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1. 发明授权

US06670423B2 Polar ethylene-based polymer, cycloolefin polymer blends 有权
公开(公告)号：US06670423B2
公开(公告)日：2003-12-30
申请号：US10071028
申请日：2002-02-08
申请人： Karlheinz Hausmann
发明人： Karlheinz Hausmann
IPC分类号： C08L2308
CPC分类号： C08L23/08 , C08L23/00 , C08L23/0846 , C08L45/00 , C08L2666/04
摘要： Blends comprising a polar derivative of an ethylene based polymer and a cycloolefin polymer are prepared. The ethylene based polymer preferably comprises at least 60 weight % of ethylene, relative to the weight of the polymer and polar monomers selected from the group of carboxylic acids, alkyl acrylates and vinyl acetates. It is preferably 0.01 to 99.5% neutralized with metal ions selected from sodium, potassium, zinc, calcium, magnesium, lithium, aluminum, nickel, and chromium. The cycloolefin polymer is preferably an ethylene-norbornene copolymer. The invention also relates to the applications of such blends as sealant layers and film packagings. The perforation resistance, the heat seal initiation temperature and the hot tack strength of such films are improved.

2. 发明授权

US06399683B1 Resin composition for extruded forms 失效
标题翻译：用于挤出形式的树脂组合物
公开(公告)号：US06399683B1
公开(公告)日：2002-06-04
申请号：US08967103
申请日：1997-11-10
申请人： Koji Yamamoto , Hajime Ikeno , Keiko Shichijo
发明人： Koji Yamamoto , Hajime Ikeno , Keiko Shichijo
IPC分类号： C08L2308
CPC分类号： C08L23/0815 , C08L23/06 , C08L2205/02 , C08L2310/00 , C08L2314/02 , C08L2666/06 , C08L2666/02
摘要： A resin composition for extruded forms that has improved workability, and excellent properties with respect to transparency, heat resistance, low-temperature resistance, etc. The composition contains 50 to 99% by weight of component A, which is a copolymer of ethylene and &agr;-olefin, and 1 to 50% by weight of component B, which is an ethylene-containing polymer. The component A has: (a) a melt flow rate (MFR) of 0.1 to 5 g/10 min.; (b) a density D of 0.88 to 0.925 g/cm3; (c) a single peak of elution volume indicated by an elution curve obtained by temperature rising elution fractionation (TREF), the peak corresponding to a temperature within a range of from 30 to 100®, and the elution curve satisfying a relationship in which the ratio H/W is not less than 1 when H represents the height of the peak and W represents the width of the elution curve at half of the height H; and (d) an elution volume Y (in % of the weight thereof with respect to the total weight of the component A) at an elution temperature of 50C in TREF, the elution volume Y satisfying the following condition: {circle around (1)} Y≦−4500D+4105 when the density D of the component A is less than 0.91 g/cm3, but Y≦100; or {circle around (2)} Y≦10 when the density D of the component A is not less than 0.91 g/cm3. The component B has: (a′) a melt flow rate of 0.1 to 20 g/10 min.; (b′) a density of 0.88 to 0.93 g/cm3; (c′) a memory effect (ME) of not less than 1.3; and (d′) a melt tension (MT) of not less than 1.0 g.
摘要翻译：用于挤出形式的树脂组合物，其具有改进的加工性，并且在透明性，耐热性，耐低温性等方面具有优异的性能。该组合物含有50至99重量％的组分A，其是乙烯和α的共聚物和1〜50重量％的作为含乙烯的聚合物的组分B。组分A具有：（a）熔体流动速率（MFR）为0.1至5g / 10min。（b）密度D为0.88-0.925g / cm3; （c）通过升温洗脱分级（TREF）获得的洗脱曲线所指示的洗脱体积的单峰，对应于30〜100（R）范围内的温度的峰，以及满足关系的洗脱曲线当H表示峰的高度时，H / W的比率不小于1，W表示高度H的一半处的洗脱曲线的宽度; 和（d）在TREF中洗脱温度为50℃的洗脱体积Y（其相对于组分A的总重量的重量％），洗脱体积Y满足以下条件：{圆周（1）当组分A的密度D小于0.91g / cm 3，但Y <= 100时，Y <= - 4500D + 4105; 或组分A的密度D为0.91g / cm 3以上的{圈（2）} Y <= 10。组分B具有：（a'）熔体流动速率为0.1至20g / 10min。（b'）密度为0.88〜0.93g / cm 3; （c'）记忆效应（ME）不小于1.3; 和（d'）不小于1.0g的熔体张力（MT）。

