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1. 发明授权

US09701553B2 Copper recovery apparatus 有权
公开(公告)号：US09701553B2
公开(公告)日：2017-07-11
申请号：US14297227
申请日：2014-06-05
申请人： Kabushiki Kaisha Toshiba
发明人： Taro Fukaya , Kenji Tsutsumi , Atsushi Yamazaki , Ichiro Yamanashi , Hirofumi Noguchi , Yasutaka Kikuchi , Shuji Seki
IPC分类号： C02F1/00 , C02F1/48 , C02F1/52 , C02F1/20 , C02F101/20
CPC分类号： C02F1/5281 , C02F1/001 , C02F1/488 , C02F1/5245 , C02F2101/20 , C02F2201/48 , C02F2209/06 , Y10S210/912
摘要： According to one embodiment, a copper recovery apparatus includes a precipitation tank, a mixing tank, a filter-aid feeder, a solid-liquid separator includes a filter, a cleaning-water supply line, a cleaning-water discharge line, a separation tank, and a filter-aid return line. The precipitation tank is configured to receive copper ions-containing water to be treated and an alkali to prepare treated water containing a precipitate of copper compound. The solid-liquid separator is configured to allow the treated water to be passed through the filter on which the precoat layer is deposited to separate the precipitate retained on the precoat layer from a filtrate.

2. 发明授权

US08986541B2 Copper recovery apparatus 有权
标题翻译：铜回收装置
公开(公告)号：US08986541B2
公开(公告)日：2015-03-24
申请号：US13491399
申请日：2012-06-07
申请人： Taro Fukaya , Kenji Tsutsumi , Atsushi Yamazaki , Ichiro Yamanashi , Hirofumi Noguchi , Yasutaka Kikuchi , Shuji Seki
发明人： Taro Fukaya , Kenji Tsutsumi , Atsushi Yamazaki , Ichiro Yamanashi , Hirofumi Noguchi , Yasutaka Kikuchi , Shuji Seki
IPC分类号： B03C1/01 , B03C1/30 , B03C1/32 , C02F1/00 , C02F1/52 , C02F1/58 , C02F1/62 , C02F1/66 , C02F1/48 , C02F101/20
CPC分类号： C02F1/5281 , C02F1/001 , C02F1/488 , C02F1/5245 , C02F2101/20 , C02F2201/48 , C02F2209/06 , Y10S210/912
摘要： According to one embodiment, a copper recovery apparatus includes a precipitation tank, a mixing tank, a filter-aid feeder, a solid-liquid separator includes a filter, a cleaning-water supply line, a cleaning-water discharge line, a separation tank, and a filter-aid return line. The precipitation tank is configured to receive copper ions-containing water to be treated and an alkali to prepare treated water containing a precipitate of copper compound. The solid-liquid separator is configured to allow the treated water to be passed through the filter on which the precoat layer is deposited to separate the precipitate retained on the precoat layer from a filtrate.
摘要翻译：根据一个实施例，一种铜回收装置包括沉淀池，混合罐，助滤剂进料器，固液分离器包括过滤器，清洁水供应管线，清洗水排出管线，分离罐，和一个助滤剂返回管线。沉淀池被配置为接收待处理的含铜离子的水和碱，以制备含有铜化合物沉淀物的处理水。固 - 液分离器被配置成允许处理过的水通过其上沉积预涂层的过滤器，以从滤液中分离保留在预涂层上的沉淀物。

