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1. 发明授权

US09447207B2 Solid catalyst component and process for the (co)polymerization of ethylene 有权
标题翻译：固体催化剂组分和乙烯（共）聚合方法
公开(公告)号：US09447207B2
公开(公告)日：2016-09-20
申请号：US13649248
申请日：2012-10-11
申请人： Giuseppe Conti , Corrado Adesso , Francesco Menconi , Francesco Masi
发明人： Giuseppe Conti , Corrado Adesso , Francesco Menconi , Francesco Masi
IPC分类号： C08F4/654 , C08F4/656 , C08F4/64 , B01J31/00 , C08F10/02 , C08F210/16
CPC分类号： C08F210/16 , C08F10/02 , C08F4/6543 , C08F4/651 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F2500/19
摘要： Catalyst and solid component of catalyst for the (co)polymerization of ethylene, comprising titanium, magnesium, chlorine, a protic organo-oxygenated compound Dp and a neutral aprotic electron-donor compound D, in the following molar ranges: Mg/Ti=1.0-50; D/Ti=1.0-15; Cl/Ti=6.0-100; Dp/D=0.05-3; and a process for obtaining said component.
摘要翻译：用于乙烯（共）聚合的催化剂和固体组分，其包含钛，镁，氯，质子有机 - 氧化化合物Dp和中性非质子电子给体化合物D，摩尔浓度范围为：Mg / Ti = 1.0 -50; D / Ti = 1.0-15; Cl / Ti = 6.0-100; Dp / D = 0.05-3; 以及用于获得所述组分的方法。

2. 发明申请

US20140228206A1 BIS-IMINE COMPLEX OF LANTHANIDES, CATALYTIC SYSTEM COMPRISING SAID BIS-IMINE COMPLEX AND PROCESS FOR THE (CO)POLYMERIZATION OF CONJUGATED DIENES 有权
标题翻译： BIS-IMINE复合物，包含相同双胺复合物的催化体系和（CO）共聚二烯的聚合方法
公开(公告)号：US20140228206A1
公开(公告)日：2014-08-14
申请号：US14344351
申请日：2012-09-13
申请人： Giovanni Ricci , Anna Sommazzi , Giuseppe Leone , Aldo Boglia , Francesco Masi
发明人： Giovanni Ricci , Anna Sommazzi , Giuseppe Leone , Aldo Boglia , Francesco Masi
IPC分类号： C08F136/06
CPC分类号： C08F136/06 , C08F36/00 , C08F136/00 , C08F136/08 , C08F4/52 , C08F4/545
摘要： A bis-imine complex of lanthanides having general formula (I): Said bis-imine complex of lanthanides having general formula (I) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.
摘要翻译：具有通式（I）的镧系元素的双亚胺络合物：具有通式（I）的镧系元素的所述双亚胺络合物可有利地用于共轭二烯（共）聚合的催化体系中。

3. 发明申请

US20130296592A1 METAL ALKYL-ARENES AND PROCESSES FOR THE PREPARATION THEREOF 有权
标题翻译：金属碱金属及其制备方法
公开(公告)号：US20130296592A1
公开(公告)日：2013-11-07
申请号：US13996842
申请日：2011-12-23
申请人： Guido Pampaloni , Filippo Renili , Anna Sommazzi , Fabio Marchetti , Francesco Masi , Mario Polesello
发明人： Guido Pampaloni , Filippo Renili , Anna Sommazzi , Fabio Marchetti , Francesco Masi , Mario Polesello
IPC分类号： C07F19/00
CPC分类号： C07F19/00 , B01J31/122 , C07F7/003 , C08F4/42 , C08F10/00 , C08F4/659
摘要： Metal alkyl-arene having general formula (I) or (Ia): M (η6-arene)2Al1XrRs (I) M (η6-arene)AlqXrRs (Ia) wherein: —M represents zirconium (Zr), hafnium (Hf), or mixtures thereof, preferably zirconium; —arene represents a benzene, or a benzene 10 substituted with from 1 to 6 linear or branched C1-C6 alkyl groups, or mixtures thereof; —X represents a halogen atom selected from chlorine, bromine, fluorine, iodine, preferably chlorine; —R represents a linear or branched C1-C15 alkyl group; —q is a number ranging from 2 to 6, preferably 3 for a metal alkyl-arene having general formula (I), 2 for a metal alkyl-arene having general formula (Ia); —r is a number ranging from 1 to 20, preferably 9 for a metal alkyl-arene having general formula (I), 6 for a metal alkyl-arene having general formula (Ia); —s is a number ranging from 1 to 6, preferably 2. Said metal alkyl-arene can be advantageously used for the preparation of solid components of catalysts for the (co)polymerization of α-olefins.
摘要翻译：具有通式（I）或（Ia）的金属烷基芳烃：M（eta6-芳烃）2Al1XrRs（I）M（eta6-芳烃）AlqXrRs（Ia）其中：-M代表锆（Zr），铪（Hf）或其混合物，优选锆; 芳烃代表苯，或被1至6个直链或支链C 1 -C 6烷基取代的苯10，或其混合物; -X表示选自氯，溴，氟，碘，优选氯的卤素原子; -R表示直链或支链的C 1 -C 15烷基; 对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，-q为2至6的数，优选3。对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，-r为1至20，优选9。 -s是1至6的数，优选2.所述金属烷基芳烃可有利地用于制备用于α-烯烃的（共）聚合的催化剂的固体组分。