3. 发明授权

US06538070B1 Ethylene interpolymer polymerizations 失效
标题翻译：乙烯互聚物聚合
公开(公告)号：US06538070B1
公开(公告)日：2003-03-25
申请号：US08858664
申请日：1997-05-19
申请人： Robert S. Cardwell , Brian W. S. Kolthammer , Deepak R. Parikh
发明人： Robert S. Cardwell , Brian W. S. Kolthammer , Deepak R. Parikh
IPC分类号： C08L2308
CPC分类号： C08F297/08 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/06 , C08L2666/06 , C08F4/65916 , C08F2/34 , C08F2500/12 , C08F2500/03 , C08L2666/04
摘要： A new process of interpolymerizing ethylene interpolymer products having improved properties, such as increased onset of crystallization temperature, is disclosed. Preferably, the process comprises interpolymerizing a first homogeneous ethylene/alpha-olefin interpolymer and at least one second homogeneous ethylene/alpha-olefin interpolymer using at least two constrained geometry catalysts having different reactivities such that the first ethylene/alpha-olefin interpolymer has a narrow molecular weight distribution (NMWD) with a very high comonomer content and relatively high molecular weight and the second ethylene/alpha-olefin interpolymer has a NMWD with a low comonomer content and a molecular weight lower than that of the first interpolymer. The resultant first homogeneous interpolymer is combined with the resultant second homogeneous interpolymer in appropriate weight ratios resulting in the desired finished polymer structure. The first interpolymer and the second interpolymer can be polymerized in a single reactor or they can be polymerized in separate reactors operated in parallel or series.
摘要翻译：公开了具有改进性能的乙烯互聚物产物的新聚合方法，例如结晶温度的开始增加。优选地，该方法包括使用具有不同反应性的至少两种约束几何催化剂使第一均匀乙烯/α-烯烃互聚物和至少一种第二均相乙烯/α-烯烃互聚物互聚，使得第一乙烯/α-烯烃互聚物具有窄的具有非常高的共聚单体含量和相对高分子量的分子量分布（NMWD），第二乙烯/α-烯烃互聚物具有低共聚单体含量低于第一互聚物的分子量的NMWD。将所得第一均匀互聚物与所得的第二均相互聚物以适当的重量比组合，得到所需的最终聚合物结构。第一互聚物和第二互聚物可以在单个反应器中聚合，或者它们可以在并行或串联操作的分离的反应器中聚合。

