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    • 10. 发明申请
    • High-Purity Cycloaliphatic Diepoxy Compound and Preparation Process Thereof
    • 高纯度环脂肪族二环氧化合物及其制备方法
    • US20080045729A1
    • 2008-02-21
    • US11792782
    • 2005-12-27
    • Hideyuki TakaiHiroto TanigawaKatsuya Maruo
    • Hideyuki TakaiHiroto TanigawaKatsuya Maruo
    • C07D303/04C07D301/14
    • C07D303/04
    • A high-purity cycloaliphatic diepoxy compound of General Formula (II) is an epoxidized product of a cycloaliphatic diolefinic compound of General Formula (I) having an isomer content as detected in gas chromatography (GC) of 15% or less: wherein X represents a bivalent group selected from the group consisting of, for example, O, S, —SO—, —SO2—, —CH2—, and —C(CH3)2—; and R1 to R18 may be the same as or different from each other and each represent hydrogen atom, a halogen atom, a hydrocarbon group which may contain oxygen atom or a halogen atom, or an alkoxy group which may be substituted. Such a high-purity cycloaliphatic diepoxy compound is prepared by producing the cycloaliphatic diolefinic compound through distillation, epoxidizing the compound with an aliphatic percarboxylic acid containing substantially no water, carrying out desolvation, and further purifying the epoxidized compound through distillation.
    • 通式(II)的高纯度脂环族二环氧化合物是通式(I)的脂环族二烯烃化合物的环氧化产物,其具有在气相色谱(GC)中检测到的异构体含量为15%以下:其中X表示 选自例如O,S,-SO-,-SO 2 - , - CH 2 - 和-C(CH 3) 2→3 R 1〜R 18可以相同或不同,表示氢原子,卤素原子,可含有氧原子的烃基或 卤素原子或可被取代的烷氧基。 这样的高纯度脂环族二环氧化合物是通过蒸馏生产环脂族二烯化合物,通过用基本上不含水的脂肪族过羧酸进行脱氧,进行去溶剂化,并通过蒸馏进一步纯化环氧化合物来制备的。