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1. 发明授权

US09868807B2 Silane-functionalized hydrocarbon polymer modifiers for elastomeric compositions 有权
公开(公告)号：US09868807B2
公开(公告)日：2018-01-16
申请号：US15165241
申请日：2016-05-26
申请人： ExxonMobil Chemical Patents Inc.
发明人： Edward J. Blok , Anthony J. Dias , Robert J. Claassen, II , Eugene R. Uhl
IPC分类号： C08F279/00 , C08L101/10 , B29B9/06 , B60C1/00 , C08C19/25 , C08J3/12 , C08L23/22 , B29D30/06 , C08K3/36 , C08L45/00 , C08L47/00 , C08L101/02 , C08F8/42 , C08L51/00 , C08F10/14 , B29K9/00
CPC分类号： C08F279/00 , B29B9/065 , B29D30/06 , B29K2009/00 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0041 , C08C19/25 , C08F8/42 , C08F10/14 , C08J3/12 , C08J2351/00 , C08K3/36 , C08L21/00 , C08L23/22 , C08L45/00 , C08L47/00 , C08L51/003 , C08L101/02 , C08L101/10 , Y02T10/862 , Y10T156/10 , C08F240/00
摘要： An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof. The method comprises melt processing a mixture to form the elastomeric composition in the shape of an article, wherein the mixture comprises elastomer, Si-HPM, silica, bifunctional organosilane crosslinking agent; and curing the elastomeric composition to form the article. Also disclosed are a silylated hydrocarbon polymer modifier coupled with a bifunctional organosilane crosslinking agent, and a silica-coupled hydrocarbon polymer modifier coupled to the silica via the bifunctional organosilane crosslinking agent.

2. 发明授权

US09481795B2 Underwater pelletizing method for low viscosity hydrocarbon resins 有权
标题翻译：低粘度烃树脂的水下造粒方法
公开(公告)号：US09481795B2
公开(公告)日：2016-11-01
申请号：US13821683
申请日：2011-08-25
申请人： Eugene Ronald Uhl , Edward J. Blok , Dennis Kumor , Randal Howard Kerstetter, III , Ronald DeYoung
发明人： Eugene Ronald Uhl , Edward J. Blok , Dennis Kumor , Randal Howard Kerstetter, III , Ronald DeYoung
IPC分类号： B29B9/06 , C08L101/02 , B60C1/00 , C08C19/25 , C08J3/12 , C08L23/22 , C08F279/00 , B29D30/06 , C08K3/36 , C08L45/00 , C08L47/00 , C08F10/14
CPC分类号： C08F279/00 , B29B9/065 , B29D30/06 , B29K2009/00 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0041 , C08C19/25 , C08F8/42 , C08F10/14 , C08J3/12 , C08J2351/00 , C08K3/36 , C08L21/00 , C08L23/22 , C08L45/00 , C08L47/00 , C08L51/003 , C08L101/02 , C08L101/10 , Y02T10/862 , Y10T156/10 , C08F240/00
摘要： An underwater pelletizing method for pelletizing brittle hydrocarbon resins with low melt viscosity. A feed material comprising the hydrocarbon resin is formed into a melt, extruded through a die into a water bath below the Tg of the hydrocarbon resin to form a plurality of extrudates and cut adjacent the die surface to form a slurry of resin pellets. A graft monomer and/or other reactants, such as a hydrosilylation agent, may be introduced into the resin melt to chemically modify the hydrocarbon resin.
摘要翻译：一种用于造粒具有低熔体粘度的脆性烃树脂的水下造粒方法。将包含烃树脂的进料形成熔体，通过模具挤出到低于烃树脂的Tg的水浴中，以形成多个挤出物，并在模具表面附近切割以形成树脂颗粒的浆料。可以将接枝单体和/或其它反应物（例如氢化硅烷化剂）引入树脂熔体中以化学改性烃树脂。

