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    • 7. 发明申请
    • PRODUCT OF POLYSILOXANE CONDENSATION
    • 多异氰酸酯缩合产物
    • US20120100298A1
    • 2012-04-26
    • US13380630
    • 2010-06-24
    • Reiko MoriyamaHideo SaitoSyouzou TakadaIchirou Doi
    • Reiko MoriyamaHideo SaitoSyouzou TakadaIchirou Doi
    • B05D5/00C08K5/05B05D3/00C08K5/07C08K5/10C08L83/04C08K5/06
    • C08L83/04C08G77/02C08G77/04C08K3/36C08K2201/016H01L21/02123H01L21/02208H01L21/02282H01L21/3121H01L51/448Y10T428/31663C08L83/00
    • Provided is a condensation reaction product solution which is particularly suitable for filling a trench formed on a substrate having a narrow width and a high aspect ratio. The condensation reaction product solution has a long pot life, superior trench-filling when used for trench-filling, and a low cure shrinkage, an excellent crack resistance and a HF resistance when cured and converted into silicon oxide. The condensation reaction product solution comprises (I) a condensation reaction product obtained by condensation reaction from a condensation component comprising (i) 40% by mass or more and 99% by mass or less in equivalent of condensate of polysiloxane compound derived from silane compounds represented by the general formula (1): R1nSiX14-n (wherein n is an integer of 0 to 3, R1 is hydrogen atom or a C1-10 hydrocarbon group, and X1 is a halogen atom, a C1-6 alkoxy group or acetoxy group) and (ii) 1% by mass or more and 60% by mass or less of silica particles, and (II) a solvent, wherein the silane compounds represented by the general formula (1) are two or more types of silane compounds comprising a tetrafunctional silane compound which corresponds to the case of n=0 in the general formula (1) and a trifunctional silane compound which corresponds to the case of n=1 in the general formula (1).
    • 提供了一种缩合反应产物溶液,其特别适用于填充形成在具有窄宽度和高纵横比的基底上的沟槽。 缩合反应产物溶液具有长的适用期,用于沟槽填充时具有优异的沟槽填充性,并且固化和转化为氧化硅时具有低固化收缩率,优异的抗裂性和耐HF性。 缩合反应产物溶液包含(I)通过缩合反应得到的缩合反应产物,该缩合反应产物包含(i)40质量%以上且99质量%以下,相当于衍生自表示的硅烷化合物的聚硅氧烷化合物的缩合物 通式(1)表示:R1nSiX14-n(其中n为0〜3的整数,R1为氢原子或C1-10烃基,X1为卤素原子,C1-6烷氧基或乙酰氧基) )和(ii)1质量%以上且60质量%以下的二氧化硅颗粒,和(II)溶剂,其中由通式(1)表示的硅烷化合物是两种或更多种类型的硅烷化合物,其包含 对应于通式(1)中n = 0的情况的四官能硅烷化合物和通式(1)中n = 1的情况下的三官能性硅烷化合物。