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1. 发明授权

US07838625B2 Dendritic polymers having biphosphonic terminations, derivatives thereof, method for preparing them, and their use 有权
标题翻译：具有双膦末端的树枝状聚合物，其衍生物，其制备方法及其应用
公开(公告)号：US07838625B2
公开(公告)日：2010-11-23
申请号：US10580459
申请日：2004-11-23
申请人： Anne-Marie Caminade , Jean-Pierre Majoral , Laurent Griffe , Cédric Turrin , Pascal Metivier
发明人： Anne-Marie Caminade , Jean-Pierre Majoral , Laurent Griffe , Cédric Turrin , Pascal Metivier
IPC分类号： C08G79/04 , C08G79/06
CPC分类号： C10M137/12 , C08G79/02 , C08G83/003 , C10M137/14 , C10M2223/06 , C10M2223/065 , C10M2225/00 , C10N2220/03 , C10N2230/04 , C10N2230/06 , C10N2230/12 , Y10S424/16
摘要： The invention relates to novel dendritic polymers having biphosphonic terminations, to derivatives thereof, to a method for preparing them and to their uses.
摘要翻译：本发明涉及具有双膦末端的新型树枝状聚合物，其衍生物，其制备方法和用途。

2. 发明授权

US4180647A Polyphosphazene copolymers containing malononitrile and _substituted malononitrile substituents 失效
标题翻译：含有丙二腈和取代的丙二腈取代基的聚磷腈共聚物
公开(公告)号：US4180647A
公开(公告)日：1979-12-25
申请号：US941117
申请日：1978-09-08
申请人： William J. Hergenrother , Adel F. Halasa
发明人： William J. Hergenrother , Adel F. Halasa
IPC分类号： C08G79/02 , C08G79/06
CPC分类号： C08G79/025
摘要： Polyphosphazene copolymers are prepared which certain randomly distributed units represented by the formulas: ##STR1## wherein X is --CR(CN).sub.2 in which R is H, a branched chain, a straight, or cyclic alkyl group containing from 1 to 12 carbon atoms or an aryl group or mixtures thereof, and wherein X' is selected from the group consisting of substituted and unsubstituted alkoxy, alkenyloxy, aryloxy, alkenylaryloxy, amino and mercapto groups or mixtures thereof.In the copolymer units represented by the above formulas, all X substituent groups may be the same or they may be mixed and all X' substituent groups may be the same or mixed. In the mixtures, the X substituent groups may be mixtures of different --CR(CN).sub.2 groups and the X' substituent groups may be mixtures of alkoxy, alkenyloxy, aryloxy, alkenylaryloxy, amino and mercapto groups or mixtures within each group.The copolymers of the invention can be utilized to form protective films and may also be utilized in applications such as for moldings, coatings, and the like where heat stability and solvent resistance are important.
摘要翻译：其中X为-CR（CN）2，其中R为H，含有1至12个碳原子的支链，直链或环状烷基，由下式表示的某些随机分布的单元制备聚磷腈共聚物：或芳基或其混合物，并且其中X'选自取代和未取代的烷氧基，烯氧基，芳氧基，烯基芳氧基，氨基和巯基或其混合物。在由上式表示的共聚物单元中，所有X取代基可以相同或可以混合，并且所有X'取代基可以相同或混合。在该混合物中，X取代基可以是不同的-CR（CN）2基团的混合物，X'取代基可以是烷氧基，烯氧基，芳氧基，烯基芳氧基，氨基和巯基的混合物或各组中的混合物。本发明的共聚物可用于形成保护膜，也可用于诸如其中热稳定性和耐溶剂性重要的模制品，涂料等应用。

