
标题翻译：用于净化包含MCA和DCA的液体进料的方法
公开(公告)号：US20140275625A1
公开(公告)日：2014-09-18
申请号：US14351313
申请日：2012-10-17
申请人： Melle Rinze Nieuwhof , Cornellis Kooijman , Willem Koelewijn , Hendrik Jan Vos , Lars Magnus Tollin , Henricus Johannes Marinus Petrus Van Hal
发明人： Melle Rinze Nieuwhof , Cornellis Kooijman , Willem Koelewijn , Hendrik Jan Vos , Lars Magnus Tollin , Henricus Johannes Marinus Petrus Van Hal
IPC分类号： C07C51/377
CPC分类号： C07C51/377 , C07C51/487 , C07C53/16
摘要： The present invention pertains to a process for the purification of a substantially water-free liquid feed comprising monochloroacetic acid, dichloroacetic acid, optionally acid chlorides, optionally anhydrides, and optionally acetic acid, which comprises the steps of (a) adding water to the liquid feed so that a liquid feed is obtained comprising between 0.01 and 5% by weight of water, based on the total weight of the liquid feed, and (b) subsequently subjecting the liquid feed obtained in step (a) to a catalytic hydrodechlorination step by contacting it with a source of hydrogen to convert the dichloroacetic acid into monochloroacetic acid in the presence of a solid heterogeneous hydrogenation catalyst comprising one or more metals of Group VIII of the Periodic Table of the Elements deposited on a carrier.
摘要翻译：本发明涉及纯化基本上无水的液体原料的方法，其中包括一氯乙酸，二氯乙酸，任选的酰氯，任选的酸酐和任选的乙酸，其包括以下步骤：（a）向该液体中加入水进料，从而获得包含0.01至5重量％的水的液体进料，基于液体进料的总重量，和（b）随后将步骤（a）中获得的液体进料经催化加氢脱氯步骤使其与氢源接触，在包含沉积在载体上的元素周期表第Ⅷ族的一种或多种金属的固体多相氢化催化剂存在下将二氯乙酸转化为一氯乙酸。

4. 发明授权

US08633336B2 Method for separating a carboxylic acid in salified form bearing at least one halogen atom 有权
标题翻译：分离含有至少一个卤素原子的盐化形式的羧酸的方法
公开(公告)号：US08633336B2
公开(公告)日：2014-01-21
申请号：US13003136
申请日：2009-07-08
申请人： Olivier Buisine , François Metz
发明人： Olivier Buisine , François Metz
IPC分类号： C07C53/21
CPC分类号： C07C51/412 , C07C51/48 , C07C53/21 , C07C53/18 , C07C53/19 , C07C53/16
摘要： The subject of the present invention is a method for separating a carboxylic acid in salified form bearing at least one halogen atom at the α position of the carbonyl group from a medium comprising it. The method according to the invention, for separating a carboxylic acid in salified form bearing at least one halogen atom at the α position of the carbonyl group from an aqueous medium comprising it, is characterized by the fact that the latter is brought into contact with an onium salt leading to the formation of two phases: an organic phase comprising the salt resulting from the reaction of the salt of the carboxylic acid bearing at least one halogen atom at the α position of the carbonyl group and of the onium salt leading to the displacement of the cation from the carboxylic acid by the onium, an aqueous phase comprising the various salts, in particular the one resulting from the reaction of the cation of the carboxylic acid with the anion of the onium, and by the fact that the organic and aqueous phases are then separated and that the onium salt of the carboxylic acid is recovered from the organic phase.
摘要翻译：本发明的主题是在含有羰基的α位的至少一个卤原子的盐化形式的羧酸的分离方法。根据本发明的方法，用于从含有它的水性介质中分离在羰基的α位上带有至少一个卤素原子的盐化形式的羧酸，其特征在于后者与导致形成两相的有机相：包含由在羰基的α位上带有至少一个卤素原子的羧酸的盐与导致位移的鎓盐反应而产生的盐的有机相的阳离子由羧酸由鎓形成，包含各种盐的水相，特别是由羧酸的阳离子与鎓的阴离子反应的水相，以及有机和水性然后分离相，并从有机相中回收羧酸的鎓盐。