3. 发明申请

US20140377152A1 COPPER RECOVERY APPARATUS AND COPPER RECOVERY METHOD 审中-公开
标题翻译：铜回收装置和铜回收方法
公开(公告)号：US20140377152A1
公开(公告)日：2014-12-25
申请号：US14477988
申请日：2014-09-05
申请人： Kabushiki Kaisha Toshiba
发明人： Taro Fukaya , Kenji Tsutsumi , Atsushi Yamazaki , Ichiro Yamanashi , Hirofumi Noguchi , Yasutaka Kikuchi , Shuji Seki
IPC分类号： C22B15/00 , B03C1/30 , B01D37/02
CPC分类号： C22B15/0089 , B01D37/02 , B03C1/01 , B03C1/30 , B03C1/32 , B03C2201/18 , C02F1/00 , C02F1/001 , C02F1/52 , C02F1/58 , C02F1/66 , C02F2101/20 , Y10S210/912
摘要： According to one embodiment, a copper recovery apparatus includes a precipitation tank configured to precipitate copper hydroxide grains in water, a filter aid supplier, a mixing tank configured to mix the filter aid with a water to produce a suspension, a separator provided with a filter, a line configured to supply the suspension to the separator, thereby forming a precoat layer formed of the filter aid on the filter, a separation tank configured to receive the detached matter of the precoat layer discharged together with the detaching water from the separator to magnetically separate copper hydroxide grains and filter aid, a line configure to discharge and recover the detaching water from the separation tank, and a line configured to return the separated filter aid to the filter aid supplier from the separation tank.
摘要翻译：根据一个实施方案，一种铜回收装置包括：沉淀池，其配置成在水中沉淀氢氧化铜颗粒;助滤剂供应商;混合罐，其配置成将助滤剂与水混合以产生悬浮液; ，被配置为将悬浮液供应到分离器的线，从而在过滤器上形成由助滤剂形成的预涂层;分离罐，其构造成将与分离水一起排出的预涂层的分离物质从分离器接收到磁性单独的氢氧化铜颗粒和助滤剂，配置为从分离罐排出和回收分离水的管线，以及被配置为将分离的助滤剂从分离罐返回到助滤剂供应器的管线。

4. 发明申请

US20140286839A1 PROCESS FOR THE SELECTIVE REMOVAL OF MOLYBDENUM FROM A SOLUTION CONTAINING IT 有权
标题翻译：从含有它的溶液中选择性去除莫来石的方法
公开(公告)号：US20140286839A1
公开(公告)日：2014-09-25
申请号：US13885504
申请日：2011-11-25
申请人： Andrea Bartolini , Emilio Sentimenti
发明人： Andrea Bartolini , Emilio Sentimenti
IPC分类号： C22B34/34
CPC分类号： C22B34/34 , C01G39/003 , C22B3/0031 , C22B3/20 , C22B7/007 , C22B7/009 , C22B34/225 , C22B34/345 , Y02P10/214 , Y02P10/23 , Y02P10/234 , Y10S210/912
摘要： The present invention relates to a process for selectively removing molybdenum from a solution which contains molybdenum, said process comprising the following steps: bringing the solution to an acid pH lower than or equal to 3, preferably lower than or equal to 2, even more preferably lower than or equal to 0.5, by the addition of an inorganic acid; adding at least one organic solvent, preferably toluene or xylene, to the solution and stirring continuously so as to create a water-organic emulsion; adding to the water-organic emulsion at least one alkaline metal xanthate having the general formula MeRX, wherein R is a linear or branched alkyl group having a number of carbon atoms higher than or equal to 2, Me is an alkaline metal selected from Li, Na, K, Rb, Cs and Fr, and X is the xanthate group, so as to form a complex with molybdenum wherein the molar ratio molybdenum/alkaline metal xanthate ranges from 1/6 to 1/2, keeping the emulsion at an acid pH by the addition of an inorganic acid, and interrupting the stirring so as to allow the separation of the aqueous phase from the organic phase. The linear or branched alkyl group R preferably has a number of carbon atoms higher than or equal to 2 and lower than or equal to 12. A reductant is optionally added to the starting solution which comprises Mo and V.
摘要翻译：本发明涉及从含有钼的溶液中选择性除去钼的方法，所述方法包括以下步骤：使溶液的pH低于或等于3，优选低于或等于2，甚至更优选低于或等于0.5，通过加入无机酸; 向溶液中加入至少一种有机溶剂，优选甲苯或二甲苯，并连续搅拌，以产生水 - 有机乳液; 向所述水 - 有机乳液中加入至少一种具有通式MeRX的碱金属黄原酸盐，其中R是具有高于或等于2个碳原子数的直链或支链烷基，Me是选自Li， Na，K，Rb，Cs和Fr，X是黄原酸酯基，以便与钼形成络合物，其中钼/碱金属黄原酸酯的摩尔比为1/6至1/2，将乳液保持在酸通过添加无机酸的pH，并且中断搅拌以使水相与有机相分离。直链或支链烷基R优选具有高于或等于2且低于或等于12的碳原子数。还原剂任选地加入到包含Mo和V的起始溶液中。

