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    • 4. 发明申请
    • FLAME RETARDANT
    • 不易燃的
    • US20120252911A1
    • 2012-10-04
    • US13516464
    • 2010-12-15
    • Christoph FleckensteinHartmut DeneckeIngo BellinOlaf KrihaPatrick SpiesSabine FuchsKlemens MassonneKlaus HahnPeter DeglmannMaximilian HofmannAlois Kindler
    • Christoph FleckensteinHartmut DeneckeIngo BellinOlaf KrihaPatrick SpiesSabine FuchsKlemens MassonneKlaus HahnPeter DeglmannMaximilian HofmannAlois Kindler
    • C07F9/655C07F9/6561C08K5/1535B29B9/06C08J9/16
    • C09K21/12C08J9/0038C08J9/14C08J9/20C08J2325/04C08K5/49C08K5/523C08K5/53C08K5/5313C08K5/5377C08K5/5398C08L2201/02C08L2203/14C08L25/00C08L25/06
    • Use of a phosphorus compound of the formula (I) as flame retardant, where the definitions of the symbols in the formula (I) are as follows: A is one of the following groups: Y is —P(═X2)SR3R4, H, a straight-chain or branched C1-C12-alkyl group, C5-C6-cycloalkyl, C6-C12-aryl, or benzyl, where the four last-mentioned groups are unsubstituted or have substitution by one or more radicals from the group of C1-C4-alkyl or C1-C4-alkenyl; R1, R2, R3, and R4 are identical or different and are hydrogen, OH, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9 COR10, COOR11, CONR12R13 or two radicals R1, R2, R3, or R4 form, together with the phosphorus atom to which they are bonded, or the P—O-A-O—P group, a ring system; R5, R6, R7, and R8 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy; R9, R10, R11, R12, R13 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy; X1 and X2 are identical or different and are S or O; r and s are identical or different and are 0 or 1; X3, X4, X5, and X6 are identical or different and are S or O, and n is a natural number from 1 to 50.
    • 式(I)的磷化合物作为阻燃剂的用途,其中式(I)中的符号的定义如下:A是以下基团之一:Y是-P(= X 2)SR 3 R 4,H 直链或支链C 1 -C 12 - 烷基,C 5 -C 6 - 环烷基,C 6 -C 12 - 芳基或苄基,其中四个最后提到的基团是未取代的或具有一个或多个自由基 C 1 -C 4 - 烷基或C 1 -C 4 - 烯基; R1,R2,R3和R4相同或不同,为氢,OH,C1-C16 - 烷基,C1-C16 - 烯基,C1-C16 - 烷氧基,C1-C16 - 烯氧基,C3-C10-环烷基,C3- C 1 -C 10 - 芳基,C 6 -C 10 - 芳氧基,C 6 -C 10 - 芳基-C 1 -C 16 - 烷基,C 6 -C 10 - 芳基-C 1 -C 16 - 烷氧基,SR 9 COR 10,COOR 11,CONR 12 R 13或两个基团R 1 R 2,R 3或R 4与它们所键合的磷原子一起形成,或与P-OAO-P基团形成环系; R 5,R 6,R 7和R 8相同或不同,为H,C 1 -C 16 - 烷基,C 1 -C 16 - 烯基,C 1 -C 16 - 烷氧基,C 1 -C 16 - 烯氧基; R9,R10,R11,R12,R13相同或不同,为H,C1-C16 - 烷基,C1-C16 - 烯基,C6-C10-芳基,C6-C10-芳基-C1-C16 - 烷基,C6-C10 芳基-C 1 -C 16 - 烷氧基; X1和X2相同或不同,为S或O; r和s相同或不同,为0或1; X3,X4,X5和X6相同或不同,为S或O,n为1〜50的自然数。
    • 7. 发明授权
    • Pneumatic tire
    • 气动轮胎
    • US06197868B1
    • 2001-03-06
    • US09187407
    • 1998-11-06
    • Nobuyuki OkamuraMasahiro Hojo
    • Nobuyuki OkamuraMasahiro Hojo
    • C08K300
    • C08K5/17C08K5/5398C08L21/00
    • A pneumatic tire having a tread layer. A rubber composition of the tread layer includes a specific diene-based rubber component, and either a specific zinc dithiophosphate vulcanization accelerator, or a specific zinc dithiophosphate vulcanization accelerator and a benzothiazole vulcanization accelerator. The zinc dithiophosphate vulcanization accelerator is contained in an amount of 0.2 to 5.0 parts by weight per 100 parts by weight of the rubber component. A molar amount of the benzothiazole vulcanization accelerator is one-half or more of a molar amount of the zinc dithiophosphate vulcanization accelerator. Further, the rubber composition contains a white filler in an amount of 15 parts by weight or more per 100 parts by weight of the rubber component. Produceability of the pneumatic tire is excellent, and a low heat build-up performance thereof is improved without any adverse effects on gripping performance.
