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    • 5. 发明授权
    • Detergent compositions having color care agents
    • 具有护肤剂的洗涤剂组合物
    • US5827813A
    • 1998-10-27
    • US993255
    • 1997-12-18
    • Frederick Anthony HartmanRobert Allen GodfroidJanet Sue LittigMark Robert Sivik
    • Frederick Anthony HartmanRobert Allen GodfroidJanet Sue LittigMark Robert Sivik
    • C11D1/40C11D1/42C11D1/44C11D3/30C11D17/06
    • C11D17/06C11D1/40C11D1/42C11D1/44C11D17/065C11D3/30
    • Detegent composition having color care agents are provided. The detergent compositions comprise from about 0.1% to about 50% of by weight of the composition of a color care agent having the formula: (R.sub.1)(R.sub.2)N(CX.sub.2).sub.n N(R.sub.3)(R.sub.4) wherein X is selected from the group consisting of hydrogen, linear or branched; substituted or unsubstituted alkyl having from 1-10 carbons atoms and substituted or unsubstituted aryl having at least 6 carbon atoms; n is an integer from 1 to 6; R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are independently selected from the group consisting of alkyl; aryl; alkaryl; arylalk; hydroxyalkyl; polyhydroxyalkyl; polyalkylether having the formula --((CH.sub.2).sub.y O).sub.z R.sub.7 where R.sub.7 is hydrogen or a linear, branched, substituted or unsubstituted alkyl chain having from 1 to 10 carbon atoms and where y is an integer from 2 to 10 and z is an integer from 1 to 30; alkoxy; polyalkoxy having the formula: --(O(CH.sub.2).sub.y).sub.z R.sub.7 ; the group --C(O)R.sub.8 where R.sub.8 is alkyl; alkaryl; arylalk; hydroxyalkyl; polyhydroxyalkyl and polyalkylether as defined in R.sub.1, R.sub.2, R.sub.3, and R.sub.4 ; CX.sub.2 CX.sub.2 N(R.sub.5)(R.sub.6) with no more than one of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 being CX.sub.2 CX.sub.2 N(R.sub.5)(R.sub.6) and wherein R.sub.5 and R.sub.6 are alkyl; alkaryl; arylalk; hydroxyalkyl; polyhydroxyalkyl, olyalkylether, alkoxy and polyalkoxy as defined in R.sub.1, R.sub.2, R.sub.3, and R.sub.4 ; and either of R.sub.1 +R.sub.3 or R.sub.4 or R.sub.2 +R.sub.3 or R.sub.4 can combine to form a cyclic substituent. The compositions also include detergent adjunct ingredients including surfactants, builders, bleaching agents, enzymes, soil release polymers, dye transfer inhibitors, and mixtures thereof.
    • 提供了具有着色护理剂的抑制组合物。 洗涤剂组合物占组合物重量的约0.1%至约50%,具有下式的着色剂:(R1)(R2)N(CX2)nN(R3)(R4)其中X选自 由氢,直链或支链组成的组; 具有1-10个碳原子的取代或未取代的烷基和具有至少6个碳原子的取代或未取代的芳基; n是1至6的整数; R 1,R 2,R 3和R 4独立地选自烷基; 芳基; 烷芳基 芳基酮 羟烷基 聚羟烷基 具有式 - ((CH 2)y O)z R 7的聚烷基醚,其中R 7是氢或具有1至10个碳原子的直链,支链,取代或未取代的烷基,其中y是2至10的整数,并且z是 1〜30; 烷氧基 具有下式的聚烷氧基: - (O(CH 2)y)z R 7; 基团-C(O)R 8,其中R 8是烷基; 烷芳基 芳基酮 羟烷基 如R1,R2,R3和R4中定义的多羟基烷基和聚烷基醚; CX2CX2N(R5)(R6),R1,R2,R3和R4中不超过一个为CX2CX2N(R5)(R6),其中R5和R6为烷基; 烷芳基 芳基酮 羟烷基 多羟基烷基,烷基醚,烷氧基和如R1,R2,R3和R4中定义的聚烷氧基; 并且R 1 + R 3或R 4或R 2 + R 3或R 4中的任一个可以结合形成环取代基。 组合物还包括洗涤剂辅助成分,包括表面活性剂,助洗剂,漂白剂,酶,去污聚合物,染料转移抑制剂及其混合物。
    • 7. 发明授权
    • Betaine-amine oxides, a process for their preparation and their use as
surfactants
    • 甜菜碱 - 氧化胺,其制备方法及其作为表面活性剂的用途
    • US4588522A
    • 1986-05-13
    • US484528
    • 1983-04-13
    • Gunter BlaschkeAlwin RengJochen M. Quack
    • Gunter BlaschkeAlwin RengJochen M. Quack
    • B01F17/18C07C291/04C11D1/75C11D1/90C11D1/42C07C101/24C07C135/02C11D1/18
    • C11D1/90C07C291/04C11D1/75
    • Betaine-amine oxides of the formula ##STR1## in which R denotes alkyl, alkenyl or hydroxyalkyl, each of which has 8-22 carbon atoms, R.sup.1 denotes hydrogen or methyl, R.sup.2 denotes ethylene, propylene or 2-hydroxypropylene, R.sup.3, R.sup.4 and R.sup.5 can be identical or different and denote C.sub.1 -C.sub.3 -alkyl or a group of the formula ##STR2## or R.sup.3 denotes a group of the formula --R.sup.2 --BR.sup.4 R.sup.5, X denotes a direct bond or a group of the formula--CO--,A and B denote a group of the formulae ##STR3## it being necessary for at least one amine oxide group and at least one betaine group to be present, a denotes 0 or 1, b denotes 1, 2 or 3, n denotes a number from 0 to 10 and m denotes 1, 2 or 3. These compounds are obtained by partially quaternizing the parent polyamines with the alkali metal salt of an .omega.-halogenocarboxylic acid and then oxidizing the non-quaternized nitrogen atoms. These betaine-amine oxides are suitable for use as surfactants in cleansing agents.
    • 其中R表示烷基,烯基或羟烷基,其中每一个具有8-22个碳原子,R1表示氢或甲基,R2表示乙烯,丙烯或2-羟基亚丙基,R3,R4和 R 5可以相同或不同,表示C 1 -C 3 - 烷基或式“基团”或R 3表示式-R 2 -BR 4 R 5的基团,X表示直接键或式-CO-的基团, A和B表示至少一个氧化胺基团和至少一个甜菜碱基团所需的一组式(IMAGE),a表示0或1,b表示1,2或3,n表示数 0至10,m表示1,2或3.这些化合物通过将母体多胺与ω-卤代羧酸的碱金属盐部分季铵化,然后氧化未季铵化的氮原子而获得。 这些甜菜碱 - 胺氧化物适合用作清洁剂中的表面活性剂。