5. 发明申请

US20140069873A1 Acidic Mine Water Remediation 失效
标题翻译：酸性矿泉水补救
公开(公告)号：US20140069873A1
公开(公告)日：2014-03-13
申请号：US13978592
申请日：2012-04-30
申请人： David Crosby
发明人： David Crosby
IPC分类号： C02F1/28
CPC分类号： C02F1/285 , B01J20/22 , B01J20/28047 , B01J2220/4893 , B01J2220/62 , C02F1/281 , C02F1/288 , C02F1/62 , C02F2101/20 , C02F2101/203 , C02F2101/206 , C02F2101/22 , C02F2103/10 , C07F7/16 , Y10S210/912 , Y10S210/913
摘要： A process for treating acidic mine drainage water to remove heavy metal ions is described in which acidic mine drainage water is contacted with direct process residue gel.
摘要翻译：描述了一种处理酸性矿井排水以除去重金属离子的方法，其中酸性矿井排水与直接工艺残渣凝胶接触。

6. 发明授权

US08377310B2 Method and composition for sorbing toxic substances 失效
标题翻译：吸附有毒物质的方法和组成
公开(公告)号：US08377310B2
公开(公告)日：2013-02-19
申请号：US12777331
申请日：2010-05-11
申请人： Joseph Iannicelli
发明人： Joseph Iannicelli
IPC分类号： C02F1/42
CPC分类号： B01J20/06 , B01J20/0229 , B01J20/0259 , B01J20/0285 , B01J20/045 , B01J20/08 , B01J20/3078 , B01J20/3085 , B01J2220/4887 , C02F1/281 , C02F2101/20 , C02F2101/22 , C02F2103/06 , C02F2103/10 , C10G25/003 , Y10S95/90 , Y10S210/912 , Y10S210/913 , Y10S210/914
摘要： Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.
摘要翻译：使用吸附剂组合物从介质中提取有毒物质如重金属。吸附剂组合物是通过红泥硫化产生的，该泥浆含有源于铝土矿的拜耳处理的水合氧化铁。示例性硫化化合物是H 2 S，Na 2 S，K 2 S，（NH 4）2 S和CaS x。硫含量通常比红泥中的残留硫高约0.2至约10％。与大部分测试重金属（Hg，Cr，Pb，Cu，Zn，Cd，Se，Th和U）的红泥相比，硫化红泥是一种改进的吸附剂。与红泥不同，硫化红泥不会浸出天然含有的金属。硫化红泥还可防止与红泥混合时金属浸出。硫化红泥和红泥的混合物比单独硫化红泥更有效地吸附其他离子，如As，Co，Mn和Sr。

7. 发明授权

US07967990B2 Hybrid chemical/mechanical dewatering method for inactivating and removing pharmaceuticals and other contaminants from wastewater 有权
标题翻译：用于灭活和除去废水中药物和其他污染物的混合化学/机械脱水方法
公开(公告)号：US07967990B2
公开(公告)日：2011-06-28
申请号：US12220265
申请日：2008-07-23
申请人： Marcus G. Theodore
发明人： Marcus G. Theodore
IPC分类号： C02F1/62 , C02F1/70 , C02F1/72
CPC分类号： C02F1/66 , C02F1/52 , C02F1/70 , C02F1/722 , C02F11/121 , C02F11/14 , C02F2101/105 , C02F2101/20 , C02F2303/02 , C02F2303/04 , Y10S210/906 , Y10S210/908 , Y10S210/912
摘要： A hybrid chemical/mechanical dewatering sewage treatment plant and method employing rapid sludge chemical dewatering technology in conjunction with slower conventional mechanical dewatering solids agglomeration and disposal methods to meet operating constraints and environmental permitting restrictions and siting limitations for disposal of sewage and wastewater.
摘要翻译：混合化学/机械脱水污水处理厂和采用快速污泥化学脱水技术的方法，结合较慢的常规机械脱水固体聚集和处理方法，以满足处理污水和废水的操作限制和环境许可限制和选址限制。

