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1. 发明授权

US08168070B2 Method for removing chromium from water using ion exchange resins including interpenetrating polymer networks 有权
标题翻译：使用包括互穿聚合物网络的离子交换树脂从水中除去铬的方法
公开(公告)号：US08168070B2
公开(公告)日：2012-05-01
申请号：US12634709
申请日：2009-12-10
申请人： Daryl J. Gisch , Jing Jin
发明人： Daryl J. Gisch , Jing Jin
IPC分类号： C02F1/42
CPC分类号： C02F1/42 , B01J41/05 , C02F1/66 , C02F2001/422 , C02F2101/22 , C02F2103/06 , C08F8/24 , C08F8/44 , C08F257/02 , C08F285/00 , C08L51/003 , C08L2205/04 , Y10S210/913 , C08F212/36 , C08L2666/02
摘要： The invention includes ion exchange resins and their use in the removal of chromium from water. In one embodiment, the invention comprises a method for removing chromium from a water source by contacting the water with an ion exchange resin, wherein the ion exchange resin comprises particles of a crosslinked copolymer comprising: an interpenetrating polymer network (IPN) of at least two polymer components each having a styrenic content greater than 50 molar percent, and a quaternary ammonium functionality.
摘要翻译：本发明包括离子交换树脂及其在从水中除去铬中的用途。在一个实施方案中，本发明包括通过使水与离子交换树脂接触从水源除去铬的方法，其中所述离子交换树脂包含交联共聚物颗粒，所述交联共聚物包含：至少两个的互穿聚合物网络（IPN）各自具有大于50摩尔％的苯乙烯含量的聚合物组分和季铵官能团。

2. 发明授权

US07897049B2 Methods for treating water using iron 有权
标题翻译：用铁处理水的方法
公开(公告)号：US07897049B2
公开(公告)日：2011-03-01
申请号：US11749448
申请日：2007-05-16
申请人： Rajat S. Ghosh , Dennis Fulmer , Kevin Kitzman , John Smith
发明人： Rajat S. Ghosh , Dennis Fulmer , Kevin Kitzman , John Smith
IPC分类号： C02F1/62 , C02F1/70 , C02F101/18 , C02F101/22
CPC分类号： C02F1/705 , C02F1/283 , C02F1/286 , C02F2101/103 , C02F2101/18 , C02F2101/22 , C02F2103/16 , C02F2209/04 , Y10S210/904 , Y10S210/911 , Y10S210/912 , Y10S210/913
摘要： Systems and associated methods for treating contaminant-containing wastewater are provided. The systems generally include a reducing zone for reducing the oxidation-reduction potential of the water and a clean-up zone comprising zero valent iron for removing at least a portion of the contaminant from the contaminant-containing water. The systems are operable to remove one or more contaminants from the contaminant-containing water and are operable for extended durations without clogging due to the formation of iron hydroxides.
摘要翻译：提供了处理含污染废水的系统和相关方法。该系统通常包括用于降低水的氧化还原电位的还原区和包含用于从含污染物的水中去除至少一部分污染物的零价铁的净化区。该系统可操作以从含污染物的水中除去一种或多种污染物，并且由于氢氧化铁的形成而可延长持续时间而不堵塞。

3. 发明申请

US20100218676A1 Method and Composition For Sorbing Toxic Substances 审中-公开
标题翻译：吸附有毒物质的方法和组成
公开(公告)号：US20100218676A1
公开(公告)日：2010-09-02
申请号：US12781955
申请日：2010-05-18
申请人： Joseph Iannicelli
发明人： Joseph Iannicelli
IPC分类号： B01D53/02 , C02F1/28 , C02F1/62 , B01D53/46 , B01D15/00 , C07C7/12
CPC分类号： B01J20/06 , B01J20/0229 , B01J20/0259 , B01J20/0285 , B01J20/045 , B01J20/08 , B01J20/3078 , B01J20/3085 , B01J2220/4887 , C02F1/281 , C02F2101/20 , C02F2101/22 , C02F2103/06 , C02F2103/10 , C10G25/003 , Y10S95/90 , Y10S210/912 , Y10S210/913 , Y10S210/914
摘要： Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.
摘要翻译：使用吸附剂组合物从介质中提取有毒物质如重金属。吸附剂组合物是通过红泥硫化产生的，该泥浆含有源于铝土矿的拜耳处理的水合氧化铁。示例性硫化化合物是H 2 S，Na 2 S，K 2 S，（NH 4）2 S和CaS x。硫含量通常比红泥中的残留硫高约0.2至约10％。与大部分测试重金属（Hg，Cr，Pb，Cu，Zn，Cd，Se，Th和U）的红泥相比，硫化红泥是一种改进的吸附剂。与红泥不同，硫化红泥不会浸出天然含有的金属。硫化红泥还可防止与红泥混合时金属浸出。硫化红泥和红泥的混合物比单独硫化红泥更有效地吸附其他离子，如As，Co，Mn和Sr。

