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    • 6. 发明申请
    • REDUCTION OF METAL OXIDES IN AN ELECTROLYTIC CELL
    • 减少电解槽中的金属氧化物
    • US20110120881A1
    • 2011-05-26
    • US12961068
    • 2010-12-06
    • LES STREZOVIvan RatchevSteve Osborn
    • LES STREZOVIvan RatchevSteve Osborn
    • C25C1/00
    • C22B5/00C22B34/129
    • A method of reducing a titanium oxide in a solid state in an electrolytic cell which includes an anode, a cathode formed at least in part from the titanium oxide, and a molten electrolyte which includes cations of a metal that is capable of chemically reducing the cathode titanium oxide, which method includes operating the cell at a potential that is above a potential at which cations of the metal that is capable of chemically reducing the cathode titanium oxide deposit as the metal on the cathode, whereby the metal chemically reduces the cathode titanium oxide, and which method is characterised by refreshing the electrolyte and/or changing the cell potential in later stages of the operation of the cell as required having regard to the reactions occurring in the cell and the concentration of oxygen in the titanium oxide in the cell in order to produce high purity titanium.
    • 一种在电解槽中还原固体状态的氧化钛的方法,该方法包括阳极,至少部分由氧化钛形成的阴极,以及包含能够化学还原阴极的金属阳离子的熔融电解质 氧化钛,该方法包括以高于能够化学还原阴极氧化钛的金属的阳离子作为阴极上的金属沉积的电位的电位操作电池,由此金属化学还原阴极氧化钛 并且该方法的特征在于,考虑到细胞中发生的反应和细胞中的氧化钛中的氧浓度,根据需要刷新电解质的后期阶段和/或改变细胞电位 以生产高纯钛。
    • 7. 发明授权
    • Reduction of metal oxides in an electrolytic cell
    • 还原电解槽中的金属氧化物
    • US07918985B2
    • 2011-04-05
    • US10482055
    • 2002-06-28
    • Les StrezovIvan RatchevSteve Osborn
    • Les StrezovIvan RatchevSteve Osborn
    • C25C3/28
    • C22B5/00C22B34/129
    • A method of reducing a titanium oxide in a solid state in an electrolytic cell which includes an anode, a cathode formed at least in part from the titanium oxide, and a molten electrolyte which includes cations of a metal that is capable of chemically reducing the cathode titanium oxide, which method includes operating the cell at a potential that is above a potential at which cations of the metal that is capable of chemically reducing the cathode titanium oxide deposit as the metal on the cathode, whereby the metal chemically reduces the cathode titanium oxide, and which method is characterized by refreshing the electrolyte and/or changing the cell potential in later stages of the operation of the cell as required having regard to the reactions occurring in the cell and the concentration of oxygen in the titanium oxide in the cell in order to produce high purity titanium.
    • 一种在电解槽中还原固体状态的氧化钛的方法,该方法包括阳极,至少部分由氧化钛形成的阴极,以及包含能够化学还原阴极的金属阳离子的熔融电解质 氧化钛,该方法包括以高于能够化学还原阴极氧化钛的金属的阳离子作为阴极上的金属沉积的电位的电位操作电池,由此金属化学还原阴极氧化钛 并且该方法的特征在于,考虑到细胞中发生的反应和细胞中的氧化钛中的氧浓度,根据需要刷新电解质的后期阶段和/或改变细胞电位 以生产高纯钛。
    • 8. 发明授权
    • Electrochemical processing of solid materials in fused salt
    • 熔融盐固体物质的电化学处理
    • US07879219B2
    • 2011-02-01
    • US10497567
    • 2002-12-02
    • Derek John FrayRobert Charles Copcutt
    • Derek John FrayRobert Charles Copcutt
    • C25F3/00C30B9/14C25C3/36
    • C22B34/129C22B5/04C22B9/14C25C3/28
    • The subject invention pertains to methods for processing a solid material (M1X) comprising a solid solution of a non-metal species (X) in a metal or semi-metal (M1) or a compound between the non-metal species and the metal or semi-metal is immersed in a molten salt (M2Y). A cathodic potential is applied to the material to remove a portion of the non-metal species by electro-deoxidation. To remove the non-metal species at lower concentrations, a source of a reactive metal (M3) is immersed in the molten salt and is electronically connected to the material. Reactions occur at the material, where the non-metal species dissolves in the salt, and at the reactive metal, which reacts with the non-metal species dissolved in the salt to form a reaction product more stable than a compound between the non-metal species and the metal or semi-metal (M1). The non-metal species is thus removed from the solid material.
    • 本发明涉及用于处理包含金属或半金属(M1)中的非金属物质(X)的固溶体或非金属物质与金属之间的化合物的固体材料(M1X)的方法,或 将半金属浸入熔融盐(M2Y)中。 通过电脱氧将阴极电势施加到材料上以除去一部分非金属物质。 为了以较低浓度去除非金属物质,将活性金属(M3)的源浸入熔融盐中并与该材料电子连接。 反应发生在非金属物质溶解在盐中的物质和反应性金属,其与溶解在盐中的非金属物质反应形成比非金属化合物更稳定的反应产物 物种和金属或半金属(M1)。 因此,非金属物质从固体材料中除去。