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    • 6. 发明授权
    • Process for producing (meth)acrylic resin composition
    • US10184015B2
    • 2019-01-22
    • US15553714
    • 2016-02-26
    • KURARAY Co., Ltd.
    • Hiroshi OzawaYasuhito KitadeShouji Tanaka
    • C08F6/28C08F20/14C08F2/02C08F6/10C08F220/14
    • A method for producing a (meth)acrylic resin composition, comprising: continuously feeding reaction starting materials to a tank reactor, the reaction starting materials comprising a polymerizable monomer component, a chain transfer agent and a radical polymerization initiator, the polymerizable monomer component comprising 50 to 100% by mass of methyl methacrylate, 0 to 20% by mass of an acrylic acid alkyl ester and 0 to 30% by mass of an additional monomer; conducting bulk polymerization of the polymerizable monomer component at a polymerization conversion ratio of 40 to 70% by mass to obtain a liquid containing a (meth)acrylic resin; continuously feeding the resulting liquid to a vented extruder to separate volatile component from the (meth)acrylic resin; conducting distillation using an atmospheric distillation column to separate the volatile component into a high boiling fraction (C1) and a low boiling fraction (A1); and conducting distillation using a vacuum distillation column having a pressure of −50 kPaG to −101 kPaG at the top of the vacuum distillation column to separate the high boiling fraction (C1) into a high boiling fraction (C2) and a low boiling fraction (A2); reusing the low boiling fraction (A1) and the low boiling fraction (A2) as part of the reaction starting materials.
    • 10. 发明授权
    • Distilled epoxy novolac resins
    • US09644067B2
    • 2017-05-09
    • US15103100
    • 2014-12-17
    • BLUE CUBE IP LLC
    • William W. FanDennis W. JewellStephen B. WallaceTravis H. Larsen
    • C08G59/02C08G59/08C08F6/28
    • C08G59/025C08G59/08
    • A continuous process comprising: a) separating a starting epoxy novolac resin comprising oligomers having an average functionality of greater than 2.5 and a hydrolyzable chlorine content of less than 450 ppm with a first continuous evaporator apparatus under a vaporization temperature in the range of from 150° C. to 250° C. and an absolute pressure of from 0.05 to 1 mmHg absolute to form a first vapor fraction comprising epoxy novolac resin having more than 95 weight percent of 2-functional components and wherein the mass of the first vapor fraction is in the range of from 5 to 20 weight percent of the starting epoxy novolac resin; and a first bottom fraction comprising epoxy novolac resin having a lower weight percent of 2-functional components in comparison with the weight percent of 2-functional components of the starting epoxy novolac resin; b) recovering the first bottom fraction; and c) condensing from 95 weight percent to 99.95 weight percent of the first vapor fraction at a temperature in the range of from 50° C. to 200° C. to form a first partially condensed vapor fraction product having at least 95 weight percent of 2-functional components and having a total chlorine content of less than 900 ppm and an uncondensed vapor product comprising halogenated impurities, is disclosed.