4. 发明授权

US07763566B2 Method and composition for sorbing toxic substances 失效
标题翻译：吸附有毒物质的方法和组成
公开(公告)号：US07763566B2
公开(公告)日：2010-07-27
申请号：US11277282
申请日：2006-03-23
申请人： Joseph Iannicelli
发明人： Joseph Iannicelli
IPC分类号： B01J20/02
CPC分类号： B01J20/06 , B01J20/0229 , B01J20/0259 , B01J20/0285 , B01J20/045 , B01J20/08 , B01J20/3078 , B01J20/3085 , B01J2220/4887 , C02F1/281 , C02F2101/20 , C02F2101/22 , C02F2103/06 , C02F2103/10 , C10G25/003 , Y10S95/90 , Y10S210/912 , Y10S210/913 , Y10S210/914
摘要： Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.
摘要翻译：使用吸附剂组合物从介质中提取有毒物质如重金属。该组合物是通过红泥硫化产生的，其中含有源自铝土矿矿石的拜耳处理的水合氧化铁。示例性硫化化合物是H 2 S，Na 2 S，K 2 S，（NH 4）2 S和CaS x。硫含量通常比红泥中的残留硫高约0.2至约10％。与大部分测试重金属（Hg，Cr，Pb，Cu，Zn，Cd，Se，Th和U）的红泥相比，硫化红泥是一种改进的吸附剂。与红泥不同，硫化红泥不会浸出天然含有的金属。硫化红泥还可防止与红泥混合时金属浸出。硫化红泥和红泥的混合物比单独硫化红泥更有效地吸附其他离子，如As，Co，Mn和Sr。

5. 发明授权

US07404939B2 Mercury removal sorbent 有权
标题翻译：除汞吸附剂
公开(公告)号：US07404939B2
公开(公告)日：2008-07-29
申请号：US11071633
申请日：2005-03-03
申请人： Joseph B. Cross , Glenn W. Dodwell , Marvin M. Johnson , Edward L. Sughrue, II , Jianhua Yao
发明人： Joseph B. Cross , Glenn W. Dodwell , Marvin M. Johnson , Edward L. Sughrue, II , Jianhua Yao
IPC分类号： B01D15/00 , B01D53/50 , B01D53/56 , B01D53/64 , C02F1/28
CPC分类号： B01D53/64 , B01D53/8665 , B01D2253/10 , B01D2257/602 , B01J20/0214 , B01J20/06 , B01J20/3204 , B01J20/3234 , B01J20/3236 , B01J2220/42 , Y10S210/912 , Y10S210/913 , Y10S210/914 , Y10S502/514 , Y10S502/516
摘要： A sorbent composition comprising a vanadium compound and a TiO2 support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels.
摘要翻译：公开了一种包含钒化合物和TiO 2载体材料的吸附剂组合物。还提供了制备和使用该组合物以从流体流中除去重金属或含重金属的化合物的方法。这种方法特别适用于从含烃材料如煤和石油燃料的燃烧产生的烟道气流中除去汞和汞化合物。

6. 发明申请

US20070278159A1 SYSTEMS AND METHODS FOR TREATING WATER USING IRON 有权
标题翻译：使用铁处理水的系统和方法
公开(公告)号：US20070278159A1
公开(公告)日：2007-12-06
申请号：US11749448
申请日：2007-05-16
申请人： Rajat S. Ghosh , Dennis Fulmer , Kevin Kitzman , John Smith
发明人： Rajat S. Ghosh , Dennis Fulmer , Kevin Kitzman , John Smith
IPC分类号： C02F1/68
CPC分类号： C02F1/705 , C02F1/283 , C02F1/286 , C02F2101/103 , C02F2101/18 , C02F2101/22 , C02F2103/16 , C02F2209/04 , Y10S210/904 , Y10S210/911 , Y10S210/912 , Y10S210/913
摘要： Systems and associated methods for treating contaminant-containing wastewater are provided. The systems generally include a reducing zone for reducing the oxidation-reduction potential of the water and a clean-up zone comprising zero valent iron for removing at least a portion of the contaminant from the contaminant-containing water. The systems are operable to remove one or more contaminants from the contaminant-containing water and are operable for extended durations without clogging due to the formation of iron hydroxides.
摘要翻译：提供了处理含污染废水的系统和相关方法。该系统通常包括用于降低水的氧化还原电位的还原区和包含用于从含污染物的水中去除至少一部分污染物的零价铁的净化区。该系统可操作以从含污染物的水中除去一种或多种污染物，并且由于氢氧化铁的形成而可延长持续时间而不堵塞。

