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    • 8. 发明授权
    • Magnetic macroinitiators and magnetically induced chain reactions
    • 磁性大分子引发剂和磁诱导链反应
    • US09545611B2
    • 2017-01-17
    • US13975902
    • 2013-08-26
    • Mark D SoucekKent R Miller
    • Mark D SoucekKent R Miller
    • B01J19/08C08F2/46
    • B01J19/087C08F2/46
    • This invention provides a method of initiating chain reaction in a chain reaction medium including (a) a macroinitiator and (b) chain reactants selected from monomers, reactive oligomers, reactive diluents and derivatives thereof and mixtures of the forgoing. The macroinitiator includes a multidentate anchor segment coordinated with a magnetic nanoparticle through more than one bond, and a chain reaction initiator segment bound to the multidentate anchor and providing a weak bond that can be cleaved to initiate a chain reaction. The method further comprises subjecting the chain reaction medium to an alternating current magnetic field to vibrate the magnetic nanoparticle and thereby cleave the weak bond, the cleavage resulting in the initiation of a chain reaction involving the chain reactants.
    • 本发明提供了在链反应介质中引发链反应的方法,其包括(a)大分子引发剂和(b)选自单体,反应性低聚物,反应性稀释剂及其衍生物的链反应物以及前述的混合物。 大分子引发剂包括通过多于一个键与磁性纳米颗粒配位的多齿锚定部分,以及与多齿锚定体结合的提供可以被切割以引发连锁反应的弱键的链式反应引发剂链段。 该方法还包括使链式反应介质经受交流磁场以振动磁性纳米颗粒,从而切断该弱键,该切割导致涉及链式反应物的连锁反应的引发。