3. 发明授权

US4166897A Phosphorus-containing condensation products, their production and their use as flame retardants 失效
标题翻译：含磷缩合产物，其生产及其用作阻燃剂
公开(公告)号：US4166897A
公开(公告)日：1979-09-04
申请号：US710856
申请日：1976-08-02
申请人： Kohei Umetani , Masakazu Date , Kiyonori Kawai
发明人： Kohei Umetani , Masakazu Date , Kiyonori Kawai
IPC分类号： D06M15/667 , C07F9/54 , C08G79/00 , C08G79/02 , D06M13/02 , D06M13/244 , D06M13/282 , C08G79/06
CPC分类号： C07F9/5449 , Y10T428/2915
摘要： Process for producing a water-soluble phosphorus-containing condensation product having a molar ratio P--CH.sub.2 --P linkage/P--CH.sub.2 OCH.sub.2 --P linkage of 0.8-4.0 by heating a tetrakis(hydroxymethyl)phosphonium compound under reduced pressure and acid conditions to condense it by dehydration and deformaldehydation reaction. This condensation product can be used for rendering textile articles flame retardant.
摘要翻译：通过在减压和酸性条件下加热四（羟甲基）鏻化合物以制备具有0.8-4.0摩尔比P-CH2-P键/ P-CH2OCH2-P键的水溶性含磷缩合产物的方法以冷凝它通过脱水和变形醛化反应。该缩合产物可用于使纺织品阻燃。

4. 发明授权

US4071501A Water soluble adduct of hydroxymethyl phosphorous compound and ammonia or amine compound and method of preparation 失效
标题翻译：羟甲基磷化合物与氨或胺化合物的水溶性加合物及其制备方法
公开(公告)号：US4071501A
公开(公告)日：1978-01-31
申请号：US648834
申请日：1976-01-14
申请人： Armand B. Pepperman, Jr. , Donald J. Daigle , Sidney L. Vail
发明人： Armand B. Pepperman, Jr. , Donald J. Daigle , Sidney L. Vail
IPC分类号： C08G8/38 , C08G14/06 , D06M15/673 , C08G79/06
CPC分类号： C08G14/06 , C08G8/38 , D06M15/673 , Y10S428/921
摘要： Soluble adduct polymers were allowed to react with phenol, alkyl substituted phenols or halogen substituted phenols which contain one or more hydrogens ortho or para to the phenolic hydroxyl group to (a) prepare flame resistant polymers and (b) prepare flame-, glow-, wrinkle- and shrink-resistant woven and knit textiles which contain 25% or more cellulosic fibers.
摘要翻译：使可溶性加合物聚合物与苯酚，烷基取代的酚或卤素取代的酚反应，所述苯酚或酚取代的苯酚含有酚羟基的邻位或对位的一个或多个氢，以（a）制备阻燃聚合物和（b）制备阻燃，发光，抗皱和抗收缩的编织和针织纺织品，其含有25％或更多的纤维素纤维。

5. 发明授权

US3907898A Process for the manufacture of polycondensation products containing phosphorus, the products and their use as flameproofing agents 失效
标题翻译：用于制造含磷的缩聚产物的方法，该产品及其用作防火剂
公开(公告)号：US3907898A
公开(公告)日：1975-09-23
申请号：US39957673
申请日：1973-09-21
申请人： CIBA GEIGY AG
发明人： NACHBUR HERMANN , KERN JOERG , MAEDER ARTHUR
IPC分类号： B27K3/15 , B27K3/50 , C08G61/12 , C08G79/06 , D06M13/285 , D06M15/431 , D06M15/667 , D06M15/673 , C11D3/26 , C07F9/28
CPC分类号： D06M15/673 , B27K3/15 , B27K2240/30 , C08G79/06 , C08K5/21 , C08K5/49 , D06M13/285 , D06M15/431 , D06M15/667 , Y10T442/2672
摘要： The subject of the invention is a process for the manufacture of polycondensation products from hydroxymethylphosphonium compounds, characterised in that at least one anhydrous tetrakis(hydroxymethyl)-phosphonium salt or tetrakis(hydroxymethyl)phosphonium hydroxide is condensed with itself in an anhydrous medium, optionally using an acid catalyst and optionally in the presence of at least one inert organic solvent, at 100* to 150*C, preferably 120* to 150*C, the condensation being continued until 0.5 to 1.5 mols of water have been eliminated per 1 mol of phosphonium compound employed, free hydroxyl groups are, if appropriate, at least partially etherified with at least one alkanol with 1 to 4 carbon atoms, and that the salt of the polycondensation products are, where relevant, converted into the corresponding hydroxides. The polycondensation products are used for the flameproofing of organic fibre material, especially textiles. Appropriately, the procedure followed is that an aqueous preparation is applied to these materials which contains at least (1) a polycondensation product of the indicated type and (2) a polyfunctional compound, and that the material thus treated are dried and subjected to a heat treatment.
摘要翻译：本发明的主题是由羟甲基鏻化合物制造缩聚产物的方法，其特征在于至少一种无水四（羟甲基）鏻盐或四（羟甲基） - 鏻氢氧化物与自身在无水介质中冷凝，任选地使用酸催化剂和任选地在至少一种惰性有机溶剂的存在下，在100-150℃，优选120-150℃下，继续进行缩合，直至每1次消除0.5至1.5摩尔的水使用的鏻化合物的摩尔数，如果合适，游离羟基与至少一种具有1至4个碳原子的链烷醇至少部分醚化，并且缩聚产物的盐在相关时转化为相应的氢氧化物。