3. 发明授权

US07513989B1 Hydrocracking process using bulk group VIII/Group VIB catalysts 有权
标题翻译：使用本体VIII / VIB族催化剂的加氢裂化工艺
公开(公告)号：US07513989B1
公开(公告)日：2009-04-07
申请号：US09869990
申请日：2000-01-14
申请人： Stuart Leon Soled , Kenneth Lloyd Riley , Gary P. Schleicher , Richard A. Demmin , Darlene Schuette, legal representative , Ian Alfred Cody
发明人： William L. Schuette
IPC分类号： C10G47/04
CPC分类号： C08F8/00 , B01J23/002 , B01J23/8885 , B01J35/1019 , B01J35/1038 , B01J37/03 , B01J37/04 , B01J37/20 , B01J2523/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847
摘要： The invention relates to a hydrocracking process for hydrocracking petroleum and chemical feedstocks using bulk Group VIII/VIB catalysts. Preferred catalysts include those comprised of Ni—Mo—W.
摘要翻译：本发明涉及使用本体VIII / VIB催化剂加氢裂化石油和化学原料的加氢裂化方法。优选的催化剂包括由Ni-Mo-W组成的催化剂。

4. 发明申请

US20040063853A1 Polyoxymethylene moulding material with improved processing stability and a reduced emissions tendency 审中-公开
标题翻译：聚甲醛成型材料具有改善的加工稳定性和减少的排放倾向
公开(公告)号：US20040063853A1
公开(公告)日：2004-04-01
申请号：US10663290
申请日：2003-09-16
发明人： Stefan Disch , Peter Eckardt , Karl-Friedrich Muck , Gerhard Reuschel , Lothar Reissmann
IPC分类号： C08K003/00
CPC分类号： C08L59/04 , C08F8/04 , C08G2/18 , C08G65/16 , C08F240/00
摘要： Molding compositions made from linear polyoxymethylene copolymers which essentially have oxymethylene units and oxyethylene units as structural units in the polymer chain, where the proportion of oxyethylene units in the structural units of the polymer chain is from 1.5 to 2.5 mol %. These molding compositions, and also uncolored or colored moldings produced from these have high stability and extremely low emission of formaldehyde and of residual monomers. At the same time they have a high level of mechanical properties, and they can therefore be utilized without restriction for the customary application sectors and processing methods.
摘要翻译：由在聚合物链中基本上具有甲醛单元和氧化乙烯单元作为结构单元的直链聚甲醛共聚物制成的成型组合物，其中聚合物链的结构单元中氧乙烯单元的比例为1.5-2.5mol％。这些成型组合物以及由它们生产的未着色或着色的模制品具有高稳定性和极低的甲醛和残余单体的排放。同时它们具有高水平的机械性能，因此可以毫无限制地利用常规应用部门和加工方法。

