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1. 发明授权

US09926386B2 Living radical polymerization catalyst, and polymer production method using same 有权
公开(公告)号：US09926386B2
公开(公告)日：2018-03-27
申请号：US15117640
申请日：2015-02-10
申请人： Kyoto University
发明人： Atsushi Goto
IPC分类号： C08F4/08 , C08F4/04 , C08F120/14 , B01J27/138 , C08F4/40 , C08F4/80
CPC分类号： C08F4/08 , B01J27/138 , C08F4/04 , C08F112/08 , C08F120/14 , C08F2438/00 , C08F2438/01
摘要： An object of the present invention is to provide a living radical polymerization catalyst that is excellent in terms of safety and cost, and is applicable to various vinyl monomers, and to provide a method for producing a polymer using this living radical polymerization catalyst. The living radical polymerization catalyst contains at least one member selected from the group consisting of alkali metal halide compounds and alkaline earth metal halide compounds.

2. 发明申请

US20170362442A1 LIQUID (METH)ACRYLIC SYRUP, METHOD FOR IMPREGNATING A FIBROUS SUBSTRATE WITH SAID SYRUP, AND COMPOSITE MATERIAL PRODUCED AFTER POLYMERISATION OF SAID IMPREGNATION SYRUP 审中-公开
公开(公告)号：US20170362442A1
公开(公告)日：2017-12-21
申请号：US15538927
申请日：2015-12-22
申请人： Arkema France
发明人： Pierre Gerard , Sébastien TAILLEMITE , Daniel CALIN
IPC分类号： C09D4/06 , C08F120/14 , B29C70/48
CPC分类号： C09D4/06 , B29C70/48 , C08F120/14 , C08F220/14 , C08F265/06 , C08J5/24 , C08J2333/04 , C08L33/06 , C09D133/06 , C08F220/18
摘要： The invention relates to a viscous liquid (meth)acrylic syrup comprising: a) a (meth)acrylic polymer, b) a (meth)acrylic monomer, c) an initiator to start the polymerization of the (meth)acrylic monomer, said initiator being in the form of a peroxide compound that is liquid in a temperature range of between 0° and 50° C., said syrup being characterized in that the initiator is combined with an accelerating system comprising: d) a vanadium salt and e) a tertiary amine.

3. 发明申请

US20160243051A1 MONO DISPERSE POLYMER NANOPARTICLES, FUNCTIONALIZED NANOPARTICLES AND CONTROLLED FORMATION METHOD 审中-公开
标题翻译：单分散聚合物纳米粒子，官能化纳米颗粒和控制形成方法
公开(公告)号：US20160243051A1
公开(公告)日：2016-08-25
申请号：US15030755
申请日：2014-10-24
申请人： THE CURATORS OF THE UNIVERSITY OF MISSOURI
发明人： Srikar RAMAN , Raghuraman KANNAN , Jatin VIMAL
IPC分类号： A61K9/51 , B01J2/04 , C08F120/14 , A61J3/02
CPC分类号： A61K9/5192 , A61J3/02 , A61K9/5138 , B01J2/04 , C08F120/14
摘要： A method produces polymer nanoparticles. Polymer solution is sprayed through a nozzle toward a collector. An electric field is created at the nozzle, such as by a voltage is applied to the nozzle to create the electric field. The voltage applied to the nozzle is from ˜10 (Kilovolt) to ˜30 (Kilovolt), distance from nozzle tip to collector is from ˜1 (centimeter) to ˜10 (centimeter) and the polymer concentration from ˜0.01% to ˜0.5% w/w. Preferably a grounded liquid collectors is used. The invention provides biocompatible monodisperse polymer nanoparticles having a size of less than ˜300 nm, preferably less than ˜150 nm. Payloads can be associated, and maintain efficacy, including more than one payload such as therapeutic agents and diagnostic agents on the same particles. Preferred particles are poly(methyl methacrylate) (PMMA-COOH) or acrylate analogues.
摘要翻译：一种方法产生聚合物纳米颗粒。聚合物溶液通过喷嘴朝向收集器喷射。在喷嘴处产生电场，例如通过向喷嘴施加电压以产生电场。施加到喷嘴的电压为〜10（千伏）〜〜30（千伏），从喷嘴尖到收集器的距离为〜（厘米）〜〜10厘米，聚合物浓度为〜0.01〜％w / w。优选使用接地液体收集器。本发明提供具有小于〜300nm，优选小于〜150nm的尺寸的生物相容性单分散聚合物纳米颗粒。有效载荷可以相关联，并保持功效，包括多个有效载荷，如治疗剂和诊断剂在同一颗粒上。优选的颗粒是聚（甲基丙烯酸甲酯）（PMMA-COOH）或丙烯酸酯类似物。

