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    • 7. 发明授权
    • Photosensitive resin precursor composition
    • 感光树脂前体组合物
    • US07507518B2
    • 2009-03-24
    • US10885100
    • 2004-07-07
    • Yoji FujitaTomoyuki YubaMitsuhito Suwa
    • Yoji FujitaTomoyuki YubaMitsuhito Suwa
    • G03F7/021G03F7/023G03F7/30
    • G03F7/0233G03F7/0045G03F7/0751
    • The present invention relates to a positive photosensitive resin precursor composition which exhibits good storage stability after exposure.A photosensitive resin precursor composition comprises (a) a polymer essentially composed of a structural unit expressed by formula (1); (b) at least two photo acid generators; and (c) a compound having an alkoxymethyl group: wherein R1 represents an organic group with a valence of 2 to 8, having at least two carbon atoms; R2 represents an organic group with a valence of 2 to 6, having at least two carbon atoms; R3 represents hydrogen or an organic group having a carbon number in the range of 1 to 20; n represents a number ranging from 10 to 100,000; m represents an integer in the range of 0 to 2; and p and q represent integers in the range of 0 to 4 and satisfy p+q>0.
    • 本发明涉及曝光后显示良好的储存稳定性的正型感光性树脂前体组合物。 光敏树脂前体组合物包含(a)基本上由式(1)表示的结构单元组成的聚合物; (b)至少两个光酸产生剂; 和(c)具有烷氧基甲基的化合物:其中R1表示具有至少两个碳原子的价数为2至8的有机基团; R2表示具有至少2个碳原子的2价至6价的有机基团; R3表示氢或碳数为1〜20的有机基团; n表示10〜100,000的数; m表示0〜2的整数, p和q表示0〜4的整数,满足p + q> 0。
    • 9. 发明授权
    • Negative photosensitive composition and negative photosensitive lithographic printing plate
    • 负感光组合物和负光敏平版印刷版
    • US07291438B2
    • 2007-11-06
    • US10558956
    • 2004-06-17
    • Hideo SakuraiEiji Hayakawa
    • Hideo SakuraiEiji Hayakawa
    • G03F7/021G03F7/031
    • B41C1/1008B41C1/1016B41C2201/02B41C2201/14B41C2210/04B41C2210/06B41C2210/22B41C2210/24G03F7/021G03F7/029
    • There are provided a negative-working photosensitive composition which can be cured by infrared rays and is less likely to suffer polymerization inhibition by oxygen during radical polymerization, and also exhibits high adhesion with a metal, and a negative-working photosensitive lithographic printing plate which is capable of directly forming images by irradiation with infrared rays from a solid or semiconductor laser based on digital signals, and also has high sensitivity and excellent printing durability. The negative-working photosensitive composition contains an infrared absorber (A), an organoboron compound (B) which functions as a polymerization initiator by using in combination with the infrared absorber (A), a compound having a polymerizable unsaturated group (C) and a diazo resin (D), and the negative-working photosensitive lithographic printing plate comprises a support, and a photosensitive layer containing the negative-working photosensitive composition formed on the support.
    • 提供了可以通过红外线固化的负性光敏组合物,并且在自由基聚合期间不太可能遭受氧的聚合抑制,并且还表现出与金属的高粘合性和负性光敏平版印刷版,其是 能够通过基于数字信号从固体或半导体激光器的红外线照射而直接形成图像,并且还具有高灵敏度和优异的印刷耐久性。 负性感光性组合物含有与红外线吸收剂(A)组合使用的作为聚合引发剂的红外线吸收剂(A),有机硼化合物(B),具有聚合性不饱和基团(C)和 重氮树脂(D),负性感光性平版印刷版包括载体和含有形成在载体上的负性感光性组合物的感光层。