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    • 3. 发明授权
    • Neutron transmutation doping of silicon single crystals
    • 硅单晶的中子转化掺杂
    • US5904767A
    • 1999-05-18
    • US705462
    • 1996-08-29
    • Chungpin Liao
    • Chungpin Liao
    • C30B29/06C30B31/20G06F19/00H01L21/261C30B15/02
    • C30B31/20
    • A working recipe for NTD CZ and MCZ silicon wafer production is provided. It teaches that a neutron-enhanced S-curve can be constructed by noting that a silicon interstitial (Si.sub.I), emitted due to volume change during the traditional oxygen precipitation, can join a neutron-created vacancy in facilitating further oxygen loss via precipitation. The former relation is: 2Si+2O.sub.I .fwdarw.SiO.sub.2 +Si.sub.i the latter is: vacancy+Si .sub.I +2O.sub.I .fwdarw.SiO ..sub.2 The total loss of oxygen interstitials is:�O.sub.I !=Max(�O .sub.I !.sub.0 �O .sub.I !.sub.s +min{2(�Si .sub.I !.sub.s +�Si .sub.I !.sub.0). �vacancy!}),with subscripts 0 and s standing for initial state and S-curve prediction, respectively; �Si.sub.I !.sub.s equal to 0.5�O .sub.I !.sub.s, and �vacancy! readily obtainable by computer simulation. �vacancy! is a function of the cadmium ratio (CR), silicon sample thickness, and total neutron fluence. The final oxygen interstitial content is: �0.sub.I !.sub.f =max{�O.sub.I !.sub.0 -�O.sub.I !,0}. Evidence for the effectiveness of the recipe taught by the present invention is provided in the form of characterization results derived from MOS capacitors and PN junctions built upon wafers produced according to the recipe. These show that the nominal minority carrier lifetime, interface density, and leakage currents under reverse bias are the same as those from a blank prime wafer.
    • 提供NTD CZ和MCZ硅晶片生产的工作配方。 它教导中子增强的S曲线可以通过注意到在传统的氧沉淀期间由于体积变化而发射的硅间隙(SiI)可以结合中子产生的空位来促进通过沉淀进一步的氧损失。 前一关系是:2Si + 2OI-> SiO2 + Sii后者是:空位+ Si I + 2OI-> SiO .2氧间隙的总损耗是:+ Z [OI] = Max([OI] 0 + Z [OI] s + min {2([Si I] s + [Si I] 0)。[空位]}),下标0和s分别表示初始状态和S曲线预测; [SiI]等于0.5 + Z [O I] s,[空位]可通过计算机模拟得到。 [空位]是镉比(CR),硅样品厚度和总中子通量的函数。 最终的氧气间质含量为:[0I] f = max {[OI] 0- + Z [OI],0}。 本发明教导的食谱的有效性的证据是以由根据配方生产的晶片上的MOS电容器和PN结产生的表征结果的形式提供的。 这些表明,反向偏置下的标称少数载流子寿命,界面密度和漏电流与来自空白原始晶圆的相同。
    • 4. 发明授权
    • Field effect transistor with offset region
    • 具有偏移区域的场效应晶体管
    • US5311051A
    • 1994-05-10
    • US854084
    • 1992-03-19
    • Masaru Tukizi
    • Masaru Tukizi
    • H01L21/261H01L21/265H01L29/08H01L29/78H01L29/76H01L29/94
    • H01L29/0847H01L29/7835
    • In a high breakdown voltage MOSFET having an offset region consisting of a low concentration impurity layer with the same conductivity type as that of a drain region between a channel region and the drain region, an impurity layer with conductivity type opposite to that of the drain region is formed on the surface of the offset region. With such a constitution, even for the case when the energy levels generated in the interface of silicon/oxide film under the environment of exposure to radiations act as the scattering centers, the drain current will not be affected by the levels. Further, the reliability of the high breakdown voltage MOSFET can be improved markedly, by suppressing the deterioration in the charge mobility due to generation of the interface levels and the accompanying reduction in the drain current.
