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1. 发明申请

US20080200626A1 Methods For Oligomerizing Olefins With Chromium Pyridine Thioether Catalysts 失效
标题翻译：使用铬吡啶硫醚催化剂低聚烯烃的方法
公开(公告)号：US20080200626A1
公开(公告)日：2008-08-21
申请号：US11956074
申请日：2007-12-13
申请人： Lily J. Ackerman , Gary Michael Diamond , Keith Anthony Hall , James M. Longmire , Vince J. Murphy , Dawn E. Verdugo
发明人： Lily J. Ackerman , Gary Michael Diamond , Keith Anthony Hall , James M. Longmire , Vince J. Murphy , Dawn E. Verdugo
IPC分类号： C08F4/616 , B01J31/00 , C08F4/612 , C08F4/00
CPC分类号： C07F11/005 , C07C2/32
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a chromium based catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl thioether compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译：本发明提供了一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与铬基催化剂反应。催化剂可以是铬化合物和吡啶基硫醚化合物的组合的产物。在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。

2. 发明授权

US5188998A Transition-metal catalyst component for a Ziegler catalyst system, and the use of said system 失效
标题翻译：用于ZIEGLER催化剂体系的过渡金属催化剂组分和使用系统
公开(公告)号：US5188998A
公开(公告)日：1993-02-23
申请号：US671591
申请日：1991-03-19
申请人： Ulrich Bueschges , Roland Saive
发明人： Ulrich Bueschges , Roland Saive
IPC分类号： C08F4/616 , C08F4/622 , C08F4/68 , C08F10/00
CPC分类号： C08F10/00
摘要： A transition-metal catalyst component for a Ziegler catalyst system, obtainable by1) mixing an inorganic, oxidic carrier with a transition-metal starting component in an organic solvent,2) removing the solvent by evaporation,3) mixing the solid-phase intermediate from step (2) with3.1) an organoaluminum catalyst component of the formula AlR.sub.m X.sub.3-m, whereR is a C.sub.1 - to C.sub.18 -hydrocarbon radical,m is from 1 to 3, andX is OR, chlorine, bromine or hydrogen, and3.2) an organic carboxylate or an organosilicon compound or a mixture thereof in an organic solvent, and4) if desired, isolating the solid-phase intermediate by filtration, washing and drying,and the use thereof for the homopolymerization or copolymerization of ethene are described.
摘要翻译：一种齐格勒催化剂体系的过渡金属催化剂组分，其可通过以下步骤获得：1）将无机氧化载体与过渡金属起始组分混合在有机溶剂中，2）通过蒸发除去溶剂; 3）将固相中间体从步骤（2）与3.1）式AlRmX3-m的有机铝催化剂组分，其中R是C 1 -C 18烃基，m为1至3，X为OR，氯，溴或氢，以及 3.2）在有机溶剂中的有机羧酸盐或有机硅化合物或其混合物，以及4）如果需要，通过过滤，洗涤和干燥分离固相中间体，并描述其用于乙烯均聚或共聚的用途。

3. 发明授权

US07521512B2 Catalyst composition and polymerization process using mixture of silane electron donors 失效
标题翻译：催化剂组合物和聚合方法使用硅烷电子给体的混合物
公开(公告)号：US07521512B2
公开(公告)日：2009-04-21
申请号：US10555548
申请日：2004-05-27
申请人： Stanley E. Wilson
发明人： Stanley E. Wilson
IPC分类号： C08F4/616
CPC分类号： C08F110/06 , C08F4/6465 , C08F2500/12
摘要： A catalyst composition for the polymerization of olefins comprising the combination of one or more Ziegler-Natta procatalysts comprising one or more transition metal compounds; one or more aluminum containing cocatalysts; and a mixture comprising two or more selectivity control agents (SCA's), corresponding to the formula: (CH3O)nSi(OR)4-n, wherein R, independently each occurrence, is C2-12 alkyl, C3-12 cycloalkyl, C6-18 aryl or (poly)alkyl-substituted aryl, or C7-18 poly(aryl)-substituted alkyl, and n is an integer from zero to 4.
摘要翻译：一种用于烯烃聚合的催化剂组合物，其包含一种或多种包含一种或多种过渡金属化合物的齐格勒 - 纳塔前催化剂的组合; 一种或多种含铝助催化剂; 对应于式（CH3O）nSi（OR）4-n的两种或多种选择性控制剂（SCA）的混合物，其中R各自独立地为C 2-12烷基，C 3-12环烷基， 18芳基或（多）烷基取代的芳基或C7-18聚（芳基） - 取代的烷基，n为0至4的整数。

