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    • 3. 发明授权
    • Polyurethane elastomers, method of producing them and their use
    • 聚氨酯弹性体,制造方法及其用途
    • US06458866B1
    • 2002-10-01
    • US09051351
    • 1998-05-15
    • Wilhelm OppermannFrank HermanutzPeter HirtMichael SchweizerOliver Oess
    • Wilhelm OppermannFrank HermanutzPeter HirtMichael SchweizerOliver Oess
    • C08G1832
    • D01F6/70C08G18/675C08G18/676C08G18/678C08G18/679Y10S528/906
    • The invention concerns a polyurethane elastomer containing structural units of type (a), in which: the group —O—R1—O—is a macrodiol group with a molecular weight of approximately 500 to 10000, R2 is a bivalent aliphatic, cycloaliphatic and/or aliphatic-cycloaliphatic group; and X is a short-chain olefinically unsaturated group, Y is NH or O, n is an integer from 1 to 10 and m is an integer of at least 4. The invention also concerns a method of preparing this polyurethane elastomer which can be melt-spun to form fibres or melt-extruded to form foils. The fibres or foils can be exposed to energy-rich radiation such that crosslinking of the polyurethane occurs. Fibres according to the invention display superior properties in terms of textile-mechanical properties, in particular good tensile strength, elongation at tear, residual elongation and heat distortion temperature.
    • 本发明涉及含有(a)型结构单元的聚氨酯弹性体,其中:-O-R 1 -O-为分子量约500〜10000的大二醇基,R2为二价脂族,脂环族和/ 或脂肪族 - 脂环族基团; X为短链烯属不饱和基团,Y为NH或O,n为1〜10的整数,m为4以上的整数。本发明还涉及制备该聚氨酯弹性体的方法,该聚氨酯弹性体可熔融 - 纺成纤维或熔融挤出以形成箔。 纤维或箔可以暴露于能量丰富的辐射,从而发生聚氨酯的交联。 根据本发明的纤维在纺织 - 机械性能,特别是良好的拉伸强度,撕裂伸长率,残余伸长率和热变形温度方面表现出优异的性能。
    • 9. 发明申请
    • METHOD FOR FUNCTIONALISING A THERMOSET, CROSSLINKED ISOCYANATE-BASED POLYMERIC SOLID MATERIAL
    • 功能性热交换器,交联的异氰酸酯基聚合物固体材料的方法
    • US20120289621A1
    • 2012-11-15
    • US13470567
    • 2012-05-14
    • Laura JONCKHEEREFilip DU PREZThu NGUYEN
    • Laura JONCKHEEREFilip DU PREZThu NGUYEN
    • C08F8/36C08G18/87
    • C08G18/835C08G18/6745C08G18/675C08G18/679
    • The invention relates to a method for functionalising a thermoset, crosslinked isocyanate-based polymeric solid material which is made of isocyanate and isocyanate reactive components, at least one of which comprises an anchor component which has at least one anchor group. The anchor groups on the solid material are formed by terminal alkene and/or alkyne groups. To functionalise this polymeric solid material it is brought in contact with a solution which contains at least one functional component. This functional component comprises at least one thiol group and is allowed to bind covalently to the polymeric solid material by a free-radical addition reaction between the thiol groups on the functional component and the terminal alkene and/or alkyne anchor groups on the undissolved solid material. An effective functionalisation of the polymeric material can thus be achieved notwithstanding the heterogeneous reaction conditions.
    • 本发明涉及一种用于使由异氰酸酯和异氰酸酯反应性组分制成的热固性交联的异氰酸酯基聚合物固体材料功能化的方法,其中至少一种包含具有至少一个锚定基团的锚固组分。 固体材料上的锚定基团由末端烯烃和/或炔烃基团形成。 为了使该聚合物固体材料功能化,其与含有至少一种官能组分的溶液接触。 该功能组分包含至少一个硫醇基团,并且通过功能组分上的硫醇基团与未溶解固体材料上的末端烯烃和/或炔炔基团之间的自由基加成反应,使其与共聚物固体材料共价键合 。 因此,即使是非均相反应条件,也可以实现聚合物材料的有效官能化。