4. 发明申请

US20160096937A1 FILM 有权
标题翻译：电影
公开(公告)号：US20160096937A1
公开(公告)日：2016-04-07
申请号：US14891544
申请日：2014-05-16
申请人： KURARAY CO., LTD.
发明人： Toru TAKAHASHI , Atsuhiro NAKAHARA , Hiroshi OZAWA , Toru ABE , Yusaku NOMOTO
IPC分类号： C08J5/18
CPC分类号： C08J5/18 , C08F120/14 , C08J2333/06 , C08J2333/12 , C08J2369/00 , C08L33/10 , C08L33/12 , C08L2205/025 , G02B5/3033 , C08L69/00
摘要： A film is obtained by forming a methacrylic resin composition comprising 100 parts by mass of a methacrylic resin (A) and preferably 1 to 10 parts by mass of a polycarbonate resin, the methacrylic resin (A) having a triad syndiotacticity (rr) of not less than 58%, a weight average molecular weight of 50000 to 150000, a content of fraction having a molecular weight of not less than 200000 of 0.1 to 10% by mass and a content of fraction having a molecular weight of less than 15000 of 0.2 to 5% by mass. A polarizer protective film comprising the above film is obtained.
摘要翻译：通过形成包含100质量份甲基丙烯酸系树脂（A），优选1〜10质量份的聚碳酸酯树脂的甲基丙烯酸系树脂组合物，具有三元组间同立构规整度（rr）的甲基丙烯酸系树脂（A）小于58％，重均分子量为50000至150000，分子量不小于200000的分数为0.1至10质量％，分子量小于15000的分数为0.2 至5质量％。得到包含上述膜的偏振片保护膜。

5. 发明申请

US20150232591A1 (METH)ACRYLATE COMPOSITION 有权
标题翻译：（METH）丙烯酸酯组合物
公开(公告)号：US20150232591A1
公开(公告)日：2015-08-20
申请号：US14429598
申请日：2013-08-09
申请人： AUTONETWORKS TECHNOLOGIES, LTD. , SUMITOMO WIRING SYSTEMS, LTD. , SUMITOMO ELECTRIC INDUSTRIES, LTD. , KYUSHU UNIVERSITY
发明人： Tatsuya Hase , Kazuo Nakashima , Makoto Mizoguchi
IPC分类号： C08F122/10 , C07D307/16 , C08F120/20 , C08F120/12 , C08F120/14 , C08F120/28 , C07C69/54 , C07C69/602
CPC分类号： C08F122/105 , C07C69/54 , C07C69/602 , C07D307/16 , C08F2/48 , C08F8/30 , C08F20/10 , C08F120/12 , C08F120/14 , C08F120/20 , C08F120/28 , C08F2220/343 , C08G18/4825 , C08G18/672 , C08G18/73 , C08G65/3322 , C08L33/00 , C08L71/02 , C09D4/06 , C09D133/08 , C09D133/10 , C09D133/14 , C09D175/16 , C09J4/06 , C09J133/08 , C09J133/10 , C09J133/14 , C09J175/16 , C08L75/08 , C08G18/48
摘要： Presented is a (meth)acrylate composition that can be cured even in an unirradiated portion that is not reached by light. The (meth)acrylate composition contains a compound having one or more vinyl groups in a molecular structure thereof. The compound has a ratio of a molecular weight thereof to a number of the vinyl groups of 300 or lower. The composition generates a heat of reaction during photopolymerization thereof, and the heat of reaction causes thermal polymerization of the composition.
摘要翻译：呈现即使在未被光照射的未照射部分也能固化的（甲基）丙烯酸酯组合物。（甲基）丙烯酸酯组合物含有其分子结构中具有一个或多个乙烯基的化合物。该化合物的分子量与乙烯基数的比例为300以下。该组合物在其光聚合期间产生反应热，反应热引起组合物的热聚合。