4. 发明授权

US6087459A Polymeric materials formed using blends of electron donors 失效
标题翻译：使用电子给体的共混物形成聚合材料
公开(公告)号：US6087459A
公开(公告)日：2000-07-11
申请号：US79425
申请日：1998-05-14
申请人： Nemesio D. Miro , Masatoshi Ohkura
发明人： Nemesio D. Miro , Masatoshi Ohkura
IPC分类号： C08F4/656 , C08F4/658 , C08F10/06 , C08F4/616
CPC分类号： C08F10/06
摘要： A method of forming a polymer that simultaneously provides an improved level of impact resistance and processability in which an .alpha.-olefin monomer is subjected to polymerization in the presence of a Ziegler-Natta catalyst system and a blend of electron donors including dicyclopentyldimethoxysilane (DCPMS) and propyltriethoxysilane (PTES). The polymer so formed will have a relationship between a first melt flow rate of a homopolymer formed by polymerizing an .alpha.-olefin monomer in the presence of a Ziegler-Natta catalyst system and a first electron donor (MFR (a)), and a second melt flow rate of a homopolymer formed polymerizing an .alpha.-olefin monomer in the presence of the Ziegler-Natta catalyst system and a second electron donor (MFR (b)), is defined by the equation:1.2.ltoreq.log [MFR(b)/MFR(a)].ltoreq.1.4
摘要翻译：一种形成聚合物的方法，其在齐格勒 - 纳塔催化剂体系和包括二环戊基二甲氧基硅烷（DCPMS）和电子供体的共混物的同时提供改进的耐冲击性水平和加工性能，其中α-烯烃单体经受聚合反应丙基三乙氧基硅烷（PTES）。如此形成的聚合物将在齐格勒 - 纳塔催化剂体系和第一电子给体（MFR（a））的存在下通过聚合α-烯烃单体形成的均聚物的第一熔体流动速率和第二熔体流动速率之间的关系，在齐格勒 - 纳塔催化剂体系和第二电子给体（MFR（b））存在下，在α-烯烃单体聚合中形成的均聚物的熔体流动速率由下式定义：1.2 [log ）/ MFR（a）]

5. 发明授权

US5627246A Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems 失效
标题翻译：在环戊二烯体系中具有杂官能团的负载金属茂络合物作为催化剂体系
公开(公告)号：US5627246A
公开(公告)日：1997-05-06
申请号：US396716
申请日：1995-03-01
申请人： Franz Langhauser , David Fischer , J urgen Kerth , G unther Schweier , Elke Barsties , Hans-Herbert Brintzinger , Stefan Schaible , Werner Roell
发明人： Franz Langhauser , David Fischer , J urgen Kerth , G unther Schweier , Elke Barsties , Hans-Herbert Brintzinger , Stefan Schaible , Werner Roell
IPC分类号： C08F4/622 , C08F4/02 , C08F4/60 , C08F4/602 , C08F4/616 , C08F4/628 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/656 , C08F4/6592 , C08F4/68 , C08F10/00
CPC分类号： C08F10/00 , C08F4/63908 , C08F4/63916 , C08F4/63927
摘要： A supported catalyst system that is obtained bya) reacting a finely divided carrier with an a-trisalkoxy-silyl-.omega.-haloalkyl compound,b) adding a metallocene complex of the indicated formula I to the reaction product of a);c) reacting the product of b) with a quaternizing agent; andd) optionally adding an open-chain or cyclic alumoxane compound.The catalyst system can be used to prepare polymers of C.sub.2 -C.sub.10 -alk-1-enes.
摘要翻译： a）通过以下步骤获得的负载型催化剂体系：a）使细分散的载体与α-三烷氧基甲硅烷基 - ω-卤代烷基化合物反应，b）将所述式I的茂金属络合物加入到a）的反应产物中; c）使b）的产物与季铵化剂反应; 和d）任选地加入开链或环状铝氧烷化合物。催化剂体系可用于制备C2-C10-烷-1-烯的聚合物。

