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    • 7. 发明申请
    • COMB-LIKE POLYURETHANE AND METHODS FOR PREPARING AND USING THE SAME
    • 类似聚氨酯的方法及其制备和使用方法
    • US20160102167A1
    • 2016-04-14
    • US14880306
    • 2015-10-12
    • SICHUAN UNIVERSITYLAVAL UNIVERSITY
    • Xingyi XIEZe ZHANGXiangyang WUQiang FUYinping ZHONG
    • C08G18/72C12N5/071C08G18/28
    • C08G18/72C08G18/10C08G18/28C08G18/34C08G18/48C12N5/0691C12N2501/165C12N2533/30
    • A method for preparing a comb-like polyurethane, including: 1) adding a diol to a reaction vessel, stirring, heating, vacuum dehydrating, and cooling the diol; adding a diisocyanate to the diol, and pre-polymerizing the diisocyanate and the diol under vacuum to yield a polyurethane prepolymer; 2) dissolving lysine in a mixture of water and an organic solvent to yield a first solution, adding the first solution to the polyurethane prepolymer to yield a first reaction mixture; stopping stirring and allowing the first reaction mixture to stand for between 10 and 12 hrs, pouring the first reaction mixture into water, and drying a precipitate to yield a polyurethane elastomer containing carboxyl groups; 3) dissolving the polyurethane elastomer in an organic solvent to yield a second solution; adding an epoxy-terminated polyethylene glycol to the second solution, and stirring a resulting mixture at between 110 and 130° C.
    • 一种制备梳状聚氨酯的方法,包括:1)将二醇加入反应容器中,搅拌,加热,真空脱水,冷却二醇; 在二醇中加入二异氰酸酯,并在真空下使二异氰酸酯和二醇预聚合得到聚氨酯预聚物; 2)将赖氨酸溶解在水和有机溶剂的混合物中以产生第一溶液,将第一溶液加入到聚氨酯预聚物中以产生第一反应混合物; 停止搅拌并使第一反应混合物静置10至12小时,将第一反应混合物倒入水中,干燥沉淀物,得到含有羧基的聚氨酯弹性体; 3)将聚氨酯弹性体溶解在有机溶剂中,得到第二溶液; 向第二溶液中加入环氧基封端的聚乙二醇,并在110-130℃下搅拌所得混合物。