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    • 8. 发明申请
    • FLUORINE-CONTAINING COPOLYMER HAVING EXCELLENT WASHING RESISTANCE AND SOIL RELEASE AGENT
    • 具有优异耐洗涤性和易释放性的含氟聚合物
    • US20100093919A1
    • 2010-04-15
    • US12525434
    • 2008-01-22
    • Norimasa Uesugi
    • Norimasa Uesugi
    • C08L27/12C08F220/22C08L31/00
    • D06M15/277D06M15/27D06M15/295D06M2200/11D06M2200/12
    • Disclosed is a soil release agent composition essentially containing a fluorine-containing copolymer, which is essentially composed of (a) a fluorine-containing monomer having a fluoroalkyl group, (b) a polyalkyleneglycol (meth)acrylate, (c) a monomer having an acetoacetyl group and (d) a monomer having a cation-donating group, and a crosslinking agent. This soil release agent composition imparts a base material such as a fiber fabric with excellent oil repellency, antifouling property and soil releasing property, while maintaining washing resistance of the base material. The monomer (a) is preferably represented by the following formula (1). CH2═C(—X)—C(═O)—Y-Z-Rf  (1) (In the formula, X represents a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom or the like; Y represents —O— or —NH—; Z represents an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-18 carbon atoms, an alicyclic group or the like; and Rf represents a linear or branched fluoroalkyl group having 1-21 carbon atoms.)
    • 公开了基本上含有含氟共聚物的去污剂组合物,其基本上由(a)具有氟代烷基的含氟单体,(b)聚亚烷基二醇(甲基)丙烯酸酯,(c)具有 乙酰乙酰基和(d)具有阳离子供体基团的单体和交联剂。 这种去污剂组合物赋予基材,例如纤维织物,具有优异的拒油性,防污性和剥离性,同时保持基材的耐洗涤性。 单体(a)优选由下式(1)表示。 CH2 = C(-X)-C(= O)-YZ-Rf(1)(式中,X表示氢原子,碳原子数1〜21的直链或支链烷基,氟原子,氯原子 Y表示-O-或-NH-,Z表示碳原子数1〜10的脂肪族基,碳原子数6〜18的芳香族基,脂环基等,Rf表示直链状或 具有1-21个碳原子的支链氟代烷基)