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1. 发明申请

US20050090694A1 Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore 有权
标题翻译：因此烯属不饱和化合物和催化剂的羰基化方法
公开(公告)号：US20050090694A1
公开(公告)日：2005-04-28
申请号：US10505019
申请日：2003-02-18
申请人： Eit Drent , Renata Van Der Made , Robert Pugh , Paul Pringle
发明人： Eit Drent , Renata Van Der Made , Robert Pugh , Paul Pringle
IPC分类号： B01J31/24 , B01J31/28 , C07B61/00 , C07C45/49 , C07C51/14 , C07C51/54 , C07C53/122 , C07C67/36 , C07C67/38 , C07C69/738 , C07F9/6564 , C07F9/6568
CPC分类号： B01J31/2485 , B01J31/28 , B01J2231/321 , B01J2531/80 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07C51/14 , C07F9/65683 , C07C53/122
摘要： A process for the carbonylation of an ethylenically unsaturated compound with carbon monoxide and a co-reactant. The carbonylation reaction is carried out in the presence of a novel catalyst involving: a) a source of a group VIII metal; b) a bidentate diphosphine of formula I, wherein R1 represents a bivalent radical that together with the phosphorus atom to which it is attached is an optionally substituted 2-phospha-tricyclo[3.3.1.1{3,7}]-decyl group or a derivative thereof in which one or more of the carbon atoms are replaced by heteroatoms (“2-PA” group); wherein R2 and R3 independently represent univalent radicals of up to 20 atoms or jointly form a bivalent radical of up to 20 atoms; and wherein A1 and A2 independently represent optionally substituted alkylene groups and R represents an optionally substituted aromatic group; and, c) a source of anions.
摘要翻译：用一氧化碳和共反应物羰基化烯属不饱和化合物的方法。羰基化反应在新型催化剂存在下进行，包括：a）VIII族金属源; b）式I的二齿二膦，其中R 1表示与连接的磷原子一起为任选取代的2-磷杂三环[3.3.1.1 {3， 7}] - 癸基或其衍生物，其中一个或多个碳原子被杂原子（“2-PA”基团）代替）; 其中R 2和R 3独立地表示至多20个原子的一价基团或共同形成至多20个原子的二价基团; 并且其中A 1和A 2独立地表示任选取代的亚烷基，R表示任选取代的芳族基团; 和c）阴离子的来源。

2. 发明授权

US5512668A Solid phase oligonucleotide synthesis using phospholane intermediates 失效
标题翻译：使用磷脂中间体的固相寡核苷酸合成
公开(公告)号：US5512668A
公开(公告)日：1996-04-30
申请号：US826929
申请日：1992-01-23
申请人： Wojciech J. Stec , Andrzej Grajkowski , Bogdan Uznanski
发明人： Wojciech J. Stec , Andrzej Grajkowski , Bogdan Uznanski
IPC分类号： C07F9/6564 , C07F9/6578 , C07H19/10 , C07H19/20 , C07H21/00 , C07H21/04 , C07H21/02
CPC分类号： C07H21/00 , C07F9/6564 , C07F9/6578 , C07H19/10 , C07H19/20
摘要： Methods and compounds are provided for solid phase synthesis of oligonucleotides and related polymers by condensing protected monomer-O- 1,3,2-dichalcogen-substituted-phospholane! synthons in the presence of a catalytic base. Compounds of the invention include 2-N-substituted-1,3,2-dichalcogen-substituted-phospholane precursors of the above synthons, the protected monomer-O- 1,3,2-dichalcogen-substituted-phospholane! synthons, and P-chiral oligonucleotides and related P-chiral polymers.
摘要翻译：提供方法和化合物用于通过在催化碱存在下缩合受保护的单体-O- [1,3,2-二硫化物取代的 - 磷脂]合成子来固相合成寡核苷酸和相关聚合物。本发明的化合物包括上述合成子的2-N-取代-1,3,2-二硫代磷酸酯前体，被保护的单体-O- [1,3,2-二硫代碳原子取代的 - 磷脂]合成子，和 P-手性寡核苷酸和相关的P-手性聚合物。

