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    • 10. 发明授权
    • (meth) Acrylate having an alkenyl group, an epoxy (meth) acrylate, a
(meth) acrylic resin having alkenyl groups, a (meth) acrylic resin
having epoxy groups, a thermosetting resin composition and coating
composition
    • (甲基)烯丙基丙烯酸酯,环氧(甲基)丙烯酸酯,具有烯基的(甲基)丙烯酸树脂,具有环氧基的(甲基)丙烯酸树脂,热固性树脂组合物和涂料组合物
    • US6071226A
    • 2000-06-06
    • US27028
    • 1998-02-20
    • Masami ShinoharaHideki Matsui
    • Masami ShinoharaHideki Matsui
    • C07C69/527C07C69/54C07D303/16C08F8/00C08F20/32C08F20/40C09D5/46
    • C08F20/40C07C69/54C07D303/16C08F20/32C08F8/00
    • Disclosed are a novel (meth)acrylate having an alkenyl group, a novel epoxy(meth)acrylate, and processes for the preparation thereof. The (meth)acrylate having an alkenyl group of the present invention can be preferably used as resins for coatings, photo-curable resins, and adhesives by (co)polymerization thereof in the presence or absence of a variety of (meth)acrylic monomers, and the (meth)acrylate compound having an alkenyl group is useful as a silane coupling agent, a starting material for epoxy (meth)acrylates, a modifier for silicone resins, a modifier for unsaturated polyester resins, and a crosslinking agent for acrylic rubbers. The epoxy(meth)acrylate has a well-balanced excellent property between a pot life and reactivity in curing, and it does not contain chlorine, resulting in that a resin therefrom is excellent in an anti-corrosive property and an anti-yellowing property. Still further, the present invention relates to a (meth)acrylic resin having alkenyl groups as side chains, a (meth)acrylic resin having epoxy groups as side chains, and processes thereof. In addition, the present invention relates to a thermosetting resin composition, a coating composition and a powder coating composition which have anti-corrosive properties to substrates and anti-yellowing properties in coating layers.
    • 公开了具有烯基的新的(甲基)丙烯酸酯,新的环氧(甲基)丙烯酸酯,及其制备方法。 具有本发明烯基的(甲基)丙烯酸酯可以通过(共)聚合在各种(甲基)丙烯酸单体存在或不存在下,作为涂料,光固化树脂和粘合剂的树脂, 具有烯基的(甲基)丙烯酸酯化合物可用作硅烷偶联剂,环氧(甲基)丙烯酸酯的起始原料,有机硅树脂的改性剂,不饱和聚酯树脂的改性剂和丙烯酸橡胶的交联剂。 环氧(甲基)丙烯酸酯在适用期和固化反应性之间具有良好的平衡性,不含氯,导致其树脂具有优异的耐腐蚀性和抗黄变性。 此外,本发明涉及具有作为侧链的烯基的(甲基)丙烯酸树脂,具有环氧基作为侧链的(甲基)丙烯酸树脂及其工艺。 此外,本发明涉及对涂层具有对基材的抗腐蚀性和抗黄变性的热固性树脂组合物,涂料组合物和粉末涂料组合物。