8. 发明授权

US07943049B1 Water purification method using plant molecules 有权
标题翻译：使用植物分子的水净化方法
公开(公告)号：US07943049B1
公开(公告)日：2011-05-17
申请号：US11934932
申请日：2007-11-05
申请人： Norma A. Alcantar , Babu Joseph , Kevin Young
发明人： Norma A. Alcantar , Babu Joseph , Kevin Young
IPC分类号： C02F1/54 , C02F1/62
CPC分类号： C02F1/5263 , C02F2101/103 , C02F2101/20 , Y10S210/911 , Y10S210/912
摘要： Arsenic is a poisonous metalloid which, because of its hydroscopic nature, is primarily transported through water. Most plant species, including the nopal cactus, produce a sticky substance called mucilage. Mucilage swells in water but is insoluble and can precipitate ions, bacteria and particles from aqueous solutions. The invention includes a method of separating particulates and heavy metals such as arsenic (As) from drinking water using natural flocculants obtained from cactus mucilage. The extraction techniques and the methodology for using the cactus mucilage obtain higher As removal than conventional methods, like aluminum sulfate precipitation.
摘要翻译：砷是一种有毒的准金属，由于其吸水性，主要通过水输送。大多数植物物种，包括胭脂仙人掌，产生一种称为粘液的粘性物质。水溶性溶胀不溶，可能会从水溶液中沉淀离子，细菌和颗粒。本发明包括使用从仙人掌胶浆获得的天然絮凝剂从饮用水中分离出砷（As）的微粒和重金属的方法。提取技术和使用仙人掌胶浆的方法比常规方法（如硫酸铝沉淀）获得更高的As去除。

9. 发明授权

US07914676B2 Method for removing sulphate and heavy metals from waste water 有权
标题翻译：从废水中去除硫酸盐和重金属的方法
公开(公告)号：US07914676B2
公开(公告)日：2011-03-29
申请号：US12377229
申请日：2007-08-10
申请人： Michael Riebensahm
发明人： Michael Riebensahm
IPC分类号： C02F3/28 , C02F3/34
CPC分类号： C02F1/5236 , C02F3/34 , C02F3/345 , C02F9/00 , C02F2101/101 , C02F2101/20 , C02F2301/046 , C02F2303/16 , C02F2303/18 , Y10S210/912
摘要： In a method for removing sulphate and heavy metals from waste water: a) in a first treatment step (I) hydrogen sulphide is guided through the waste water, heavy metals that are present in the waste water are precipitated as sulphide, and are removed from the waste water, b) in a second treatment step (II), calcium sulphate is precipitated from the waste water by adding a precipitation auxiliary agent, c) the calcium sulphate is removed in the second treatment step (II) and one part thereof is guided to a third treatment step (III) in which sulphate is converted into hydrogen sulphide with the aid of sulphate-reducing bacteria, d) hydrogen sulphide formed in the third treatment step (III) is guided back to the first treatment step (I).
摘要翻译：在从废水中除去硫酸盐和重金属的方法中：a）在第一处理步骤（I）中，将硫化氢引导通过废水，存在于废水中的重金属作为硫化物沉淀，并从废水，b）在第二处理步骤（II）中，通过加入沉淀助剂从废水中沉淀出硫酸钙，c）在第二处理步骤（II）中除去硫酸钙，其一部分为引导到第三处理步骤（III），其中借助硫酸盐还原细菌将硫酸盐转化为硫化氢，d）在第三处理步骤（III）中形成的硫化氢被引导回到第一处理步骤（I）。

10. 发明授权

US07871524B2 Method for removing merury and/or arsenic from water using a silane coupling agent reacted organoclay 有权
标题翻译：使用硅烷偶联剂从水中除去汞和/或砷的方法与有机粘土反应
公开(公告)号：US07871524B2
公开(公告)日：2011-01-18
申请号：US11810240
申请日：2007-06-05
申请人： Zhen Wang , Robert Abraham
发明人： Zhen Wang , Robert Abraham
IPC分类号： C02F1/28
CPC分类号： C02F1/288 , C02F1/281 , C02F1/285 , C02F2101/103 , C02F2101/20 , Y10S210/912 , Y10S210/914
摘要： The use of a coupling agent containing a mercapto, disulfide, tretrasulfide and/or polysulfide end group provides a mercury removal media having increased reactivity, stability, and mercury removal ability. The mercury removal media described herein is prepared by reacting an organophilic clay containing onium ions with a mercapto, disulfide, tetrasulfide, and/or polysulfide end moiety. Alternatively, the clay can be made organophilic by onium ion reaction prior to or simultaneously with the coupling reaction of the mercapto- or sulfide- end group-containing coupling agent.
摘要翻译：使用含有巯基，二硫化物，四硫化硫和/或多硫化物末端基团的偶联剂提供了具有增加的反应性，稳定性和除汞能力的汞去除介质。本文所述的除汞介质通过使含有鎓离子的亲有机粘土与巯基，二硫化物，四硫化物和/或多硫末端部分反应来制备。或者，在含巯基或硫末端基的偶联剂的偶联反应之前或同时，可以通过鎓离子反应将粘土制成亲有机物。

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