3. 发明授权

US5449798A Phospholipid derivatives containing higher elements of the fifth group 失效
标题翻译：磷脂衍生物含有较高元素的第五组
公开(公告)号：US5449798A
公开(公告)日：1995-09-12
申请号：US124492
申请日：1993-09-22
申请人： Gerhard Nossner , Jurij Stekar , Peter Hilgard , Bernhard Kutscher , Jurgen Engel
发明人： Gerhard Nossner , Jurij Stekar , Peter Hilgard , Bernhard Kutscher , Jurgen Engel
IPC分类号： A61K31/66 , A61K31/285 , A61K31/665 , A61K31/67 , A61K31/675 , A61K38/00 , A61P3/00 , A61P7/02 , A61P19/10 , A61P31/04 , A61P31/12 , A61P33/02 , A61P35/00 , A61P37/00 , A61P43/00 , C07F9/09 , C07F9/10 , C07F9/54 , C07F9/655 , C07F9/6564 , C07F9/66 , C07F9/68 , C07F9/72 , C07F9/90 , C07F9/94 , C07F9/70
CPC分类号： C07F9/723 , C07F9/5407
摘要： Phospholipid derivatives containing higher elements of the Vth main group (P, As, Sb, Bi), their method of preparation and antineoplastic and antimicrobially active medications that can be prepared from the phospholipid derivatives.
摘要翻译：含有Th2主要组分（P，As，Sb，Bi）的更高元素的磷脂衍生物，它们的制备方法以及可从磷脂衍生物制备的抗肿瘤和抗微生物活性药物。

4. 发明授权

US5053546A Chiral compounds of the beta-binaphthyl type, their preparation and their use 失效
标题翻译：二苯乙烯类型的化合物及其制备及其使用
公开(公告)号：US5053546A
公开(公告)日：1991-10-01
申请号：US446843
申请日：1989-12-06
申请人： Dieter Kaufman
发明人： Dieter Kaufman
IPC分类号： C07D487/08 , C07B53/00 , C07C45/69 , C07C62/36 , C07D493/08 , C07D497/08 , C07F5/02 , C07F5/04 , C07F5/06 , C07F7/18 , C07F7/22 , C07F9/145 , C07F9/18 , C07F9/24 , C07F9/6564 , C07F19/00
CPC分类号： C07F9/6564 , C07C45/69 , C07F5/04
摘要： New chiral compounds of the formula ##STR1## a process for their preparation and their use for the preparation of optically active compounds.
摘要翻译：式（I）的新型手性化合物（I）它们的制备方法及其用于制备光学活性化合物的方法。

5. 发明授权

US5008457A Chiral phospholane transition metal catalysts 失效
标题翻译：手性磷脂过渡金属催化剂
公开(公告)号：US5008457A
公开(公告)日：1991-04-16
申请号：US524737
申请日：1990-05-17
申请人： Mark J. Burk
发明人： Mark J. Burk
IPC分类号： B01J31/22 , C07F9/6564 , C07F9/6568 , C07F15/00 , C07F15/02
CPC分类号： C07F9/65683 , C07F15/0073
摘要： Chiral 2,5-disubstituted phospholanes useful as transition metal ligands in asymmetric catalysis and processes for their preparation are disclosed.
摘要翻译：公开了在不对称催化中用作过渡金属配体的手性2,5-二取代磷脂及其制备方法。