7. 发明申请

US20070209989A1 REDUCING WATER PURIFICATION MATERIAL, METHOD FOR PRODUCING REDUCING WATER PURIFICATION MATERIAL, METHOD FOR TREATING WASTEWATER, AND WASTEWATER TREATMENT APPARATUS 有权
标题翻译：减少水净化材料，减少水净化材料的生产方法，废水处理方法和废水处理装置
公开(公告)号：US20070209989A1
公开(公告)日：2007-09-13
申请号：US10598494
申请日：2005-04-25
申请人： Hiroshi Hayashi , Hitoshi Takeuchi , Hajime Negishi , Shigeyuki Tsuzaki , Yoshio Aikawa , Ayako Mimoto , Shintaro Nakaya
发明人： Hiroshi Hayashi , Hitoshi Takeuchi , Hajime Negishi , Shigeyuki Tsuzaki , Yoshio Aikawa , Ayako Mimoto , Shintaro Nakaya
IPC分类号： C02F1/48
CPC分类号： C02F1/705 , C02F1/5236 , C02F1/66 , C02F2101/20 , Y10S210/911 , Y10S210/912 , Y10S210/913
摘要： A reducing water purification material having a reducing iron-based precipitate selected from green rust, iron ferrite, reducing iron hydroxide, and a mixture thereof. A wastewater treatment process having steps of adding a reducing iron compound to wastewater, leading the wastewater to which the reducing iron compound is added to a reaction tank and forming a precipitate, separating the formed precipitate by a solid-liquid separation to obtain a sludge, and alkalinizing all or a portion of the separated sludge to form an alkaline sludge followed by returning to the reaction tank, wherein in the precipitation step, the wastewater to which the reducing iron compound is added and the alkaline sludge are mixed and are allowed to react in a non-oxidizing atmosphere under alkaline condition to form a reducing iron compound precipitate as the precipitate, thereby incorporating contaminants in the precipitate to remove the contaminants from the wastewater.
摘要翻译：一种还原性水净化材料，其具有选自绿锈，铁铁素体，还原铁氢氧化物的还原性铁基沉淀物及其混合物。一种废水处理方法，其具有将还原铁化合物添加到废水中的步骤，将还原铁化合物加入到反应罐中并形成沉淀物的废水，通过固液分离分离形成的沉淀物以获得污泥，使全部或一部分分离的污泥碱化，形成碱性污泥，然后返回反应槽，其中在沉淀步骤中，加入还原铁化合物的废水和碱性污泥混合并使其反应在非氧化性气氛中在碱性条件下形成还原铁化合物作为沉淀物沉淀物，从而在沉淀物中掺入污染物以从废水中除去污染物。

8. 发明授权

US07244359B1 Inorganic ion sorbent method 有权
标题翻译：无机离子吸附剂法
公开(公告)号：US07244359B1
公开(公告)日：2007-07-17
申请号：US10955292
申请日：2004-09-30
申请人： David M. Teter , Patrick V. Brady , James L. Krumhansl
发明人： David M. Teter , Patrick V. Brady , James L. Krumhansl
IPC分类号： C02F1/28
CPC分类号： B01J20/06 , B01J20/0229 , B01J20/0237 , B01J20/08 , C02F1/281 , C02F1/683 , C02F2101/103 , C02F2101/22 , Y02C10/08 , Y10S210/911 , Y10S210/913
摘要： A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.
摘要翻译：用于净化包含砷和铬的阴离子物质的水的方法和介质，其中包含二价和三价金属氧化物和硫化物的化合物用于在饮用水范围内的pH条件下与污染物形成表面络合物。在一个实施方案中，使用天然和合成的尖晶石和尖晶石样材料作为吸附剂物质。