4. 发明授权

US06458893B1 Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US06458893B1
公开(公告)日：2002-10-01
申请号：US09904977
申请日：2001-07-13
申请人： Michihisa Tasaka , Toshimi Yamanaka
发明人： Michihisa Tasaka , Toshimi Yamanaka
IPC分类号： C08L2308
CPC分类号： C08L75/04 , C08L15/00 , C08L23/08 , C08L23/0861 , C08L23/26 , C08L25/10 , C08L29/04 , C08L33/066 , C08L53/02 , C08L53/025 , C08L2666/06 , C08L2666/24 , C08L2666/04 , C08L2666/02 , C08L2666/14 , C08L29/00 , C08L25/00
摘要： A thermoplastic resin composition comprising 40 to 95 parts by weight of (a) a saponified ethylene-vinyl acetate copolymer resin and 60 to 5 parts by weight of (b) at least one selected from the group consisting of copolymers of a vinyl aromatic compound with a conjugated diene compound, and hydrogenated derivatives thereof, characterized in that the saponified ethylene-vinyl acetate copolymer resin (a) has an ethylene content of 40 to 95 wt % based on a weight of the saponified ethylene-vinyl acetate copolymer resin and a degree of saponification of the vinyl acetate of at least 80 wt % and (b)at least one selected from the group consisting of copolymers of a vinyl aromatic compound with a conjugated diene compound is selected from the group consisting of (b-1) block copolymers of a vinyl aromatic compound with a conjugated diene compound, and hydrogenated derivatives thereof and (b-2) hydrogenated random copolymers of a vinyl aromatic compound with a conjugated diene compound, the copolymers having a vinyl aromatic compound content of at most 50 wt %, a number average molecular weight(Mn) of from 5,000 to 1,000,000, a polydispersity(Mw/Mn) of at most 10, and a content of vinyl bonds derived from the conjugated diene compound of at least 10% based on bonds derived from the conjugated diene compound.
摘要翻译：一种热塑性树脂组合物，其包含40至95重量份的（a）皂化的乙烯 - 乙酸乙烯酯共聚物树脂和60至5重量份的（b）至少一种选自乙烯基芳族化合物与共轭的共聚物二烯化合物及其氢化衍生物，其特征在于皂化乙烯 - 乙酸乙烯酯共聚物树脂（a）的乙烯含量为乙烯 - 乙酸乙烯酯共聚物树脂皂化物的重量百分比为40-95wt％，皂化度至少80重量％的乙酸乙烯酯和（b）选自乙烯基芳族化合物与共轭二烯化合物的共聚物中的至少一种选自（b-1）乙烯基的（b-1）嵌段共聚物芳族化合物与共轭二烯化合物及其氢化衍生物和（b-2）乙烯基芳族化合物与共轭二烯化合物的氢化无规共聚物，共聚物乙烯基芳族化合物含量至多为50重量％，数均分子量（Mn）为5,000至1,000,000，多分散性（Mw / Mn）至多为10，以及衍生自共轭的基于衍生自共轭二烯化合物的键，至少10％的二烯化合物。

5. 发明授权

US06333387B1 Ethylene copolymer composition 有权
标题翻译：乙烯共聚物组成
公开(公告)号：US06333387B1
公开(公告)日：2001-12-25
申请号：US09703665
申请日：2000-11-02
申请人： Mamoru Takahashi , Seiichi Ikeyama , Akira Todo , Toshiyuki Tsutsui , Seiji Ohta , Hajime Inagaki
发明人： Mamoru Takahashi , Seiichi Ikeyama , Akira Todo , Toshiyuki Tsutsui , Seiji Ohta , Hajime Inagaki
IPC分类号： C08L2308
CPC分类号： C08L23/0815 , C08F10/02 , C08F110/02 , C08F210/16 , C08F210/18 , C08L23/06 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L23/20 , C08L23/22 , C08L51/06 , C08L2205/02 , Y10S526/943 , C08F2/00 , C08L2666/24 , C08L2666/06 , C08F2500/12 , C08F2500/11 , C08F2500/08 , C08F210/14 , C08F210/08 , C08F232/00 , C08F2500/25 , C08L2666/04
摘要： Ethylene/&agr;-olefin copolymer with olefin type elastomer, each having particular properties, including density and melt flow rate, with a density ratio of elastomer to copolymer of less than 1, provide compostions which have excellent moldability and form films having high mechanical strength.
摘要翻译：具有烯烃类弹性体的乙烯/α-烯烃共聚物各自具有特定的性能，包括密度和熔体流动速率，弹性体与共聚物的密度比小于1，提供了具有优异成型性和具有高机械强度的成型膜的组合物。