5. 发明申请

US20030199636A1 Process for synthesizing tackifier resin 有权
标题翻译：合成增粘剂树脂的方法
公开(公告)号：US20030199636A1
公开(公告)日：2003-10-23
申请号：US10458506
申请日：2003-06-10
发明人： Kirkwood Storer Cottman
IPC分类号： C08F114/14
CPC分类号： C08F240/00 , C08F210/14
摘要： This invention is based upon the unexpected discovery that the reactivity of the most important monomers commonly used in synthesizing tackifier resins with aluminum halide catalysts can be enhanced by conducting the polymerization in the presence of an allylic halide. For instance, the conversions of 2-methyl-2-butene, cis-piperylene, and cyclopentene that are attained in polymerizations that are catalyzed with aluminum halide catalysts are increased by conducting the polymerization in the presence of an allylic halide, such as allyl chloride. Increased monomer conversion is of great commercial importance because it leads to an increased level of efficiency and reactor capacity. The present invention more specifically discloses a process for synthesizing a resin having characteristics that make it particularly useful as a tackifier resin, said process comprising the polymerization of an unsaturated hydrocarbon monomer mixture in the presence of aluminum halide and an allylic halide, wherein the unsaturated hydrocarbon monomer mixture is comprised of unsaturated hyrdocarbon monomers containing from about 4 to about 18 carbon atoms, and wherein said process is conducted in the absence of tantalum compounds. The subject invention further reveals a process for synthesizing a resin having characteristics that make it particularly useful as a tackifier resin, said process comprising the polymerization of an unsaturated hydrocarbon monomer mixture in the presence of aluminum halide and an allylic halide, wherein the unsaturated hydrocarbon monomer mixture is comprised of monomers including but not limited to 2-methyl-2-butene, cis-piperylene, trans-piperylene, cyclopentene, and additional unsaturated hyrdocarbon monomers containing from about 4 to about 18 carbon atoms, wherein said process is conducted in the absence of tantalum compounds.
摘要翻译：本发明基于意想不到的发现，通过在烯丙基卤化物存在下进行聚合可以提高通常用于合成增粘树脂与卤化铝催化剂的最重要的单体的反应性。例如，在用卤化铝催化剂催化的聚合中获得的2-甲基-2-丁烯，顺 - 戊间二烯和环戊烯的转化率通过在烯丙基卤化物如烯丙基氯的存在下进行聚合而增加。增加的单体转化率具有很大的商业重要性，因为它导致提高的效率和反应器容量水平。本发明更具体地公开了一种具有使其特别用作增粘树脂的特性的树脂的方法，所述方法包括在卤化铝和烯丙基卤的存在下聚合不饱和烃单体混合物，其中不饱和烃单体混合物由含有约4至约18个碳原子的不饱和羧基碳单体组成，并且其中所述方法在不存在钽化合物的情况下进行。本发明还揭示了一种具有使其特别用作增粘树脂的特性的树脂的方法，所述方法包括在卤化铝和烯丙基卤化物存在下聚合不饱和烃单体混合物，其中不饱和烃单体混合物由包括但不限于2-甲基-2-丁烯，顺式 - 戊间二烯，反式 - 戊间二烯，环戊烯和含有约4至约18个碳原子的其它不饱和羧基碳单体组成的单体组成，其中所述方法在没有钽化合物。

6. 发明申请

US20030083447A1 Petroleum resins and their production with BF3 catalyst 失效
标题翻译：石油树脂及其与BF3催化剂的生产
公开(公告)号：US20030083447A1
公开(公告)日：2003-05-01
申请号：US10242869
申请日：2002-09-13
发明人： Kenneth Lewtas , Maria Leonor Garcia , James Hanley Clark , Karen Wilson
IPC分类号： C08F002/00
CPC分类号： C08F240/00 , C08F4/14 , C08L2666/04 , C09J107/00
摘要： Petroleum resins are produced using a supported BF3 cocatalyst complex Preferably the cocatalyst is organic such as an alcohol or a carboxylic acid. Use of the catalyst in supported form together with the cocatalyst enables control over both Bronsted and Lewis acidity leading to better control of resin properties. Waste disposal and catalyst handling problems are also overcome.
摘要翻译：使用负载的BF 3助催化剂复合物制备石油树脂。优选地，助催化剂是有机的，例如醇或羧酸。使用载体形式的催化剂与助催化剂一起可以控制布朗斯台德和路易斯酸度，从而更好地控制树脂性能。废物处理和催化剂处理问题也得到克服。

7. 发明授权

US06479598B1 Petroleum resins and their production with BF3 catalyst 失效
公开(公告)号：US06479598B1
公开(公告)日：2002-11-12
申请号：US09619419
申请日：2000-07-19
申请人： Kenneth Lewtas , Maria Leonor Garcia , James Hanley Clark , Karen Wilson
发明人： Kenneth Lewtas , Maria Leonor Garcia , James Hanley Clark , Karen Wilson
IPC分类号： C08F204
CPC分类号： C08F240/00 , C08F4/14 , C08L2666/04 , C09J107/00
摘要： Petroleum resins are produced using a supported BF3 cocatalyst complex. Preferably the cocatalyst is organic such as an alcohol or a carboxylic acid. Use of the catalyst in supported form together with the cocatalyst enables control over both Bronsted and Lewis acidity leading to better control of resin properties. Waste disposal and catalyst handling problems are also overcome.