9. 发明授权

US07160526B2 Process for detoxification of CCA-treated wood 失效
标题翻译： CCA处理木材的解毒过程
公开(公告)号：US07160526B2
公开(公告)日：2007-01-09
申请号：US10434529
申请日：2003-05-09
申请人： Lin Lianzhen , Chung-Yun Hse , Todd Finley Shupe
发明人： Lin Lianzhen , Chung-Yun Hse , Todd Finley Shupe
IPC分类号： C01G3/00 , C01G37/00 , C01G28/00
CPC分类号： A62D3/33 , A62D2101/43 , B27K2240/15 , Y10S210/912 , Y10S210/913
摘要： A chemical process for detoxifying spent CCA (copper, chrome, arsenic)—treated wood, from which CCA and detoxified wood are recovered for recycling comprising the steps of (a) treating CCA-treated wood in the presence of a liquefying reagent such as an organic solvent at 100–250° C. with or without ferrous ions to form liquefied CCA-treated wood (b) adding water or an aqueous solution of an organic solvent to the liquefied CCA-treated wood with stirring to obtain an aqueous solution of liquefied CCA-treated wood (c) adding complexing or precipitating agents, such as phosphoric acid or calcium hydroxide to the aqueous solution of step (b) thereby precipitating insoluble heavy metal complexes or precipitates and forming a solution of detoxified CCA-treated wood (d) separating said heavy metal complexes or precipitates from the solution of detoxified liquefied CCA-treated wood and (e) isolating chromated copper arsenate from said heavy metal complex or precipitate.Further, the solvent may be removed from the solution of detoxified CCA-treated wood of step (d) to obtain concentrated liquefied detoxified CCA-treated wood. This concentrated material may be used as a phenolic or polyurethane intermediate.Additionally, by adding a concentrated inorganic acid, such as sulfuric acid, nitric acid or phosphoric acid, to the complex or precipitated solids of step (d), chromated copper arsenate can be recovered for use in manufacturing additional CCA-treated wood.
摘要翻译：回收用于回收CCA和解毒木材的废CCA（铜，铬，砷）处理木材的化学过程，包括以下步骤：（a）在液化试剂存在下处理CCA处理的木材，例如有机溶剂在100-250℃下有或没有亚铁离子形成液化的CCA处理的木材（b）在搅拌下向液化的CCA处理的木材中加入水或有机溶剂的水溶液，得到液化的水溶液 CCA处理的木材（c）向步骤（b）的水溶液中加入络合或沉淀剂如磷酸或氢氧化钙，从而沉淀不溶重金属络合物或沉淀物并形成解毒的CCA处理的木材溶液（d）从解毒的液化CCA处理的木材的溶液中分离所述重金属络合物或沉淀物，和（e）从所述重金属络合物或沉淀物中分离铬酸铜铜酸盐。此外，溶剂可以从步骤（d）的解毒的CCA处理的木材的溶液中除去，得到浓缩的液化解毒的CCA处理的木材。该浓缩物可用作酚醛或聚氨酯中间体。此外，通过向浓缩步骤（d）的复合物或沉淀固体中加入浓硫酸，硝酸或磷酸等无机酸，可以回收铬酸铜铜，以制备额外的经CCA处理的木材。

10. 发明申请

US20060266711A1 Method for removing fluorine from a fluorine-containing wastewater 失效
标题翻译：从含氟废水中除去氟的方法
公开(公告)号：US20060266711A1
公开(公告)日：2006-11-30
申请号：US11142874
申请日：2005-05-31
申请人： Ming-Hui Liao
发明人： Ming-Hui Liao
IPC分类号： C02F1/52
CPC分类号： C02F1/5245 , C02F1/66 , C02F9/00 , C02F2101/14 , C02F2101/20 , Y10S210/912 , Y10S210/913 , Y10S210/915
摘要： A method for removing fluorine from wastewater includes the steps of: adding a fluorine-reactive agent, that comprises a water-soluble sodium compound and a water-soluble aluminum compound, into the wastewater so as to form sodium ions and aluminum ions in the wastewater and so as to precipitate sodium aluminum fluoride by reaction of the sodium ions and the aluminum ions with fluorine ions in the wastewater; and removing the precipitate of sodium aluminum fluoride from the wastewater.
摘要翻译：从废水中除去氟的方法包括以下步骤：向废水中加入包含水溶性钠化合物和水溶性铝化合物的氟反应剂，以在废水中形成钠离子和铝离子并通过废水中的钠离子和铝离子与氟离子的反应来沉淀氟化铝钠; 并从废水中除去氟化铝钠的沉淀物。

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