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    • 8. 发明申请
    • Ethylene-aromatic vinyl compound-vinyl norbonene terpolymer
    • 乙烯 - 芳族乙烯基化合物 - 乙烯基降冰片烯三元共聚物
    • US20030130446A1
    • 2003-07-10
    • US10129685
    • 2002-06-07
    • Xuequan ZhangJae Gon LimSung Cheol YoonHyun Joon KimYoung Sub Lee
    • C08F004/44C08F136/00
    • C08F212/04C08F4/65912C08F210/02C08F4/6592C08F212/08C08F236/20C08F2500/25
    • The ethylene/aromatic vinyl compound/vinylnorbornene terpolymer according to the present invention is prepared by copolymerizing 50-90 mol % of ethylene, 1-55 mol % of an aromatic vinyl compound and 1-55 mol % of a vinylnorbornene under a catalyst system consisting of a transition metal compound represented by formula (I) and a cocatalyst, where M represents a transition metal of Group IV of the Periodic Table such as titanium, zirconium or hafnium; Cpnull is a non-substituted cyclopentadienyl group; a cyclopentadienyl group with 1 to 4 liner alkyl substitutes; an indenyl group; a substituted indenyl group; a fluorenyl group; or a substituted fluorenyl group; Y is a hydrogen or a silyl group of C1-10, an alkyl group of C1-10, an aryl group of C1-10, or a combination thereof; A is an alkyl group of C1-30, an alkylamide group of C1-30 or a derivative of cyclopentadienyl group which is identical to Cpnull; and X is selected from the group consisting of a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a diene group.
    • 根据本发明的乙烯/芳族乙烯基化合物/乙烯基降冰片烯三元共聚物通过在催化剂体系下共聚50-90mol%的乙烯,1-55mol%的芳族乙烯基化合物和1-55mol%的乙烯基降冰片烯, 由式(I)表示的过渡金属化合物和助催化剂,其中M表示周期表第IV族的过渡金属,例如钛,锆或铪; Cp'是未取代的环戊二烯基; 具有1至4个烷基取代基的环戊二烯基; 茚基; 取代茚基; 芴基; 或取代的芴基; Y是C1-10的氢或甲硅烷基,C1-10的烷基,C1-10的芳基或它们的组合; A是C1-30的烷基,C1-30的烷基酰胺基或与Cp'相同的环戊二烯基的衍生物; X选自氢原子,卤素原子,烷基,芳基或二烯基。