6. 发明申请

US20110054078A1 PHOSPHORUS-CONTAINING COMPOUNDS USEFUL FOR MAKING HALOGEN-FREE, IGNITION-RESISTANT POLYMERS 有权
标题翻译：用于制备无卤素，耐点火聚合物的含磷化合物有用
公开(公告)号：US20110054078A1
公开(公告)日：2011-03-03
申请号：US12939725
申请日：2010-11-04
申请人： Joseph Gan
发明人： Joseph Gan
IPC分类号： C07F9/6564 , C07F9/576
CPC分类号： C08L61/00 , C07F9/657172 , C08G59/1488 , C08G59/304 , C08G59/3254 , C08G79/04 , C08K5/53 , C08K5/5313 , C08L61/14 , C08L63/00 , C08L63/04 , C09K21/12 , C09K21/14
摘要： Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P═O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R′(Y)m′]m(X—O—R″)n Formula (I) wherein R′ is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R″ is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m′, m and n are, independently, numbers equal to or greater than 1; and (C) a thermosetting or thermoplastic composition. These compounds are useful for making flame retardant epoxy and polyurethane resins and ignition resistant thermoplastic resins, each of which is useful for a variety of end uses requiring flame retardancy or ignition resistance. Flame retardant epoxy resins may be used to make electrical laminates. Flame retardant polyurethane is useful for making rigid polyurethane foam used in construction and flexible polyurethane foam used to make vehicle upholstery. Ignition resistant thermoplastic resins are useful for making television cabinets, computer monitors, printer housings, automotive parts, and housings and parts for appliances. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.
摘要翻译：公开了含磷化合物，其可通过以下方法获得：（A）至少一种具有选自H-P = O的基团的有机磷化合物; P-H族和P-OH基; 和（B）至少一种具有下式（I）的化合物：[R'（Y）m'] m（X-O-R“）n其中R'是有机基团的式（I） Y是选自羟基，羧酸和胺的官能团; X是亚烃基; R“是氢或具有1至8个碳原子的烃基，R是具有1至12个碳原子的烷基或芳基; m'，m和n独立地为等于或大于1的数; 和（C）热固性或热塑性组合物。这些化合物可用于制备阻燃环氧树脂和聚氨酯树脂和耐点火热塑性树脂，其各自可用于需要阻燃性或耐点火性的各种最终用途。阻燃环氧树脂可用于制造电气层压板。阻燃聚氨酯可用于制造用于建筑的硬质聚氨酯泡沫和用于制造车辆装饰的柔性聚氨酯泡沫。耐点火热塑性树脂可用于制作电视机柜，电脑显示器，打印机外壳，汽车零件以及家用电器的外壳和零件。本发明特别适用于其中需要或期望低溴或低卤素含量的最终用途。

7. 发明申请

US20090131370A1 Novel Nucleoside Derivatives 审中-公开
标题翻译：新型核苷衍生物
公开(公告)号：US20090131370A1
公开(公告)日：2009-05-21
申请号：US11572785
申请日：2005-07-29
申请人： K. Raja Reddy , Mark D. Erion
发明人： K. Raja Reddy , Mark D. Erion
IPC分类号： A61K31/675 , C07D473/30 , A61K31/522 , A61P31/14 , C07F9/6564
CPC分类号： C07H19/04 , C07H19/20
摘要： Compounds of Formulae I-XVI, stereoisomers, and pharmaceutically acceptable salts or prodrugs thereof, their preparation, and their uses for the treatment of viral diseases including hepatitis C viral infection, cancer, diabetes, and other diseases are described: formula (I).
摘要翻译：式I-XVI的化合物，立体异构体及其药学上可接受的盐或前药，其制备方法及其用于治疗包括丙型肝炎病毒感染，癌症，糖尿病和其他疾病在内的病毒疾病的用途描述如下：式（I）。

8. 发明申请

US20080045465A1 Phosphole Derivatives Complexed with Metals, and Pharmaceutical Uses Thereof 有权
标题翻译：与金属络合的磷矿衍生物及其药物用途
公开(公告)号：US20080045465A1
公开(公告)日：2008-02-21
申请号：US11658694
申请日：2005-07-29
申请人： Elisabeth Davioud-Charvet , Katja Becker-Brandenburg , Valerie Deborde , Regis Reau , R. Heiner Schirmer , Christel Herold-Mende
发明人： Elisabeth Davioud-Charvet , Katja Becker-Brandenburg , Valerie Deborde , Regis Reau , R. Heiner Schirmer , Christel Herold-Mende
IPC分类号： A61K31/675 , A61P17/06 , A61P19/02 , A61P31/18 , A61P35/00 , C07F9/6564 , C07H23/00
CPC分类号： A61K31/675 , A61K31/555
摘要： The invention concerns pharmaceutical compositions comprising as active compound at least one compound of general formula (A), wherein: M represents a metal atom, and their uses in particular for preventing or treating pathologies associated with an excess activity of glutathion reductase and/or thioredoxin reductase.
摘要翻译：本发明涉及包含至少一种通式（A）的化合物作为活性化合物的药物组合物，其中：M表示金属原子，特别是其用于预防或治疗与谷胱甘肽还原酶和/或硫氧还蛋白过量活性相关的病症还原酶。