4. 发明授权

US06984703B1 Bridged metallocene compounds as olefin-polymerization catalysts 有权
标题翻译：桥接金属茂化合物作为烯烃聚合催化剂
公开(公告)号：US06984703B1
公开(公告)日：2006-01-10
申请号：US10148571
申请日：2000-11-27
申请人： Paolo Biagini , Roberto Santi , Giuliana Schimperna , Maria Caldararo , Giampietro Borsotti , Francesco Masi
发明人： Paolo Biagini , Roberto Santi , Giuliana Schimperna , Maria Caldararo , Giampietro Borsotti , Francesco Masi
IPC分类号： C08F4/42
CPC分类号： C07F7/10 , C07C13/465 , C07C2602/08 , C08F4/65908 , C08F4/65912 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F210/06 , C08F2500/03
摘要： The present invention relates to metallocene compounds consisting of indenyl-cyclopentadienyl groups non-symmetrically joined by a bivalent radical. Said compounds can be conveniently used as components of catalysts for the polymerization of olefins.
摘要翻译：本发明涉及由二价基团非对称连接的茚基 - 环戊二烯基组成的茂金属化合物。所述化合物可以方便地用作烯烃聚合催化剂的组分。

5. 发明申请

US20050113518A1 Process for the functionalization of polyolefins 审中-公开
标题翻译：聚烯烃官能化方法
公开(公告)号：US20050113518A1
公开(公告)日：2005-05-26
申请号：US10507218
申请日：2003-03-12
申请人： Tiziano Tanaglia , Aroldo Biggi , Orsola Casaburo , Lisa Biggi , Francesco Masi
发明人： Tiziano Tanaglia , Aroldo Biggi , Orsola Casaburo , Lisa Biggi , Francesco Masi
IPC分类号： C08F8/50 , C08F255/00 , C08F287/00 , C08F8/00
CPC分类号： C08F287/00 , C08F8/50 , C08F210/18 , C08F255/00 , C08F255/06 , C08F2800/20 , C08F210/06 , C08F236/20 , C08F222/06
摘要： Process for the preparation of functionalized polyolefins, which comprises treatment under shear conditions of said polyolefins with an unsaturated monomer containing polar groups in the presence of at least one hydroperoxide as radicalic initiator. The process allows the grafting of unsaturated monomers without the formation of cross-linked polymeric material and without modifying the molecular weight distribution.
摘要翻译：用于制备官能化聚烯烃的方法，其包括在至少一种氢过氧化物作为自由基引发剂的存在下，在所述聚烯烃与含极性基团的不饱和单体的剪切条件下进行处理。该方法允许接枝不饱和单体而不形成交联的聚合物材料，而不改变分子量分布。

