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1. 发明申请

US20170088639A1 Heterogeneous Ziegler-Natta Catalysts with Fluorided Silica-Coated Alumina 有权
公开(公告)号：US20170088639A1
公开(公告)日：2017-03-30
申请号：US14863575
申请日：2015-09-24
申请人： Chevron Phillips Chemical Company LP
发明人： Errun Ding , Qing Yang , Lloyd W. Guatney , Jeffrey F. Greco
IPC分类号： C08F4/6592 , C08F4/645
CPC分类号： C08F4/65925 , C08F4/6457 , C08F210/16 , C08F2410/04 , C08F4/6543 , C08F4/025 , C08F4/685 , C08F4/6343 , C08F210/14 , C08F2500/04 , C08F2500/01 , C08F2500/12 , C08F2500/17 , C08F110/02 , C08F4/65904
摘要： Catalyst systems containing a Ziegler-Natta catalyst component are disclosed. Such catalyst systems can contain a co-catalyst and a supported catalyst containing a fluorided silica-coated alumina, a magnesium compound, and vanadium and/or tetravalent titanium.

2. 发明授权

US07144964B2 Solution polymerization process utilizing preassembled bimetallic Ziegler-Natta catalyst 失效
标题翻译：溶液聚合法利用预组装的双金属齐格勒 - 纳塔催化剂
公开(公告)号：US07144964B2
公开(公告)日：2006-12-05
申请号：US10921687
申请日：2004-08-19
申请人： Sandor Nagy , Mark P. Mack
发明人： Sandor Nagy , Mark P. Mack
IPC分类号： C08F4/68 , C08F4/72 , C08F4/52
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F2410/03 , C08F4/685 , C08F4/68 , C08F2/06 , C08F4/64079 , C08F4/68198 , C08F4/69
摘要： A high-temperature solution process for polymerizing ethylene is disclosed. The polymerization is performed in the presence of a preassembled bimetallic Ziegler-Natta catalyst and an aluminum compound. Molecular modeling calculations predict that the bimetallic Ziegler-Natta catalyst will have good activity and improved stability versus traditional Ziegler-Natta catalysts. This makes the catalyst especially suitable for solution polymerization processes, which require a thermally robust catalyst.
摘要翻译：公开了用于聚合乙烯的高温溶液方法。在预组装的双金属齐格勒 - 纳塔催化剂和铝化合物的存在下进行聚合。分子模拟计算预测，与传统的齐格勒 - 纳塔催化剂相比，双金属齐格勒 - 纳塔催化剂具有良好的活性和改进的稳定性。这使得催化剂特别适用于需要热稳定催化剂的溶液聚合方法。

3. 发明授权

US06762145B2 Method of making a catalyst for polymerization and co-polymerization of ethylene 失效
标题翻译：制备乙烯聚合和共聚合催化剂的方法
公开(公告)号：US06762145B2
公开(公告)日：2004-07-13
申请号：US09728427
申请日：2000-12-01
申请人： Chun-Byung Yang , Weon Lee , Sang-Yull Kim
发明人： Chun-Byung Yang , Weon Lee , Sang-Yull Kim
IPC分类号： B01J3100
CPC分类号： C08F10/02 , C08F110/02 , C08F4/685 , C08F4/651 , C08F4/6367 , C08F2500/18 , C08F2500/12
摘要： The present invention relates to a catalyst for polymerization and co-polymerization of ethylene. More particularly, the present invention relates to a solid titanium catalyst containing magnesium, wherein said catalyst is produced by preparing a magnesium solution by contact-reacting a halogenated magnesium compound with alcohol; reacting said solution with an ester compound having at least one hydroxy group, or a phosphorous compound and a silicon compound having alkoxy groups; producing a solid component with an adjusted particle morphology by adding a mixture of a titanium compound and a silicon compound; reacting the same with an aluminum compound; and then reacting the same with a titanium compound, or a titanium compound and a vanadium compound. As a result, the catalyst of the present invention has high catalytic activity with excellent catalyst morphology.
摘要翻译：本发明涉及一种用于乙烯聚合和共聚的催化剂。更具体地说，本发明涉及含有镁的固体钛催化剂，其中所述催化剂通过使卤化镁化合物与醇接触反应制备镁溶液来制备; 使所述溶液与具有至少一个羟基的酯化合物或具有烷氧基的磷化合物和硅化合物反应; 通过添加钛化合物和硅化合物的混合物来生产具有调节的颗粒形态的固体组分; 使其与铝化合物反应; 然后使其与钛化合物或钛化合物和钒化合物反应。结果，本发明的催化剂具有高催化活性，催化剂形态优良。