6. 发明申请

US20150158237A1 VACUUM FORMING PROCESS AND USE 审中-公开
标题翻译：真空成型工艺和使用
公开(公告)号：US20150158237A1
公开(公告)日：2015-06-11
申请号：US14412477
申请日：2013-06-20
申请人： EVONIK INDUSTRIES AG
发明人： Torsten Frank , Manfred Rimpl , Vitali Klein
IPC分类号： B29C51/10 , C08L27/16 , C08L33/12 , C08L69/00 , C08F120/14 , C08G64/00
CPC分类号： B29C51/10 , B29C37/0028 , B29C51/002 , B29C51/06 , B29C51/14 , B29C51/421 , B29C2791/006 , B29C2791/007 , B29C2793/009 , B29K2033/12 , B29K2069/00 , B29K2995/0018 , B29K2995/0026 , B29L2031/3052 , B29L2031/778 , C08F120/14 , C08G64/00 , C08L27/16 , C08L33/12 , C08L69/00 , C08L2201/10
摘要： A vacuum thermoforming process for producing a transparent molding free from optical defects, whereby the prior temperature of the mold and preform is controlled, the preform is premolded, the mold is shaped under sub-atmospheric pressure, the mold shape is cooled, and the transparent molding is removed. The transparent plastic molding is produced from polymethyl methacrylate (PMMA) or polycarbonate (PC) with particularly good optical quality and with relatively low cycle times. Upon removal, these moldings are dimensionally stable, free from distortion, and exhibit no surface defects such as pimples.
摘要翻译：一种用于制造无光学缺陷的透明模制品的真空热成型方法，由此控制模具和预制件的先前温度，将预成型坯预成型，模具在低于大气压的压力下成型，模具形状被冷却，透明成型被去除。透明塑料模塑由具有特别好的光学质量和相对低的循环时间的聚甲基丙烯酸甲酯（PMMA）或聚碳酸酯（PC）生产。去除时，这些模制件尺寸稳定，没有变形，并且没有表现出缺陷，例如粉刺。

7. 发明申请

US20150018446A1 ORGANOCATALYZED PHOTOREDOX MEDIATED POLYMERIZATION USING VISIBLE LIGHT 有权
标题翻译：使用可见光的有机硅化合物介质聚合
公开(公告)号：US20150018446A1
公开(公告)日：2015-01-15
申请号：US14331323
申请日：2014-07-15
申请人： California Istitute of Technology
发明人： Garret M. Miyake
IPC分类号： C08F2/48
CPC分类号： C08F2/48 , C08F2/50 , C08F112/08 , C08F118/08 , C08F120/14 , C08F120/52 , C08F2438/01
摘要： The present invention is directed to method of forming a polymer comprising exposing a mixture comprising an organic pre-polymer, an organic photoredox catalyst, and an organic initiator to a source of visible or near-infrared light under conditions and for a time sufficient to polymerize the organic pre-polymer, and polymers and articles derived therefrom.
摘要翻译：本发明涉及形成聚合物的方法，其包括将包含有机预聚物，有机光氧化催化剂和有机引发剂的混合物暴露于可见光或近红外光的光源下，在足以聚合的条件下有机预聚物，以及由其衍生的聚合物和制品。

8. 发明授权

US08933143B2 On-demand photoinitiated polymerization 有权
标题翻译：按需光引发聚合
公开(公告)号：US08933143B2
公开(公告)日：2015-01-13
申请号：US14071947
申请日：2013-11-05
申请人： California Institute of Technology
发明人： Andrew J. Boydston , Robert H. Grubbs , Chris Daeffler , Nebojsa Momcilovic
IPC分类号： C08F2/10 , C08F2/46 , C08F2/50 , B29C71/04 , A61L2/08 , A61L24/00 , C08G61/04 , A61K9/00 , C08J3/24 , C08J3/28 , G02B1/04 , G02C7/02 , C08F22/14 , C08F120/14 , C08G77/38 , A61F2/14 , A61F2/16
CPC分类号： A61K9/0051 , A61F2/14 , A61F2/1624 , A61F2/1627 , C08F22/14 , C08F120/14 , C08G77/38 , C08J3/24 , C08J3/28 , C08J2333/00 , G02B1/043 , G02C7/022 , C08L83/04 , C08L33/08 , C08L33/10
摘要： Compositions and methods for adjustable lenses are provided. In some embodiments, the lenses contain a lens matrix material, a masking compound, and a prepolymer. The lens matrix material provides structure to the lens. The masking compound is capable of blocking polymerization or crosslinking of the prepolymer, until photoisomerization of the compound is triggered, and the compound is converted from a first isomer to a second isomer having a different absorption profile. The prepolymer is a composition that can undergo a polymerization or crosslinking reaction upon photoinitiation to alter one or more of the properties of the lenses.
摘要翻译：提供可调透镜的组成和方法。在一些实施方案中，透镜含有透镜基质材料，掩蔽化合物和预聚物。透镜基体材料为透镜提供结构。掩蔽化合物能够阻断预聚物的聚合或交联，直到触发化合物的光异构化，并且化合物从第一异构体转变为具有不同吸收曲线的第二异构体。预聚物是一种组合物，其可以在光引发时经历聚合或交联反应以改变透镜的一种或多种性质。