6. 发明授权

US06831034B2 Catalytic composition for the (co) polymerization of &agr;-olefins 有权
标题翻译： α-烯烃（共）聚合的催化组合物
公开(公告)号：US06831034B2
公开(公告)日：2004-12-14
申请号：US10670211
申请日：2003-09-26
申请人： Francesco Masi , Anna Sommazzi , Roberto Santi
发明人： Francesco Masi , Anna Sommazzi , Roberto Santi
IPC分类号： C08F464
CPC分类号： C08F10/02 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65925 , C08F4/6592 , C08F4/65927 , C08F4/76 , C08F2500/03 , C08F210/14
摘要： Catalytic composition for the (co)polymerization of ethylene and other &agr;-olefins, including a metallocene complex of a metal M of group 4 of the periodic table or the product obtainable from the same combined with a suitable activator, wherein said metallocene complex includes at least one cyclopentadienyl group and at least one unsaturated hydrocarbyl organic group bonded to the metal M, having the following formula (I): -(AxDyUz)RI (I) wherein: A represents any monomeric unit deriving from a vinylaromatic group polymerizable by means of anionic polymerization, having from 6 to 20 carbon atoms; D represents any monomeric unit deriving from a conjugated diolefin polymerizable by means of anionic polymerization, having from 4 to 20 carbon atoms; U represents any generic optional monomeric unit deriving from an unsaturated compound co-polymerizable with any of the above conjugated diolefins D or vinylaromatic compounds A; RI represents hydrogen or a hydrocarbyl group having from 1 to 20 carbon atoms, each index “x” and “y” can be independently zero or an integer, provided the sum (x+y) is equal to or higher than 2, preferably between 2 and 50, more preferably between 2 and 25; “z” can be zero or an integer ranging from 1 to 20.
摘要翻译：乙烯和其它α-烯烃（包括周期表第4族金属M的茂金属络合物）的共聚合的催化组合物或其合适的活化剂得到的产物，其中所述茂金属络合物包括在至少一个环戊二烯基和至少一个与金属M键合的不饱和烃基有机基团，具有下式（I）：其中：A表示衍生自通过阴离子聚合可聚合的乙烯基芳族基团的任何单体单元，其具有6至20个碳原子; D表示衍生自具有4至20个碳原子的通过阴离子聚合可共聚的共轭二烯烃的任何单体单元; U表示衍生自与任何上述共轭二烯烃共聚的不饱和化合物的任何通用任选的单体单元 D或乙烯基芳族化合物A; R 1表示氢或具有1至20个碳原子的烃基，ea 如果和（x + y）等于或高于2，优选在2和50之间，更优选在2和25之间，则ch指数“x”和“y”可以独立地为零或整数，“z” 为零或整数范围从1到20。

7. 发明授权

US06780947B1 Metal complexes comprising a 2,6-diacylpyridine-ligand and their use in the polymerization of ethylene 有权
标题翻译：包含2,6-二酰基吡啶 - 配体的金属络合物及其在乙烯聚合中的用途
公开(公告)号：US06780947B1
公开(公告)日：2004-08-24
申请号：US10048921
申请日：2002-06-12
申请人： Anna Sommazzi , Barbara Milani , Antonio Proto , Gianni Corso , Giovanni Mestroni , Francesco Masi
发明人： Anna Sommazzi , Barbara Milani , Antonio Proto , Gianni Corso , Giovanni Mestroni , Francesco Masi
IPC分类号： C08F452
CPC分类号： C07D213/53 , C07F15/025 , C07F15/065 , C08F10/00 , C08F4/7044
摘要： Organometallic complex having the formula (IAP)M(X)n which can be used for die formation of catalytic systems wherein: M is a metal selected from transition metals and lanthanides, in oxidation state “s” positive and different from zero; each X is independently a group of an anionic nature bound to the metal as an anion in an ionic couple or with a convalent bond of the “&sgr;” type; “n” expresses the number of X groups sufficient for neutralizing the formal “+s” charge of the metal M, and (IAP) represents a neutral bond consisting of a mono-imine of 2,6-diacylpyridine. Said complex is prepared with relatively simple methods and can be used, combined with a suitable co-catalyst, such as for example, an aluminoxane, as a catalyst in normal (co)polymerization processes of &agr;-olefins, and especially ethylene.
摘要翻译：具有式（IAP）M（X）n的有机金属络合物，其可用于催化体系的模具形成，其中：M为选自过渡金属和镧系元素的金属，氧化态为“正”且不同于零; 每个X独立地是在离子对中或与“σ”型的共价键作为阴离子结合金属的阴离子性基团; “n”表示足以中和金属M的正式“+ s”电荷的X基团的数目，（IAP）表示由2,6-二酰基吡啶的单亚胺组成的中性键。所述络合物以相对简单的方法制备，并且可以与合适的助催化剂（例如铝氧烷）一起使用，作为α-烯烃，特别是乙烯的正常（共）聚合方法中的催化剂。

