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    • 1. 发明申请
    • OLIGOMERIZATION OF PROPYLENE TO PRODUCE BASE OIL PRODUCTS USING IONIC LIQUIDS-BASED CATALYSIS
    • 使用基于离子液体的催化剂生产基础油产品的丙烯的低级化
    • US20110034748A1
    • 2011-02-10
    • US12538738
    • 2009-08-10
    • Saleh ElomariStephen J. Miller
    • Saleh ElomariStephen J. Miller
    • C07C2/20C07C2/04
    • C10G29/205C10G2300/1092C10G2300/301C10G2300/302C10G2300/304C10G2400/10
    • We provide a process, comprising: a. oligomerizing propylene in ionic liquid; b. optionally alkylating the oligomer; to make a base oil having: i. a kinematic viscosity at 100° C. of 2.9 mm2/s or greater, ii. a viscosity index from 25 to 90, and iii. a low cloud point. We provide a process, comprising: oligomerizing a feed comprising propylene and propane to make a base oil having: i. from 45 to 70 wt % hydrocarbons boiling at 900° F. or higher, ii. a viscosity index from 25 to 90, and iii. a low cloud point. We provide a process, comprising: a. mixing longer chain alpha olefins with propylene; b. oligomerizing the feed, to make a base oil having: i. a kinematic viscosity at 100° C. greater than 10 mm2/s; ii. a viscosity index from 50 to 90; iii. a low pour point; and iv. a low cloud point.
    • 我们提供一个过程,包括:a。 在离子液体中使丙烯低聚; b。 任选地使低聚物烷基化; 制作基础油,具有:i。 在100℃下的运动粘度为2.9mm 2 / s以上,ii。 粘度指数为25至90,和iii。 低浊点。 我们提供一种方法,其包括:使包含丙烯和丙烷的进料低聚以制备具有以下成分的基础油: 在90°F或更高沸点的45至70wt%烃,ii。 粘度指数为25至90,和iii。 低浊点。 我们提供一个过程,包括:a。 将长链α-烯烃与丙烯混合; b。 使进料低聚,以制备具有以下成分的基础油:i。 100°C下的运动粘度大于10 mm2 / s; ii。 粘度指数为50〜90; iii。 低倾点; 和iv。 低浊点。
    • 3. 发明授权
    • Production of monoolefin oligomer
    • 单烯烃低聚物的生产
    • US5877375A
    • 1999-03-02
    • US659661
    • 1996-06-06
    • Michel Clarembeau
    • Michel Clarembeau
    • C07C2/20C07C2/08
    • C07C2/20C07C2527/1213C07C2531/02
    • A monoolefin oligomerization process which gives high yields of dimer and trimer at high monoolefin conversions in a single stage reaction is described. The process involves contacting a C.sub.6-20 vinyl olefin with a catalyst comprising boron trifluoride and from 0.075 to 0.5 mol %, based on the total quantity of monoolefin being used, of an alcohol catalyst promoter. The oligomerization is performed at a temperature below about 40.degree. C. and under a pressurized atmosphere of boron trifluoride in the range of 2 to 4 bars gauge until the monoolefin conversion is at least 95% and the combined total of dimer and trimer in the liquid reaction mixture is at least 60% by weight.
    • 描述了在单阶段反应中在高单烯烃转化下提供高产率的二聚物和三聚体的单烯烃低聚方法。 该方法包括使C 6-20乙烯基烯烃与包含三氟化硼的催化剂和基于所使用的单烯烃的总量的0.075至0.5mol%的醇催化剂促进剂接触。 低聚反应在低于约40℃的温度下进行,并在三氟化硼的压力气氛下在2至4巴的规格范围内进行,直到单烯烃转化率至少为95%,液体中二聚体和三聚体的总和 反应混合物为至少60重量%。