5. 发明申请

US20060014631A1 Supported catalyst containing active titanium in the homo, co-, and ter-polymerization of olefin-unsaturated compounds 有权
标题翻译：在烯烃不饱和化合物的同质，共聚和三聚中的含有活性钛的载体催化剂
公开(公告)号：US20060014631A1
公开(公告)日：2006-01-19
申请号：US10497549
申请日：2002-12-06
申请人： Francesco Masi , Roberto Santi , Maria Rivellini , Stefano Santi , Laura Santi , Anna Sommazzi , Antonio Proto , Mario Polesello , Andrea Vallieri
发明人： Francesco Masi , Roberto Santi , Maria Rivellini , Stefano Santi , Laura Santi , Anna Sommazzi , Antonio Proto , Mario Polesello , Andrea Vallieri
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C07C53/16 , C07C53/19 , C07C57/52 , C07C57/58 , C07F3/003 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/06 , C08F210/18 , C08F4/6555 , C08F4/025 , C08F2500/04 , C08F232/00 , C08F210/16 , C08F2500/24 , C08F236/20 , C08F2500/25
摘要： The present invention relates to a supported catalyst containing titanium, its preparation and it use in the homo-, co-, and ter-polymerization of olefin-unsaturated compounds. The present invention also relates to a catalytic system comprising a supported catalyst based on titanium and a co-catalyst selected from organo-derivatives of aluminum. More, specifically, the present invention relates to catalyst supported on silica, obtained by reacting a titanium halocarboxylate and a magnesium halocarboxylate with an aluminum chloroakylderivative, in the presente of a carrier consisting of high porosity silica. The above reaction essentially takes place in the pores of the silica itself.
摘要翻译：本发明涉及含钛的负载型催化剂，其制备方法及其用于烯烃 - 不饱和化合物的均相，共聚和三元共聚。本发明还涉及包含基于钛的负载催化剂和选自铝的有机衍生物的助催化剂的催化体系。更具体地，本发明涉及在由高孔隙率二氧化硅组成的载体的存在下，通过使卤代钛卤化物和卤代羧酸镁与氯代氯酰卤衍生物反应而获得的二氧化硅上负载的催化剂。上述反应基本上发生在二氧化硅本身的孔中。

6. 发明授权

US3754029A Continuous process for the purification of monochloroacetic acid 失效
标题翻译：用于纯化单氯酸的连续方法
公开(公告)号：US3754029A
公开(公告)日：1973-08-21
申请号：US3754029D
申请日：1971-09-13
申请人： HOECHST AG
发明人： HOLTERMANN R , WIRTZ R , FREYER W , GSCHEIDMEIER M
IPC分类号： C07C51/377 , C07C51/487 , C07C51/42
CPC分类号： C07C51/377 , C07C51/487 , C07C53/16
摘要： DI- AND TRICHLOROACETIC ACID CONTAINED AS IMPURITTIES IN CRUDE MONOCHLOROACETIC ACID ARE PARRTIALLY DEHALOGENATEDD AND TRANSFORMED IN MONOCHLOROACETIC ACID AT A TEMPERATURE OF FROM 110 TO 145*C. IN A CONTINUOUS PROCESS IN THE PPRESENCE OF HYDROGEN WHILE TRICKLING THROUGH A CATALYST LAYER THE ACTIVE CONSTITUENT OF WHICH IS A NOBLE METAL OF SUBGROUP VIII OF THE PERIODIC TABLE.

7. 发明授权

US3627826A Process for halogenating carboxylic acids 失效
标题翻译：羧酸羧酸反应的方法
公开(公告)号：US3627826A
公开(公告)日：1971-12-14
申请号：US3627826D
申请日：1970-11-25
申请人： GULF RESEARCH DEVELOPMENT CO
发明人： SELWITZ CHARLES M
IPC分类号： C07C51/363 , C07C53/16 , C07C53/32
CPC分类号： C07C51/363 , C07C53/16
摘要： A process for chlorinating or brominating a carboxylic acid which involves heating a carboxylic acid with chloride ions or bromide ions and molecular oxygen in the presence of nitrate ions, a carboxylic acid anhydride and a heavy metal cation. Acetic acid is converted to chloroacetic acid.

8. 发明授权

US3364257A Process for the preparation of monochloracetic acid 失效
公开(公告)号：US3364257A
公开(公告)日：1968-01-16
申请号：US47142265
申请日：1965-07-12
申请人： RHONE POULENC SA
发明人： EMMANUEL MOUNIER PAULIN
IPC分类号： C07C51/235
CPC分类号： C07C51/235 , C07C53/16

9. 发明授权

US3220846A Use of salts of readily decarboxylated acids in thermography, photography, photothermography and thermophotography 失效
标题翻译：在热成像，摄影，光热成像和热摄影中使用容易脱羧酸的盐
公开(公告)号：US3220846A
公开(公告)日：1965-11-30
申请号：US3915560
申请日：1960-06-27
申请人： EASTMAN KODAK CO
发明人： TINKER JOHN F , SAGURA JOHN J
IPC分类号： B41M5/323 , C07C53/16 , C07C53/18 , C07C53/21 , C07D213/18 , C07D213/26 , C07D295/02 , C07D295/027 , G03C1/42 , G03C1/61
CPC分类号： G03C1/615 , B41M5/323 , C07C53/16 , C07C53/18 , C07C53/21 , C07D213/18 , C07D213/26 , C07D295/027 , G03C1/42 , Y10S430/145

10. 发明授权

US3152174A Manufacture of monochloroacetic acid 失效
标题翻译：一氯乙酸的制造
公开(公告)号：US3152174A
公开(公告)日：1964-10-06
申请号：US2365960
申请日：1960-04-21
申请人： DOW CHEMICAL CO
发明人： MORRIS ELTON K , BAKKE WILLIAM W
IPC分类号： C07C51/363
CPC分类号： C07C51/363 , C07C53/16

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