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    • 10. 发明授权
    • Polyacetylene production
    • 聚乙炔生产
    • US4564492A
    • 1986-01-14
    • US591470
    • 1984-03-20
    • David C. BottDonald White
    • David C. BottDonald White
    • C08F38/00C08F138/02C08G61/06C08G61/08C08J5/18D01F6/02H01B1/12
    • C08J5/18D01F6/02C08J2349/00Y10S264/47
    • This invention relates to a process for producing an oriented, crystalline poly(acetylene) (III) in film or fibrillar form by solvent casting a film from a solution of a polymer of the general formula (V) derived from a precursor monomer (IV), and transforming the pre-cast film of polymer (V) under tension or in a stress field into the poly(acetylene) (III). The transformation is carried out at a temperature between 20.degree. and 200.degree. C. under reduced pressure over a duration of between 1 and 100 hours in an atmosphere inert to the precursor polymer (V) film and to the poly(acetylene) (III). Poly(acetylenes) are conducting polymers and find use in solid state batteries, field effect transistors and the like.
    • 本发明涉及通过从衍生自前体单体(IV)的通式(V)的聚合物的溶液流延膜而制备膜或纤维形式的取向的结晶聚(乙炔)(III)的方法, ,并将聚合物(V)的预制膜在张力下或应力场中转化成聚(乙炔)(III)。 在惰性的前体聚合物(V)膜和聚(乙炔)(III))的气氛中,在减压下在1〜100小时的持续时间内,在20〜200℃的温度下进行转化, 。 聚(乙炔)是导电聚合物,可用于固态电池,场效应晶体管等。