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    • 9. 发明授权
    • (Meth)acrylic polymer particle, method for producing the same, plastisol composition made from the polymer particle, and article made from the plastisol composition
    • (甲基)丙烯酸聚合物颗粒,其制备方法,由聚合物颗粒制成的增塑溶胶组合物和由增塑溶胶组合物制成的制品
    • US08039541B2
    • 2011-10-18
    • US12524255
    • 2008-01-23
    • Satoshi Mae
    • Satoshi Mae
    • C08L33/00C08L33/06
    • C08F265/04C08F265/06C08F285/00C08K5/0016C08L51/003C08L2666/02C09D133/10C09D151/003C09J133/10C09J151/003C09K3/10C09K2200/0625C08F220/18
    • Disclosed are an industrially useful (meth)acrylic polymer particle for use in a plastisol which is excellent in storage stability, particularly under circumstance at 40° C. or above, so that it can suppress gelation and maintain a sol state during storage and which can give a shaped article excellent in flexibility and chipping resistance; a method for producing the (meth)acrylic polymer particle; and a plastisol composition made from the (meth)acrylic polymer particle. Specifically disclosed is a method for producing a (meth)acrylic polymer particle, which comprises polymerizing a monomer or monomer mixture (B) to form a polymer (b) in the presence of a polymer (a) obtained by polymerization of a monomer or monomer mixture (A), wherein a glass transition temperature (Tg) of the polymer (a) as calculated from the FOX equation is 90° C. or above, a solubility parameter of the polymer (a) is 19.90 (J/cm3)1/2 or below, and a solubility parameter of the polymer (b) is 20.22 (J/cm3)1/2 or above.
    • 公开了一种用于增塑溶胶的工业上有用的(甲基)丙烯酸类聚合物颗粒,其储存稳定性优异,特别是在40℃以上的情况下,可以抑制凝胶化并保持溶液状态,并且可以 给出具有优异的柔韧性和耐崩裂性的成型制品; (甲基)丙烯酸系聚合物粒子的制造方法, 和由(甲基)丙烯酸聚合物颗粒制成的增塑溶胶组合物。 具体公开了一种(甲基)丙烯酸系聚合物粒子的制造方法,其特征在于,在单体或单体聚合得到的聚合物(a)的存在下,使单体或单体混合物(B)聚合形成聚合物(b) 混合物(A),其中根据FOX方程计算的聚合物(a)的玻璃化转变温度(Tg)为90℃以上,聚合物(a)的溶解度参数为19.90(J / cm 3)1 / 2以下,聚合物(b)的溶解度参数为20.22(J / cm 3)1/2以上。