6. 发明授权

US06316546B1 Ethylene polymer film resins 失效
标题翻译：乙烯聚合物膜树脂
公开(公告)号：US06316546B1
公开(公告)日：2001-11-13
申请号：US08083866
申请日：1993-06-28
申请人： S. Christine Ong , Sandra D. Schregenberger , Pradeep P. Shirodkar
发明人： S. Christine Ong , Sandra D. Schregenberger , Pradeep P. Shirodkar
IPC分类号： C08L2308
CPC分类号： C08F210/16 , B01J8/26 , B01J2219/0004 , C08F10/02 , C08F297/08 , C08F297/083 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08F2/002 , C08F2/001 , C08L2666/04 , C08F210/14 , C08F2500/12 , C08F2500/05 , C08F2500/26 , C08F2500/01 , C08F2500/18 , C08F2500/02
摘要： A class of relatively high molecular weight, high density ethylene polymers (HMW-HDPE) is disclosed capable of being formed into thin films of high strength, such polymers having a density of at least about 0.925 g/cc, a flow index (I21) no highier than about 15 g/10 min., a melt flow ratio (MFR) of at least about 65, and a dynamic elasticity at 0.1 rad./sec. of no higher than about 0.7 at a corresponding complex viscosity at 0.1 rad./sec. no highier than about 14E5, i.e., about 14×105 poises. The ethylene polymer is a bimodal blend of relatively high molecular weight (HMW) and low molecular weight (LMW) ethylene polymers.
摘要翻译：公开了一类相对高分子量的高密度乙烯聚合物（HMW-HDPE），能够形成高强度的薄膜，这种聚合物具有至少约0.925g / cc的密度，流动指数（I21）不高于约15g / 10min，熔体流动比（MFR）为至少约65，动态弹性为0.1rad / sec。在0.1rad./sec的相应复数粘度下不高于约0.7。不高于约14E5，即约14×10 5泊。乙烯聚合物是相对高分子量（HMW）和低分子量（LMW）乙烯聚合物的双峰共混物。

7. 发明授权

US06300398B1 Polymer compositions having improved elongation 失效
标题翻译：聚合物组合物具有改善的伸长率
公开(公告)号：US06300398B1
公开(公告)日：2001-10-09
申请号：US09059753
申请日：1998-04-14
申请人： Gary Lee Jialanella , Thomas J. McKeand, Jr. , Kalyan Sehanobish
发明人： Gary Lee Jialanella , Thomas J. McKeand, Jr. , Kalyan Sehanobish
IPC分类号： C08L2308
CPC分类号： C09J123/0815 , C08L23/0815 , C08L91/06 , C08L2205/02 , C08L2314/06 , C08L2666/02 , C08L2666/06 , C08L2666/04
摘要： The subject invention is directed to polymer compositions which comprise a homogeneous ethylene/&agr;-olefin interpolymer, a wax and a nucleating agent, wherein the nucleating agent is provided in an effective amount such that the percent elongation at break of the polymer composition is at least about fifty percent greater than the percent elongation at break of a comparative composition which lacks the nucleating agent. The polymer compositions of the invention will find utility in applications r equiring high elongation at break, while maintaining a high onset of crystallization temperature, such as in the high-speed coating of fabrics, carpet backing, floor tile and sheeting, and adhesives.
摘要翻译：本发明涉及包含均相乙烯/α-烯烃互聚物，蜡和成核剂的聚合物组合物，其中所述成核剂以有效量提供，使得聚合物组合物的断裂伸长百分比至少为比缺少成核剂的比较组合物的断裂伸长率大大约百分之五十。本发明的聚合物组合物在保持高结晶温度的起始时，例如在织物，地毯背衬，地板瓦和片材以及粘合剂的高速涂层中，可应用于高断裂伸长率的应用。

8. 发明授权

US06809125B1 Foam comprising polyolefin blend and method for producing same 有权
标题翻译：包含聚烯烃共混物的泡沫及其制造方法
公开(公告)号：US06809125B1
公开(公告)日：2004-10-26
申请号：US09586493
申请日：2000-06-02
申请人： Shau-Tarng Lee , Natarajan S. Ramesh
发明人： Shau-Tarng Lee , Natarajan S. Ramesh
IPC分类号： C08L2308
CPC分类号： C08L23/06 , C08L23/0815 , C08L2203/14 , C08L2666/06
摘要： A foam and method for making such foam includes a blend of a low density polyethylene and a higher density ethylene polymer. The ethylene polymer has a density ranging from greater than 0.94 to about 0.97 grams/cubic centimeter and a melt flow index of greater than 10 g/10 minutes, and may include at least one member selected from ethylene/alpha-olefin copolymer, ethylene homopolymer, and blends thereof.
摘要翻译：泡沫和制造这种泡沫的方法包括低密度聚乙烯和较高密度乙烯聚合物的共混物。乙烯聚合物的密度范围大于0.94至约0.97克/立方厘米，熔体流动指数大于10g / 10分钟，并且可包括至少一种选自乙烯/α-烯烃共聚物，乙烯均聚物，及其混合物。