8. 发明申请

US20020086954A1 Petroleum resins and their production with BF3 catalyst 失效
标题翻译：石油树脂及其与BF3催化剂的生产
公开(公告)号：US20020086954A1
公开(公告)日：2002-07-04
申请号：US10006764
申请日：2001-12-06
发明人： Kenneth Lewtas , Maria Leonor Garcia , James Hanley Clark , Karen Wilson
IPC分类号： C08F002/00
CPC分类号： C08F240/00 , C08F4/14 , C08L2666/04 , C09J107/00
摘要： Petroleum resins are produced using a supported BF3 cocatalyst complex. Preferably the cocatalyst is organic such as an alcohol or a carboxylic acid. Use of the catalyst in supported form together with the cocatalyst enables control over both Bronsted and Lewis acidity leading to better control of resin properties. Waste disposal and catalyst handling problems are also overcome.
摘要翻译：使用支撑的BF 3助催化剂络合物制备石油树脂。优选地，助催化剂是有机的，例如醇或羧酸。使用载体形式的催化剂与助催化剂一起可以控制布朗斯台德和路易斯酸度，从而更好地控制树脂性能。废物处理和催化剂处理问题也得到克服。

9. 发明授权

US06278030B1 Process for preparing alcohols by the Oxo process 失效
标题翻译：通过Oxo方法制备醇的方法
公开(公告)号：US06278030B1
公开(公告)日：2001-08-21
申请号：US09483067
申请日：2000-01-14
申请人： Jose Manuel Vargas , Kenneth Lloyd Riley
发明人： Jose Manuel Vargas , Kenneth Lloyd Riley
IPC分类号： C07C2916
CPC分类号： B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41 , C07C31/125
摘要： An improved process for preparing alcohols by the Oxo process. More particularly this invention relates to an improvement in the hydrogenation step of the Oxo process characterized in the use of certain bulk multimetallic hydrogenation catalysts comprised of at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译：通过Oxo方法制备醇的改进方法。更具体地说，本发明涉及Oxo方法的氢化步骤的改进，其特征在于使用由至少一种VIII族非贵金属和至少两种VIB族金属组成的某些本体多金属氢化催化剂。

10. 发明授权

US06232418B1 Process for the production of an aromatic modified resin based on crude C5 失效
标题翻译：基于粗C5制备芳香族改性树脂的方法
公开(公告)号：US06232418B1
公开(公告)日：2001-05-15
申请号：US08876825
申请日：1997-06-17
申请人： Anne Vera Macedo , Martijn Hendrik Willem Burgers , Leonor Ma Garcia , Lutz Erich Jacob , Jozef Aleida Florent Smits , R. Derric Lowery , Jerry Lee Haluska , Charles L. Sims , Frank Carl Jagisch
发明人： Anne Vera Macedo , Martijn Hendrik Willem Burgers , Leonor Ma Garcia , Lutz Erich Jacob , Jozef Aleida Florent Smits , R. Derric Lowery , Jerry Lee Haluska , Charles L. Sims , Frank Carl Jagisch
IPC分类号： C08F24000
CPC分类号： C08F240/00 , C08L2666/02 , C09J153/02
摘要： This invention relates to novel resins, blends of the novel resins with base polymers and a process for producing a resin comprising combining a reactor feed blend comprising: (a) at least 2 weight % of isoprene, (b) at least 2 weight % of one or more of dicyclopentadiene, substituted cyclopentadienes and substituted dicyclopentadienes, (c) at least 2 weight % piperylene, (d) at least 1 weight % aromatic olefins, and (e) 0 to 92 weight % of additional aliphatic olefins, based upon the weight of the reactor feed blend, with a polymerization catalyst under polymerization conditions, preferably where the ratio of component (c) to component (b) is less than 8 and the ratio of component (a) to component (b) is less than 5.
摘要翻译：本发明涉及新型树脂，新型树脂与基础聚合物的共混物和一种生产树脂的方法，包括组合反应器进料共混物，其包括：（a）至少2重量％的异戊二烯，（b）至少2重量％的一个或多个二环戊二烯，取代的环戊二烯和取代的二环戊二烯，（c）至少2重量％的间戊二烯，（d）至少1重量％的芳族烯烃，和（e）0至92重量％的另外的脂族烯烃，反应器进料共混物的重量，在聚合条件下使用聚合催化剂，优选组分（c）与组分（b）的比例小于8，组分（a）与组分（b）的比例小于5 。

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