6. 发明授权

US06897274B2 Prepolymerization method of α-olefin 失效
标题翻译： α-烯烃的预聚方法
公开(公告)号：US06897274B2
公开(公告)日：2005-05-24
申请号：US10416399
申请日：2001-10-18
申请人： Yoo-Kyoung Kim , Kun Lo , Il-Seop Kim
发明人： Yoo-Kyoung Kim , Kun Lo , Il-Seop Kim
IPC分类号： C08F4/658 , C08F4/616 , C08F4/649 , C08F4/651 , C08F4/656 , C08F10/00 , C08F110/02 , C08F4/42
CPC分类号： C08F110/02 , C08F4/6565 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： The present invention relates to a method for the prepolymerization of α-olefin in the presence of a catalyst system which comprises (a) a magnesium supported solid complex titanium catalyst and (b) an organometallic compound of metal of Group I or III of the Periodic Table, characterized in that an inert solvent having high viscosity with molecular weight of 300 g/mole or more is used as a reaction medium.
摘要翻译：本发明涉及一种在催化剂体系存在下预聚合α-烯烃的方法，该催化剂体系包括（a）镁负载的固体络合物钛催化剂和（b）元素周期表I或III族金属的有机金属化合物表格，其特征在于使用分子量为300g / mol以上的高粘度的惰性溶剂作为反应介质。

7. 发明授权

US5747404A Polysiloxane supported metallocene catalysts 失效
标题翻译：聚硅氧烷负载金属茂催化剂
公开(公告)号：US5747404A
公开(公告)日：1998-05-05
申请号：US654435
申请日：1996-05-28
申请人： Sandor Nagy , John A. Tyrell
发明人： Sandor Nagy , John A. Tyrell
IPC分类号： C08F4/605 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/616 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/6192 , Y10S526/943
摘要： Disclosed is a catalyst having the formula ##STR1## where each R is independently selected from aliphatic from C.sub.1 to C.sub.6 and aromatic from C.sub.6 to C.sub.10, each R.sub.5 is independently selected from H, R, and L', each L' is independently selected from LM'L.sub.r X.sub.3-r or two L' groups form the bridge --LM'X.sub.2-r L.sub.r --, each L is independently selected from cyclopentadienyl, indenyl, and fluorenyl, X is chlorine or bromine, M' is zirconium, titanium, or hafnium, n is 5 to 500, the ratio of R to H+L in R.sub.5 is 0 to 100, the ratio of H to L' in R.sub.5 is 0 to 4, and r is 0 or 1.
摘要翻译：公开了具有式“IMAGE”的催化剂，其中每个R独立地选自C1至C6的脂族基和C6至C10的芳族，每个R5独立地选自H，R和L'，每个L'独立地选自 LM'LrX3-r或两个L'基团形成桥-LM'X2-rLr-，每个L独立地选自环戊二烯基，茚基和芴基，X是氯或溴，M'是锆，钛或铪， n为5〜500，R5中的R与H + L的比例为0〜100，R5中的H与L'的比例为0〜4，r为0或1。