9. 发明授权

US06653401B2 Thermoplastic elastomer composition 失效
标题翻译：热塑性弹性体组合物
公开(公告)号：US06653401B2
公开(公告)日：2003-11-25
申请号：US09796481
申请日：2001-03-02
申请人： Hideo Kinoshita , Ikuji Ohtani , Takeshi Yasui
发明人： Hideo Kinoshita , Ikuji Ohtani , Takeshi Yasui
IPC分类号： C08L2308
CPC分类号： C08F291/00 , C08L23/0815 , C08L23/10 , C08L25/06 , C08L53/00 , C08L2312/00 , C08F2/02 , C08L2666/04
摘要： Disclosed is a thermoplastic elastomer composition which comprises (A) a thermoplastic resin containing a polystyrene resin, (B) a rubber-like polymer obtained by partially or completely crosslinking an ethylene-&agr;-olefin copolymer and (C) a compatibilizing agent, the amount of the component (B) being 40-90 parts by weight and the amount of the component (C) being 0.1-40 parts by weight based on 100 parts by weight of the components (A), (B) and (C) in total. According to the present invention, an elastomer composition excellent in abrasion resistance can be provided.
摘要翻译：公开了一种热塑性弹性体组合物，其包含（A）含有聚苯乙烯树脂的热塑性树脂，（B）通过部分或完全交联乙烯-α-烯烃共聚物获得的橡胶状聚合物和（C）相容剂，的组分（B）为40-90重量份，并且组分（C）的量基于100重量份的组分（A），（B）和（C）中的0.1-40重量份，在总。根据本发明，可以提供耐磨性优异的弹性体组合物。

10. 发明授权

US06599984B1 Rubber modified with ethylene/&agr;-olefin(/diene) rubber(s) 有权
标题翻译：用乙烯/α-烯烃（/二烯）橡胶改性的橡胶
公开(公告)号：US06599984B1
公开(公告)日：2003-07-29
申请号：US09556936
申请日：2000-04-21
申请人： Masaaki Kawasaki , Taku Koda , Takashi Hakuta , Tetsuo Tojo
发明人： Masaaki Kawasaki , Taku Koda , Takashi Hakuta , Tetsuo Tojo
IPC分类号： C08L2308
CPC分类号： C08L23/16 , C08L2205/02 , C08L2666/04
摘要： A blend of a rubber and a rubber modifier, the rubber modifier comprising an ethylene/&agr;-olefin copolymer rubber (A) composed of one or more copolymers selected from the group consisting of a copolymer of ethylene and an &agr;-olefin having 3-20 carbon atoms and a copolymer of ethylene, an &agr;-olefin having 3-20 carbon atoms and a non-conjugated polyene, the copolymer rubber (A) having the parameters: an ethylene/&agr;-olefin mole ratio in the range of 51/49 to 87/13, an intrinsic viscosity [&eegr;] determined in decahydronaphthalene at 135° C. in the range of 0.8 to 2.5 dl/g and an iodine value in the range of 0 to 40.
摘要翻译：橡胶和橡胶改性剂的共混物，橡胶改性剂包括由一种或多种共聚物组成的乙烯/α-烯烃共聚物橡胶（A），所述共聚物选自乙烯和具有3-20的α-烯烃的共聚物碳原子和乙烯，具有3-20个碳原子的α-烯烃和非共轭多烯的共聚物，共聚物橡胶（A）具有参数：乙烯/α-烯烃摩尔比在51/49范围内至87/13，在十氢萘中在135℃下测定的特性粘度在0.8至2.5dl / g的范围内，碘值在0至40的范围内。

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