9. 发明授权

US5675001A Heteroatom-functionalized porphyrazines and multimetallic complexes and polymers derived therefrom 失效
标题翻译：杂原子官能化的四氮杂卟啉和多金属络合物及其衍生的聚合物
公开(公告)号：US5675001A
公开(公告)日：1997-10-07
申请号：US403302
申请日：1995-03-14
申请人： Brian M. Hoffman , Anthony G. M. Barrett
发明人： Brian M. Hoffman , Anthony G. M. Barrett
IPC分类号： C07D487/22 , C07D491/22 , C07D495/22 , C07D497/22 , C07D498/22 , C07F1/00 , C07F1/08 , C07F3/00 , C07F5/00 , C07F5/06 , C07F7/22 , C07F7/24 , C07F7/30 , C07F9/6561 , C07F9/6564 , C07F15/00 , C07F15/04 , C07D478/22 , C09B47/00 , C09B62/00
CPC分类号： C07D487/22 , C07D491/22 , C07D497/22 , C07D498/22 , C07F9/6561
摘要： Porphyrazine compounds having moieties substituted at the eight peripheral .beta.-pyrrole positions are disclosed. The porphyrazine compounds have the general structural formula: ##STR1## wherein M is H.sub.2 or a metal capable of complexing with the pyrrole nitrogen atoms, and A, B, C and D are independently selected from the group consisting of a thio moiety, an amino moiety, an oxo moiety, a phospho moiety, a seleno moiety, a telluro moiety and a non-coordinating moiety, like a hydrocarbon moiety, with the proviso that not all of A, B, C and D are a thio moiety and that not all of A, B, C, and D are a hydrocarbon moiety. The porphyrazine compounds, depending on the identity of A, B, C and D, are capable of complexing one to four metal ions to the periphery of the porphyrazine to form a multimetallic porphyrazine. Multimetallic porphyrazine compounds can be linked by the peripherally-complexed metal ions to form a linear, i.e., ribbon, polymer or a two-dimension, i.e., sheet polymer. The porphyrazine compounds, and the multimetallic complexes and polymers derived therefrom, are useful in, or as, magnet materials, molecular metal conductors, pharmaceuticals, imaging agents, and dyes.
摘要翻译：公开了在八个外围β-吡咯位置取代部分的四氮杂卟啉化合物。四氮杂卟啉化合物具有以下通式结构式：其中M为H 2或能与吡咯氮原子络合的金属，A，B，C和D独立地选自硫基部分，氨基部分，氧代部分，磷酸部分，硒部分，尾流部分和非配位部分，如烃部分，条件是不是全部A，B，C和D都是硫基部分，而不是全部所有A，B，C和D都是烃部分。取决于A，B，C和D的同一性，四氮杂卟啉化合物能够将1-4个金属离子络合到四氮杂卟啉的周围以形成多金属四氮杂卟啉。多金属四氮杂卟啉化合物可以通过周边配合的金属离子连接以形成线性，即带状聚合物或二维即片状聚合物。四氮杂卟啉化合物及其衍生的多金属络合物和聚合物可用于或作为磁体材料，分子金属导体，药物，成像剂和染料。

10. 发明授权

US4827067A Azaphospholenes and use thereof 失效
标题翻译： Azaphospholenes及其用途
公开(公告)号：US4827067A
公开(公告)日：1989-05-02
申请号：US246577
申请日：1988-09-19
申请人： Gunther Wilke , Jaroslaw Monkiewicz , Herbert Kuhn
发明人： Gunther Wilke , Jaroslaw Monkiewicz , Herbert Kuhn
IPC分类号： B01J31/14 , B01J31/00 , B01J31/22 , B01J31/24 , C07B61/00 , C07C2/04 , C07C2/32 , C07C5/29 , C07C5/31 , C07C13/12 , C07C13/40 , C07C15/44 , C07F9/6564 , C07F9/6584 , C07C2/42
CPC分类号： C07F9/6584 , C07C2/04 , C07C5/31 , C07C2101/10 , C07C2102/42 , C07C2531/02 , C07C2531/14 , C07C2531/22
摘要： The invention relates to azaphospholene of the type ##STR1## wherein R.sub.1 and R.sub.2 may be alkyl, aryl and aralkyl groups, processes for preparing same and the use thereof.
摘要翻译：本发明涉及类型“IMAGE”的氮杂磷脂，其中R 1和R 2可以是烷基，芳基和芳烷基，其制备方法及其用途。

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