6. 发明授权

US3397219A Preparation of phosphorus-containing olefin polymers and salts thereof 失效
标题翻译：含磷烯烃聚合物及其盐的制备
公开(公告)号：US3397219A
公开(公告)日：1968-08-13
申请号：US35326964
申请日：1964-03-19
申请人： BRITISH PETROLEUM CO
发明人： FREDERICK FORD JOHN , MICHAEL WOOD JOHN
IPC分类号： C07F9/38 , C08F8/00 , C08F8/12 , C08F8/32 , C08F8/40 , C08F10/00 , C08G79/00 , C08G79/06 , C10M135/02 , C10M159/12
CPC分类号： C10M159/123 , C07F9/38 , C08F8/00 , C08F8/12 , C08F8/32 , C08F8/40 , C08F10/00 , C08G79/00 , C08G79/06 , C10M1/08 , C10M135/02 , C10M2205/02 , C10M2205/026 , C10M2205/028 , C10M2215/04 , C10M2215/26 , C10M2217/046 , C10M2217/06 , C10M2223/00 , C10M2223/08 , C10M2225/00 , C10M2225/02 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C08F110/00 , C08F30/02 , C08F4/00

7. 发明授权

US3101278A Flame proofing of cellulosic materials 失效
公开(公告)号：US3101278A
公开(公告)日：1963-08-20
申请号：US7038860
申请日：1960-11-21
申请人： HOOKER CHEMICAL CORP
发明人： WAGNER GEORGE M , HOCH PAUL E
IPC分类号： C07F9/54 , C08G79/06 , D06M15/431 , D06M15/673
CPC分类号： D06M15/673 , C07F9/5407 , C08G79/06 , D06M15/431 , Y10S428/921 , Y10T442/268

8. 发明授权

US3044984A Phosphorus containing compounds 失效
标题翻译：含磷化合物
公开(公告)号：US3044984A
公开(公告)日：1962-07-17
申请号：US85915159
申请日：1959-12-14
申请人： MICROCELL LTD
发明人： RICHARD BLOOMFIELD PETER
IPC分类号： C08G79/06
CPC分类号： C08G79/06

9. 发明授权

US2983623A Flame proofing agents derived from methylol phosphorus polymers 失效
标题翻译：衍生自羟甲基磷聚合物的防火剂
公开(公告)号：US2983623A
公开(公告)日：1961-05-09
申请号：US85638059
申请日：1959-12-01
申请人： ALBRIGHT & WILSON
发明人： HAROLD COATES
IPC分类号： B27K3/52 , C08G79/02 , C08G79/06 , C09D5/18 , D06M15/415 , D06M15/43 , D06M15/431 , D06M15/667 , D06M15/673 , D21H25/02
CPC分类号： D21H21/34 , B27K3/15 , B27K3/20 , B27K5/04 , B27K2200/10 , C08G79/02 , C08G79/06 , D06M15/415 , D06M15/431 , D06M15/667 , D06M15/673 , D21H5/0002 , D21H25/02 , Y10S428/921 , Y10T442/268

10. 发明授权

US2830964A Process of producing ethylene oxide methylol phosphorus polymers, products obtained and aqueous compositions thereof 失效
标题翻译：生产环氧乙烷羟甲基磷聚合物的方法，所得产物及其含水组合物
公开(公告)号：US2830964A
公开(公告)日：1958-04-15
申请号：US51634555
申请日：1955-06-17
申请人： BULLOCK AUSTIN L , REEVES WILSON A , GUTHRIE JOHN D
发明人： BULLOCK AUSTIN L , REEVES WILSON A , GUTHRIE JOHN D
IPC分类号： C08G79/06
CPC分类号： C08G79/06

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