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    • 7. 发明申请
    • Si-BLOCK COPOLYMER CORE-SHELL NANOPARTICLES TO BUFFER VOLUMETRIC CHANGE AND ANODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY USING THE SAME
    • 用于缓冲体积变化的硅嵌段共聚物核壳纳米颗粒和使用其的锂二次电池的阳极活性材料
    • US20160285104A1
    • 2016-09-29
    • US15083094
    • 2016-03-28
    • OCI COMPANY LTD.
    • Yo-Seop KIMEun-Hye JEONGSung-Ho JUNGHyung-Rak KIM
    • H01M4/62C08J3/11H01M4/04H01M4/134H01M4/1395
    • H01M4/628C08J3/11C08J2353/00H01M4/0402H01M4/0457H01M4/0471H01M4/134H01M4/1395H01M4/366H01M4/386H01M4/602
    • The Si-block copolymer core-shell nanoparticles include: a Si core; and a block copolymer shell including a block having relatively relatively high affinity for Si and a block having relatively low affinity for Si and forming a spherical micelle structure around the Si core. Since the Si-block copolymer core-shell nanoparticles exhibit excellent dispersibility and stability in a mixed solution including the same, the Si-block copolymer core-shell nanoparticles are easily applied to an anode active material for lithium secondary battery by carbonization thereof. In addition, since the anode active material for lithium secondary battery using the Si-block copolymer core-shell nanoparticles includes carbonized Si-block copolymer core-shell nanoparticles and pores, the anode active material has long lifespan, high capacity and high energy density, and the block copolymer shell of the carbonized Si-block copolymer core-shell nanoparticles can improve lifespan of lithium secondary battery by buffering volumetric change thereof during charge and discharge.
    • Si嵌段共聚物核 - 壳纳米粒子包括:Si核; 以及嵌段共聚物壳,其包括对Si具有相对较高亲和力的嵌段和对Si具有相对低亲和力的嵌段并在Si芯周围形成球形胶束结构。 由于Si嵌段共聚物核 - 壳纳米粒子在包含其的混合溶液中表现出优异的分散性和稳定性,因此通过碳化将Si嵌段共聚物核 - 壳纳米颗粒容易地应用于锂二次电池用负极活性物质。 另外,由于使用了Si嵌段共聚物核 - 壳纳米粒子的锂二次电池用负极活性物质,具有碳化硅嵌段共聚物核 - 壳纳米粒子和细孔,因此阳极活性物质的寿命长,容量大,能量密度高, 碳化硅嵌段共聚物核 - 壳纳米粒子的嵌段共聚物壳可以通过在充放电期间缓冲其体积变化来提高锂二次电池的使用寿命。
    • 8. 发明申请
    • DISPERSIONS FOR NANOPLATELETS OF GRAPHENE-LIKE MATERIALS AND METHODS FOR PREPARING AND USING SAME
    • 类似石墨材料的纳米材料的分散体及其制备和使用方法
    • US20160276056A1
    • 2016-09-22
    • US14901032
    • 2014-06-28
    • GRAPHENE 3D LAB INC.
    • Daniel StolyarovElena PolyakovaIrina Pomestchenko
    • H01B1/24C08J3/11C09D11/38B29C67/00
    • H01B1/24B29C64/165B29C64/40B29K2105/16B33Y10/00B33Y40/00B33Y70/00B33Y80/00B82Y30/00C08J3/11C08J2301/02C09D11/38H01B1/04
    • A dispersion of nanoplatelet graphene-like material, such as graphene nanoplatelets, in a solid or liquid dispersion media wherein the nanoplatelet graphene-like material is dispersed substantially uniformly in the dispersion media with a graphene-like material dispersant. Such dispersions may be used to prepare articles by three-dimensional (3D) printing, as well as to provide electrically conductive inks and coatings, chemical sensors and biosensors, electrodes, energy storage devices, solar cells, etc. Liquid dispersions may be prepared, for example, by sonication of solutions of graphite flakes, dispersant, and liquid dispersion media, while solid dispersions may be prepared, for example, by combining the melted polymer with the liquid dispersion, dissolving the solid polymer in a miscible solvent and then blending with the liquid dispersion, dissolving the solid polymer in the liquid dispersion, or polymerizing one or more monomers in the liquid dispersion to form the solid polymer.
    • 在固体或液体分散介质中的纳米血小板石墨烯样材料(例如石墨烯纳米片)的分散体,其中纳米血小板石墨烯样材料基本上均匀地分散在具有石墨烯类材料分散剂的分散介质中。 这种分散体可用于通过三维(3D)印刷制备制品,以及提供导电油墨和涂层,化学传感器和生物传感器,电极,储能装置,太阳能电池等。可以制备液体分散体, 例如通过超声处理石墨薄片,分散剂和液体分散介质的溶液,而固体分散体可以例如通过将熔融的聚合物与液体分散体组合,将固体聚合物溶解在可混溶的溶剂中,然后与 液体分散体,将固体聚合物溶解在液体分散体中,或在液体分散体中聚合一种或多种单体以形成固体聚合物。