4. 发明申请

US20010031694A1 Catalyst for polymerization and co-polymerization of ethylene 失效
标题翻译：用于聚合和乙烯共聚的催化剂
公开(公告)号：US20010031694A1
公开(公告)日：2001-10-18
申请号：US09728427
申请日：2000-12-01
发明人： Chun-Byung Yang , Weon Lee , Sang-Yull Kim
IPC分类号： B01J031/00 , B01J037/00 , C08F004/02 , C08F004/60
CPC分类号： C08F10/02 , C08F110/02 , C08F4/685 , C08F4/651 , C08F4/6367 , C08F2500/18 , C08F2500/12
摘要： The present invention relates to a catalyst for polymerization and co-polymerization of ethylene. More particularly, the present invention relates to a solid titanium catalyst containing magnesium, wherein said catalyst is produced by preparing a magnesium solution by contact-reacting a halogenated magnesium compound with alcohol; reacting said solution with an ester compound having at least one hydroxy group, or a phosphorous compound and a silicon compound having alkoxy groups; producing a solid component with an adjusted particle morphology by adding a mixture of a titanium compound and a silicon compound; reacting the same with an aluminum compound; and then reacting the same with a titanium compound, or a titanium compound and a vanadium compound. As a result, the catalyst of the present invention has high catalytic activity with excellent catalyst morphology.
摘要翻译：本发明涉及一种用于乙烯聚合和共聚的催化剂。更具体地说，本发明涉及含有镁的固体钛催化剂，其中所述催化剂是通过使卤化镁化合物与醇接触反应制备镁溶液来制备的; 使所述溶液与具有至少一个羟基的酯化合物或具有烷氧基的磷化合物和硅化合物反应; 通过添加钛化合物和硅化合物的混合物来生产具有调节的颗粒形态的固体组分; 使其与铝化合物反应; 然后使其与钛化合物或钛化合物和钒化合物反应。结果，本发明的催化剂具有高催化活性，催化剂形态优良。

5. 发明授权

US3824224A Process for preparing alternating copolymers of butadiene and alphaolefins 失效
标题翻译：制备丁二烯和二羟甲基纤维素交替共聚物的方法
公开(公告)号：US3824224A
公开(公告)日：1974-07-16
申请号：US25959372
申请日：1972-06-05
申请人： MARUZEN PETROCHEM CO LTD
发明人： KAWASAKI A , MARUYAMA I
IPC分类号： C08F210/00 , C08F236/04 , C08F236/06 , C08D1/14 , C08D3/02 , C08D3/06
CPC分类号： C08F236/04 , C08F210/00 , C08F236/06 , C08F4/68 , C08F4/60 , C08F4/685 , C08F4/695 , C08F4/64 , C08F4/025
摘要： A PROCESS FOR PREPARING AN ALTERNATING COPOLYMER OF BUTADIENE AND A-OLEFINE HAVING THE FORMULA O CH2=CHR, WHEREIN R REPRESENTS PHENYL OR A NORMAL OR BRANCHED CHAIN LOWER ALKYL RADICAL, WHICH COMPRISES CONTACTING BUTADIENE AND THE A-OLEFINE IN LIQUID PHASE WITH A CATALYST SYSTEM OF AN ORGANOALUMINUM COMPOUND, A VANADIUM COMPOUND HAVING V-X LINKAGE (X IS HALOGEN) AND A COMPOUND HAVING M-OR LINKAGE (M IS AN ATOM WHOSE ELECTRO NEGATIVITY (H. O. PRITCHARD, CHEM, REV., 55, 745 (1955)) IS LOWER THAN 2.2 AND R IS A HYDROCARBON RADICAL O ALKYL, ARYL, CYCLOALKYL KOR HALOGENATED ETHER RADICAL) OR A COMPOUND HAVING (O-M)X-(0-M'')Y-OR LINKAGE (M IS DEFINED AS ABOVE AND M'' CAN BE DEFINED BY THE SAME DEFINITION GIVEN IN M). OPTIONALLY A HALOGEN ATOM, A HALOGEN CONTAINING COMPOUND, A METAL OXIDE OR A METALLOID OXIDE CAN BE ADDED TO THE ABOVE MENTIONED THREE COMPONENT CATAYAST SYSTEM AS THE FOURTH COMPONENT TO FURTHER IMPROVE THE CATALYTIC PROPERTIES. THE ALTERNATING COPOLYMERS OBTAINED BY THIS INVENTION ARE RUBBER-LIKE IN CHARACTER AND CAN BE USED AS POLYMERIC PLASTICIZERS IN ADHESIVES AND CAN BE VULCANIZED WITH SULFUR OR A SULFUR COMPOUND TO PRODUCE VULCANIZED ELASTOMERS.

6. 发明授权

US3766158A Process for polymerization of olefins 失效
标题翻译：烯烃聚合方法
公开(公告)号：US3766158A
公开(公告)日：1973-10-16
申请号：US3766158D
申请日：1971-06-04
申请人： MITSUBISHI CHEM IND
发明人： YAMAGUCHI K , ENOKIDO N , SARUWATARI H , TANAKA T , OKANO S
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F136/06 , C08F236/04 , C08F1/42 , C08F3/06
CPC分类号： C08F10/00 , C08F136/06 , C08F236/04 , C08F4/685 , C08F4/68
摘要： OLEFIN POLYMERIZATION IS CONDUCTED USING A TWO COMPONENET CATALYST SYSTEM COMPRISING (1) A HYDROCARBON INSOLUBLE SOLID PREPARED BY REDUCING A MIXTURE OF TITANIUM TETRAHALIDE AND TRIALKYL VANADATE WITH AN ORGANO ALUMINUM COMPOUND AND (2) AN ORGANO ALUMINUM COMPOUND.