8. 发明授权

US4981826A Polymerization catalyst prepared with a halogenated silane compound 失效
标题翻译：用卤代硅烷化合物制备的聚合催化剂
公开(公告)号：US4981826A
公开(公告)日：1991-01-01
申请号：US438905
申请日：1989-11-17
申请人： Anthony N. Speca
发明人： Anthony N. Speca
IPC分类号： C08F4/616 , C08F4/646 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/904 , Y10S526/943
摘要： Described is a magnesium-transition metal containing catalyst component, comprising a solid reaction product obtained by treating a solid support material in an inert solvent in any order with (A) a halogenated silane compound, (B) an alkoxy-containing magnesium compound, (C) and acyl halide, (D) at least one transition metal compound of a Group IVb-VIb or VIII metal, and optionally (E) treating the magnesium-transition metal containing product with an organometallic compound of a Group IIa, IIb, or IIIa metal. The magnesium-transition metal containing catalyst component, when employed with known Ziegler cocatalyst, provides a catalyst system which have very high catalytic activities for production of polyolefin of high bulk density. The polymerization kinetics of the catalyst system is controllable as a function of the reagent molar ratios selected for production of the magnesium-transition metal containing catalyst component.
摘要翻译：描述了含镁过渡金属的催化剂组分，其包含通过在惰性溶剂中以（A）卤化硅烷化合物（A）和（B）含烷氧基的镁化合物（A）的任意顺序处理固体载体材料而获得的固体反应产物， C）和酰卤，（D）至少一种IVb-VIb或VIII族金属的过渡金属化合物，和任选地（E）用含有II族，IIb族的有机金属化合物处理含镁过渡金属的产物 IIIa金属。当与已知齐格勒助催化剂一起使用时，含镁过渡金属的催化剂组分提供了一种具有非常高的催化活性，用于生产高堆积密度的聚烯烃。催化剂体系的聚合动力学可以作为选择用于生产含镁过渡金属的催化剂组分的试剂摩尔比的函数来控制。

9. 发明授权

US10259893B1 Reinforcement of a chromium/silica catalyst with silicate oligomers 有权
公开(公告)号：US10259893B1
公开(公告)日：2019-04-16
申请号：US15899448
申请日：2018-02-20
申请人： Chevron Phillips Chemical Company LP
发明人： Max P. McDaniel , Stephen L. Kelly
IPC分类号： C08F10/02 , C08F4/603 , C08F4/616 , C08F4/69 , C08F4/24
摘要： Methods for reinforcing chromium catalysts by the deposition of additional silica are disclosed herein. The resultant silica-reinforced chromium supported catalysts can be used to polymerize olefins to produce, for example, ethylene based homopolymers and copolymers with higher molecular weights and additional long chain branching.

10. 发明授权

US06916759B2 Method for producing a catalyst for homo-or co-polymerization of ethylene 失效
标题翻译：制备乙烯均相或共聚合催化剂的方法
公开(公告)号：US06916759B2
公开(公告)日：2005-07-12
申请号：US10416428
申请日：2001-11-09
申请人： Chun-Byung Yang , Won-Young Kim , Weon Lee
发明人： Chun-Byung Yang , Won-Young Kim , Weon Lee
IPC分类号： C08F4/658 , C08F4/616 , C08F4/649 , C08F4/651 , C08F4/656 , C08F10/00 , C08F110/02 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F110/02 , C08F4/6565 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： A method of making an olefin polymerization catalyst is disclosed. The method involves contacting a magnesium halide compound with an alcohol, adding a mineral oil to the product, reacting this product with a hydroxylated ester and an alkoxy silane, then adding a titanium compound and a second silicon compound. The titanium compound is preferably an alkoxy halide, and the second silicon compound is preferably a silicon halide.
摘要翻译：公开了一种制备烯烃聚合催化剂的方法。该方法包括使卤化镁化合物与醇接触，向产物中加入矿物油，使该产物与羟化酯和烷氧基硅烷反应，然后加入钛化合物和第二硅化合物。钛化合物优选为烷氧基卤化物，第二硅化合物优选为卤化硅。

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