    • 在具有与沟道区域和漏极区域之间的漏极区域具有相同导电类型的低浓度杂质层构成的偏移区域的高击穿电压MOSFET中,具有与漏极区域相反的导电类型的杂质层 形成在偏移区域的表面上。 通过这样的结构,即使在辐射照射环境下的硅/氧化膜的界面产生的能量水平作为散射中心的情况下,漏极电流也不受电平的影响。 此外,通过抑制由于界面电平的产生以及随之而来的漏极电流的降低导致的电荷迁移率的劣化,可以显着地提高高击穿电压MOSFET的可靠性。
    • 5. 发明授权
    • Process for decreasing crystal damages in the production of n-doped
silicon by neutron bombardment
    • 通过中子轰击在减少n掺杂硅的生产中降低晶体损伤的方法
    • US4260448A
    • 1981-04-07
    • US889172
    • 1978-03-23
    • Heinz Herzer
    • Heinz Herzer
    • G21G1/06H01L21/261C30B31/20
    • H01L21/261G21G1/06
    • A process for decreasing crystal damages in the production of n-doped silicon by neutron bombardment, in which phosphorus atoms are formed from silicon by nuclear transmutation, wherein the number of desired phosphorus atoms N.sub.31.sbsb.p per cc, can be calculated by the known equationN.sub.31.sbsb.p =N.sub.30.sbsb.Si .multidot..sigma..multidot..phi..multidot.tin which N.sub.30.sbsb.Si is the number of .sup.30 Si-isotopes per cc, .sigma.=0.13 barn effective cross section, .phi. the flux density of the thermal neutrons per cm.sup.2 and t the bombardment time in seconds, the process consisting of adjusting the ratio between thermal and fast neutrons in the neutron flux acting upon the bombarded silicon work piece, so that the higher the ratio, the higher the specific resistance of the bombarded silicon, and thus, the lower the number of N.sub.31.sbsb.p and therewith the acting dose .phi..multidot.t.
    • 通过中子轰击减少在n掺杂硅中产生晶体损伤的方法,其中磷原子由硅通过核变换形成,其中所需磷原子数N31p / cc可以通过已知的方程式计算N31p = N30Six 西格玛x phi xtin,其中N30Si是每cc的30Si同位素数,sigma = 0.13巴有效截面,phi是每平方厘米热中子的通量密度,t是以秒为单位的轰击时间,该过程由调整 作用于被轰击的硅工件的中子通量中的热和快中子,使得比率越高,被轰击的硅的电阻率越高,因此N31p的数量越少,并且由此施加剂量。
    • 9. 发明授权
    • Location selective transmutation doping on silicon wafers using high
energy deuterons
    • 使用高能量氘核在硅晶片上的位置选择性转换掺杂
    • US6100168A
    • 2000-08-08
    • US192452
    • 1998-11-16
    • Chungpin LiaoMeihua ChaoShan-Ming Lan
    • Chungpin LiaoMeihua ChaoShan-Ming Lan
    • H01L21/261
    • H01L21/261Y10S438/974
    • Efficient transmutation doping of silicon through the bombardment of silicon wafers by a beam of deuterons is described. A key feature of the invention is that the deuterons are required to have an energy of at least 4 MeV, to overcome the Coulomb barrier and thus achieve practical utility. When this is done, transmutationally formed phosphorus in concentrations as high as 10.sup.16 atoms per cc. are formed from deuteron beams having a fluence as low as 10.sup.19 deuterons per square cm. As a byproduct of the process sulfur is also formed in a practical concentration range of about 10.sup.14 atoms per cc. This can be removed by annealing at temperatures in the order of 700 .degree. C. Additional sulfur continues to form as a result of the decay of P.sup.32. Because of the high energy of the deuterons, several silicon wafers may be processed simultaneously if a suitable mask is available and proper alignment is achieved. It is expected that the additional phosphorus is essentially uniformly deposited throughout the entire thickness of a wafer. Masks, either freestanding or contact, may also be used in order to limit the transmuted regions to particular desired areas.
    • 描述了通过氘核的束对硅晶片的轰击的硅的有效的transm变掺杂。 本发明的一个关键特征是氘核需要具有至少4MeV的能量,以克服库仑势垒,从而实现实用性。 当这样做时,以浓度高达每立方厘米1016原子的透射形成的磷。 由具有低至1019氘核每平方厘米的注量的氘核束形成。 作为该方法的副产物,硫也在约1014个原子/ cc的实用浓度范围内形成。 这可以通过在700℃的温度退火而除去。由于P32的衰变,附加的硫继续形成。 由于氘核的高能量,如果合适的掩模可用并且实现了适当的对准,则可以同时处理几个硅晶片。 预期在晶片的整个厚度上附加的磷基本均匀地沉积。 也可以使用独立或接触的面罩,以便将变形区域限制到特定的所需区域。