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    • 9. 发明授权
    • Polymer dispersions containing starch
    • 含淀粉的聚合物分散体
    • US06835767B2
    • 2004-12-28
    • US10344118
    • 2003-02-07
    • Ingolf KühnRudolf Schuhmacher
    • Ingolf KühnRudolf Schuhmacher
    • C08F222
    • D21H21/16C08B31/00C08F251/00C08F251/02C09D151/02D21H17/28D21H17/43
    • A polymer dispersion is prepared by copolymerization of from 20 to 70 parts by weight of a monomer mixture comprising a) from 2.5 to 100% by weight of one or more (meth)acrylates of monohydric, saturated C3-C8-alcohols as monomers A and b) from 0 to 97.5% by weight of one or more further ethylenically unsaturated monomers as monomers B in 100 parts by weight of an aqueous solution which contains from 5 to 35% by weight of a starch or of a starch derivative by emulsion polymerization in the presence of an initiator containing peroxide groups, by a process in which the initiator and monomers are metered in continuously and wherein, a first amount of initiator is metered in over a first feed period of from 5 to 60 minutes and a second amount of initiator is metered in over a second feed period of from 15 to 180 minutes, the first amount of initiator being greater than the second amount of initiator.
    • 通过共聚20至70重量份的单体混合物制备聚合物分散体,所述单体混合物包含a)2.5至100重量%的一种或多种(甲基)丙烯酸酯作为单体A的一元饱和C 3 -C 8醇,和b) 0至97.5重量%的一种或多种其它烯键式不饱和单体作为单体将100重量份的含有5至35重量%淀粉或淀粉衍生物的水溶液在存在下通过乳液聚合 含有过氧化物基团的引发剂,其中引发剂和单体连续计量的方法,其中第一量的引发剂在5至60分钟的第一进料周期内计量,并且将第二量的引发剂计量加入 在15至180分钟的第二进料周期内,第一量的引发剂大于第二量引发剂。