9. 发明授权

US08779068B2 Aziridinyl-containing compounds 有权
标题翻译：含氮丙啶基的化合物
公开(公告)号：US08779068B2
公开(公告)日：2014-07-15
申请号：US13703230
申请日：2011-06-20
申请人： Jason D. Clapper , Kevin M. Lewandowski
发明人： Jason D. Clapper , Kevin M. Lewandowski
IPC分类号： C08F8/30 , C08F26/06 , C08F20/02 , C08F20/62
CPC分类号： C08G63/91 , C08F8/30 , C08F112/08 , C08F212/08 , C08F293/005 , C08F2438/02 , C08F2800/20 , C08F2810/40 , C08F120/18 , C08F120/14 , C08F220/18 , C08F226/06 , C08F2/38 , C08F2220/1875 , C08F2220/185
摘要： Compounds are described that have both an aziridinyl group as well as a polymeric group. Methods of making these compounds are also described. The aziridinyl group of the compound can be reacted with an acidic group on a second compound resulting in the opening of the aziridinyl ring and the attachment of the polymeric group to the second compound.
摘要翻译：描述了具有吖丙啶基以及聚合基团的化合物。还描述了制备这些化合物的方法。化合物的氮丙啶基可以与第二化合物上的酸性基团反应，导致氮丙啶基环的开放和聚合基团与第二化合物的连接。

10. 发明申请

US20140128494A1 ON-DEMAND PHOTOINITIATED POLYMERIZATION 有权
标题翻译： ON-DEMAND光化聚合
公开(公告)号：US20140128494A1
公开(公告)日：2014-05-08
申请号：US14071947
申请日：2013-11-05
申请人： CALIFORNIA INSTITUTE OF TECHNOLOGY
发明人： ANDREW J. BOYDSTON , ROBERT H. GRUBBS , CHRIS DAEFFLER , NEBOJSA MOMCILOVIC
IPC分类号： A61K9/00 , C08F120/14 , C08G77/38 , C08F22/14
CPC分类号： A61K9/0051 , A61F2/14 , A61F2/1624 , A61F2/1627 , C08F22/14 , C08F120/14 , C08G77/38 , C08J3/24 , C08J3/28 , C08J2333/00 , G02B1/043 , G02C7/022 , C08L83/04 , C08L33/08 , C08L33/10
摘要： Compositions and methods for adjustable lenses are provided. In some embodiments, the lenses contain a lens matrix material, a masking compound, and a prepolymer. The lens matrix material provides structure to the lens. The masking compound is capable of blocking polymerization or crosslinking of the prepolymer, until photoisomerization of the compound is triggered, and the compound is converted from a first isomer to a second isomer having a different absorption profile. The prepolymer is a composition that can undergo a polymerization or crosslinking reaction upon photoinitiation to alter one or more of the properties of the lenses.
摘要翻译：提供可调透镜的组成和方法。在一些实施方案中，透镜含有透镜基质材料，掩蔽化合物和预聚物。透镜基体材料为透镜提供结构。掩蔽化合物能够阻断预聚物的聚合或交联，直到触发化合物的光异构化，并且化合物从第一异构体转变为具有不同吸收曲线的第二异构体。预聚物是一种组合物，其可以在光引发时经历聚合或交联反应以改变透镜的一种或多种性质。

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