8. 发明授权

US5189000A Supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds, and a (co)polymerization process which uses it 失效
标题翻译：用于烯烃不饱和化合物的聚合和共聚的支持催化剂和使用它的（CO）聚合方法
公开(公告)号：US5189000A
公开(公告)日：1993-02-23
申请号：US673272
申请日：1991-03-21
申请人： Francesco Masi , Renzo Invernizzi , Antonio Carbonaro , Lorenzo Costa , Angelo Moalli
发明人： Francesco Masi , Renzo Invernizzi , Antonio Carbonaro , Lorenzo Costa , Angelo Moalli
IPC分类号： C08F4/658 , B01J20060101 , C07F20060101 , C08F20060101 , C08F2/00 , C08F4/00 , C08F4/02 , C08F4/60 , C08F4/61 , C08F4/617 , C08F4/62 , C08F4/622 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16
CPC分类号： C08F10/00
摘要： A supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds is described, comprising an organometallic compound of aluminium and a second component obtained by bringing a titanium, vanadium or chromium compound, at least one compound of a second metal chosen from V, Al, Zr, Hf, Mo and Nd and optionally a magnesium compound into contact with a porous support consisting of microbeads of aerogels of one or more inorganic oxides distinguished by low density, high porosity and the fact that at least 90% of the pores have a diameter lying within a very narrow range of values. The process for the polymerization or copolymerization of olefinically unsaturated compounds based on the use of said catalyst is also described.

9. 发明授权

US5093508A Process for producing vanadium-arenes 失效
标题翻译：生产钒酸盐的方法
公开(公告)号：US5093508A
公开(公告)日：1992-03-03
申请号：US641877
申请日：1991-01-04
申请人： Fausto Calderazzo , Guido Pampaloni , Lucia Rocchi , Angelo Moalli , Francesco Masi , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Lucia Rocchi , Angelo Moalli , Francesco Masi , Renzo Invernizzi
IPC分类号： C07F9/00 , C08F4/20
CPC分类号： C07F9/00
摘要： Vanadium-arenes[V(arene).sub.2 ]wherein "arene" means benzene or mono-, di- or poly-(C.sub.1 -C.sub.5)-alkyl-substituted benzene, are prepared by means of a process which comprises:(a) forming a complex:[V(arene).sub.2 ](+).AlCl.sub.4 (-) by reacting vanadium trichloride, aluminum metal and aluminum trichloride with one another, by operating in the presence of the selected arene;(b) treating the so obtained complex with an either cyclic or acyclic, liquid aliphatic ether to obtain the reduction of [V(arene).sub.2 ](+) to [V(arene).sub.2 ]; and(c) recovering the so separated vanadium-arene.The vanadium-arenes are useful in the preparation of catalysts for olefin polymerization.

10. 发明申请

US20130303360A1 SOLID CATALYST COMPONENT, CATALYST COMPRISING SAID SOLID COMPONENT, AND PROCESS FOR THE (CO)POLYMERIZATION OF ALPHA-OLEFINS 有权
标题翻译：固体催化剂组分，包含固体组分的催化剂，以及（CO）聚合烯烃的方法
公开(公告)号：US20130303360A1
公开(公告)日：2013-11-14
申请号：US13997967
申请日：2011-12-20
申请人： Anna Sommazzi , Francesco Masi , Guido Pampaloni , Filippo Renili , Fabio Marchetti , Anna Maria Raspolli Galletti
发明人： Anna Sommazzi , Francesco Masi , Guido Pampaloni , Filippo Renili , Fabio Marchetti , Anna Maria Raspolli Galletti
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C07F17/00 , C08F4/52 , C08F4/65912 , C08F4/76 , C08F110/02 , C08F210/16 , C08F4/6557 , C08F4/65904 , C08F4/6552 , C08F2500/12 , C08F210/14
摘要： A solid catalyst component for the (co)polymerization of α-olefins having general formula (I): ZrnMAlxClMgp (I) wherein: M represents titanium (Ti), vanadium (V), or mixtures thereof; n is a number ranging from 0.01 to 2; x is a number ranging from 0.1 to 4; y is a number ranging from 5 to 53; p is a number ranging from 0 to 15; obtained by means of a process comprising putting at least one zirconium arene in contact with at least one metal compound and, optionally, with at least one compound of magnesium. Said solid catalyst component can be advantageously used as a solid component in a catalyst for the (co)polymerization of α-olefins. Said catalyst can be advantageously used in a process for the (co)polymerization of α-olefins.
摘要翻译：用于通式（I）的α-烯烃的（共）聚合的固体催化剂组分：ZrnMAlxClMgp（I）其中：M表示钛（Ti），钒（V）或其混合物; n为0.01〜2的数; x是从0.1到4的数字; y是从5到53的数字; p是从0到15的数字; 通过包括将至少一种锆芳烃与至少一种金属化合物和任选地与至少一种镁化合物接触的方法获得。所述固体催化剂组分可有利地用作α-烯烃（共）聚合的催化剂中的固体组分。所述催化剂可以有利地用于α-烯烃的（共）聚合方法中。

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