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    • 8. 发明授权
    • Highly acetalized, coarse-grained polyvinyl acetoacetals
    • 高度缩醛化,粗粒度聚乙烯乙酰乙缩醛
    • US08309675B2
    • 2012-11-13
    • US12302104
    • 2007-05-25
    • Werner Bauer
    • Werner Bauer
    • C08G16/02C08G16/04C08G16/00
    • C08F8/28C08F16/06
    • The invention relates to highly acetalized, coarse-grained polyvinyl acetals with a degree of acetalization of >80 mol % and an average grain size of ≧100 μm obtainable by acetalization of partially or fully hydrolyzed polyvinyl esters with a degree of hydrolysis of ≧70 mol % with acetaldehyde, characterized by the fact that the acetalization is started at a temperature T1 of 0° C.≦T1≦+20° C. and is then continued at a temperature T2 of >+40° C., wherein the temperature T2 is held for a time period of 0.05 to 4 hours and the acetalization is performed in a closed reactor.
    • 本发明涉及通过部分或全部水解的水解聚乙烯酯的水解度为≥70摩尔的缩醛化得到的缩醛化粗粒度聚乙烯醇缩醛,缩醛化度> 80摩尔%,平均粒径≥100微米 %的乙醛,其特征在于缩醛化在0℃和nlE; T1≦̸ + 20℃的温度T1开始,然后在> 40℃的温度T2继续,其中温度 T2保持0.05〜4小时,缩醛化在封闭式反应器中进行。