    • 一种具有胎面层的充气轮胎。 胎面层的橡胶组合物包括特定的二烯系橡胶成分,特定的二硫代磷酸锌硫化促进剂,特定的二硫代磷酸锌锌硫化促进剂和苯并噻唑硫化促进剂。 二硫代磷酸锌硫化促进剂的含量相对于100重量份的橡胶成分为0.2〜5.0重量份。 苯并噻唑硫化促进剂的摩尔量为二硫代磷酸锌硫化促进剂的摩尔量的一半以上。 此外,橡胶组合物含有每100重量份橡胶组分为15重量份以上的白色填料。 充气轮胎的生产性优异,并且其发热性能低,而对夹持性能没有任何不利影响。
    • 8. 发明授权
    • Pneumatic tire with tread formed with a rubber compound containing a rubber component, a softener and a benzothiazole compound type vulcanization accelerator
    • 具有胎面的气动轮胎与由橡胶组分,软化剂和苯并噻唑化合物型硫化促进剂组成的橡胶混合物形成
    • US06186204B1
    • 2001-02-13
    • US09107431
    • 1998-06-30
    • Naohiro SasakaKazuo YagawaShigeo Kimura
    • Naohiro SasakaKazuo YagawaShigeo Kimura
    • B06C1100
    • C08K5/47B60C1/0016C08K5/5398Y10T152/10495C08L9/06
    • A pneumatic tire comprising a tread portion formed by using a rubber composition which comprises: a rubber component comprising 50 parts by weight or more of SBR in 100 parts by weight of the rubber component; optionally, 5 to 40 parts by weight of aluminum hydroxide per 100 parts of the rubber component; per 100 parts by weight of the rubber component, 20 parts by weight or more of a softener which comprises 5 to 55 parts by weight of a specific resin softener having a softening point of 35 to 150° C.; and per 100 parts by weight of the rubber component, 0.2 to 10.0 parts by weight of a specific vulcanization accelerator of a dithiophosphoric acid compound or a specific vulcanization accelerator of a benzothiazole compound. The pneumatic tire exhibits excellent stability and controllability on wet roads or a combination of excellent stability and controllability on wet roads and excellent comfort of ride even when a vehicle is vibrating throughout the life of the pneumatic tire.
    • 一种充气轮胎,包括通过使用橡胶组合物形成的胎面部分,所述胎面部分包括:在100重量份的所述橡胶组分中包含50重量份或更多的SBR的橡胶组分; 任选地,每100份橡胶组分为5至40重量份的氢氧化铝; 每100重量份的橡胶组分,20重量份或更多的软化剂,其包含5至55重量份的软化点为35至150℃的特定树脂软化剂; 和100重量份的橡胶组分,0.2至10.0重量份的二硫代磷酸化合物的特定硫化促进剂或苯并噻唑化合物的特定硫化促进剂。 充气轮胎在潮湿道路上表现出优异的稳定性和可控性,或者即使当车辆在充气轮胎的整个使用寿命期间振动时,在湿路面上也具有优异的稳定性和可控性的组合,并且具有优异的乘坐舒适性。
    • 9. 发明授权
    • Pneumatic tire
    • 橡胶组成
    • US5939493A
    • 1999-08-17
    • US998551
    • 1997-12-24
    • Masahiro Hojo
    • Masahiro Hojo
    • C08K5/17C08K5/5398C08C19/00
    • C08K5/17C08K5/5398
    • A rubber composition comprising 100 parts by weight of a rubber component which comprises at least one type of rubber selected from the group consisting of natural rubber and diene synthetic rubbers, 0.1 to 10 parts by weight of at least one type of metal dithiophosphate represented by the following general formula, optionally 15 to 85 parts by weight of a reinforcing inorganic filler, and optionally a specific tertiary amine compound in an amount of 0.5 to 15% by weight of the amount of the reinforcing inorganic filler is provided.General formula ##STR1## wherein R.sup.1 and R.sup.3 each independently represents an alkyl group or a cycloalkyl group, M represents an antimony atom, a zinc atom, a copper atom, or an iron atom, and n represents a valency of M.The rubber composition of the present invention exhibits excellent resistance to heat or resistance to heat aging (particularly excellent resistance to hardening and excellent fracture properties).
    • 一种橡胶组合物,其包含100重量份的橡胶组分,其包含至少一种选自天然橡胶和二烯合成橡胶的橡胶,0.1至10重量份的至少一种由 按照通式,可提供任选的15至85重量份的增强无机填料,以及任选的加成无机填料量的0.5至15重量%的特定叔胺化合物。 通式其中R 1和R 3各自独立地表示烷基或环烷基,M表示锑原子,锌原子,铜原子或铁原子,n表示M的化合价。本发明的橡胶组合物 本发明具有优异的耐热性或耐热老化性(特别优异的耐硬化性和优异的断裂性)。