7. 发明授权

US3723350A Process for the polymerization of olefins 失效
标题翻译：烯烃聚合方法
公开(公告)号：US3723350A
公开(公告)日：1973-03-27
申请号：US3723350D
申请日：1970-08-17
申请人： SCHOLVER CHEMIE AG
发明人： SCHMITT K , GUDE F
IPC分类号： C08F4/68 , C08F10/00 , C08F1/42
CPC分类号： C08F10/00 , C08F4/685 , C08F4/613 , C08F4/6022
摘要： Improved olefin polymerization catalyst made by mixing a titanium tetra halide, a zirconium tetra halide, a titanium tetra ester, a chromium oxyhalide or a mixture thereof with a vanadium oxyhalide or a vanadium tetra halide; reducing such admixture with a dialkylaluminum halide, wherein at least one of the mixture components and/or reductant has a fluorine substituent; and reacting the reduction product with an aluminum trialkyl, and alkyl aluminum halide and/or a dialkyl aluminum halide. In a preferred embodiment, the reaction product is heated to above about 20* C, preferably about 20* to 200* C, to even further improve the catalytic activity thereof.
摘要翻译：通过将四卤化钛，四卤化锆，四钛酸钛，卤氧化铬或其混合物与卤氧化钒或四卤化钒混合来制备的改进的烯烃聚合催化剂; 减少与二烷基卤化铝的混合物，其中至少一种混合物组分和/或还原剂具有氟取代基; 并使还原产物与三烷基铝和烷基铝卤化物和/或二烷基卤化铝反应。在优选的实施方案中，将反应产物加热至约20℃，优选约20至200℃，以进一步提高其催化活性。

8. 发明授权

US3218266A Olefin polymerization catalysts 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US3218266A
公开(公告)日：1965-11-16
申请号：US39000764
申请日：1964-08-17
申请人： DU PONT
发明人： BLODGETT LUDLUM DAVID
IPC分类号： C08F2/00 , C08F4/64 , C08F4/68 , C08F10/00
CPC分类号： C08F10/00 , C08F4/685

9. 发明授权

US3139419A Cocrystallized aluminum chloridevanadium chloride-titanium chloride polymerization catalyst 失效
标题翻译：氯化氯化铵氯化钛 - 氯化钛聚合催化剂
公开(公告)号：US3139419A
公开(公告)日：1964-06-30
申请号：US82771059
申请日：1959-07-17
申请人： EXXON RESEARCH ENGINEERING CO
发明人： ERIK TORNQVIST , ARGABRIGHT PERRY A
IPC分类号： B01J27/06 , C08F10/00
CPC分类号： B01J27/06 , C08F10/00 , Y10S526/906 , C08F4/685

10. 发明申请

US20140178614A1 MONO- AND MULTI-LAYER FILMS AND ARTICLES MADE THEREFROM 审中-公开
标题翻译：单层和多层薄膜及其制品
公开(公告)号：US20140178614A1
公开(公告)日：2014-06-26
申请号：US14175264
申请日：2014-02-07
申请人： Dow Global Technologies LLC
发明人： Mehmet Demirors , Teresa P. Karjala , Nilesh R. Savargaonkar , Rajen M. Patel , Sylvie Desjardins
IPC分类号： C08F210/14
CPC分类号： C08F210/16 , Y10T428/1334 , C08F210/14 , C08F2500/03 , C08F2500/12 , C08F2500/26 , C08F4/685 , C08F4/6545 , C08F2/001
摘要： Mono- and multi-layer films comprising a polyethylene composition which comprises the reaction product of ethylene and optionally one or more alpha olefin comonomers in the presence of a catalyst composition comprising a multi-metallic procatalyst via a solution polymerization process in at least one reactor; wherein said polyethylene composition is characterized by one or more of the following properties: a melt index, I2, measured according to ASTM D 1238 (2.16 kg@190° C.), from 0.1 to 5 g/10 min; density, measured according to ASTM D-792, from 0.910 to 0.935 g/cc; melt flow ratio, I10/I2, wherein I10 is measured according to ASTM D1238 (10 kg@190° C.), from 6 to 7.4; and molecular weight distribution, (Mw/Mn) from 2.5 to 3.5 are provided. Also provided are articles made from the mono- and/or multi-layer films.
摘要翻译：包含聚乙烯组合物的单层和多层膜，其包含乙烯和任选的一种或多种α-烯烃共聚单体的反应产物，所述反应产物在包含至少一个反应器中的溶液聚合方法的多金属前催化剂的催化剂组合物存在下; 其中所述聚乙烯组合物的特征在于一种或多种以下性质：根据ASTM D 1238（2.16kg，190℃）测量的熔体指数I2，为0.1至5g / 10min; 密度，根据ASTM D-792测量，0.910至0.935g / cc; 熔体流动比I10 / I2，其中I10根据ASTM D1238（10kg @ 190℃）测量，为6至7.4; 和分子量分布（Mw / Mn）为2.5〜3.5。还提供了由单层和/或多层膜制成的制品。

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