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1. 发明申请

WO2017011052A3 VERTICALLY ALIGNED CARBON NANOTUBE ARRAYS AS ELECTRODES 审中-公开
标题翻译：垂直排列的碳纳米管阵列作为电极
公开(公告)号：WO2017011052A3
公开(公告)日：2017-02-23
申请号：PCT/US2016029184
申请日：2016-04-25
申请人： UNIV RICE WILLIAM M
发明人： TOUR JAMES M , RAJI ABDUL-RAHMAN O , SALVATIERRA RODRIGO V
IPC分类号： H01J1/63 , H01J17/49 , H01J63/04
CPC分类号： H01M10/0525 , H01G11/06 , H01G11/28 , H01G11/36 , H01G11/68 , H01G11/86 , H01M4/045 , H01M4/587 , H01M4/625 , H01M4/66 , H01M4/661 , H01M4/663 , Y02E60/13
摘要： Embodiments of the present disclosure pertain to electrodes that include a plurality of vertically aligned carbon nanotubes and a metal associated with the vertically aligned carbon nanotubes. The vertically aligned carbon nanotubes may be in the form of a graphene-carbon nanotube hybrid material that includes a graphene film covalently linked to the vertically aligned carbon nanotubes. The metal may become reversibly associated with the carbon nanotubes in situ during electrode operation and lack any dendrites or mossy aggregates. The metal may be in the form of a non-dendritic or non-mossy coating on surfaces of the vertically aligned carbon nanotubes. The metal may also be infiltrated within bundles of the vertically aligned carbon nanotubes. Additional embodiments pertain to energy storage devices that contain the electrodes of the present disclosure. Further embodiments pertain to methods of forming said electrodes by applying a metal to a plurality of vertically aligned carbon nanotubes.
摘要翻译：本公开的实施例涉及包括多个垂直排列的碳纳米管和与垂直排列的碳纳米管相关联的金属的电极。垂直排列的碳纳米管可以是石墨烯 - 碳纳米管混合材料的形式，其包括与垂直排列的碳纳米管共价连接的石墨烯膜。在电极操作过程中，金属可能与碳纳米管原位可逆地结合，并且缺乏任何树突或苔状聚集体。金属可以在垂直排列的碳纳米管的表面上呈非树枝状或非苔藓状涂层的形式。金属也可以渗入垂直排列的碳纳米管束内。另外的实施例涉及包含本公开的电极的能量存储装置。其他实施例涉及通过将金属施加到多个垂直排列的碳纳米管来形成所述电极的方法。

2. 发明申请

WO2013162660A3 SYNTHESIS OF MAGNETIC CARBON NANORIBBONS AND MAGNETIC FUNCTIONALIZED CARBON NANORIBBONS 审中-公开
标题翻译：磁性纳米颗粒和磁性功能碳纳米管的合成
公开(公告)号：WO2013162660A3
公开(公告)日：2013-12-19
申请号：PCT/US2013023472
申请日：2013-01-28
申请人： UNIV RICE WILLIAM M , MI LLC
发明人： TOUR JAMES M , GENORIO BOSTJAN , LU WEI , PRICE-HOELSCHER BRANDI KATHERINE
IPC分类号： H01F1/34 , C01B31/02
CPC分类号： H01F1/01 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/194 , C09K8/032 , C09K8/32 , C09K8/36 , C09K2208/10 , E21B21/00 , E21B47/12
摘要： Various embodiments of the present disclosure pertain to methods of making magnetic carbon nanoribbons. Such methods generally include: (1) forming carbon nanoribbons by splitting carbon nanomaterials; and (2) associating graphene nanoribbons with magnetic materials, precursors of magnetic materials, or combinations thereof. Further embodiments of the present disclosure also include a step of reducing the precursors of magnetic materials to magnetic materials. In various embodiments, the associating occurs before, during or after the splitting of the carbon nanomaterials. In some embodiments, the methods of the present disclosure further comprise a step of (3) functionalizing the carbon nanoribbons with functionalizing agents. In more specific embodiments, the functionalizing occurs in situ during the splitting of carbon nanomaterials. In further embodiments, the carbon nanoribbons are edge-functionalized. Additional embodiments of the present disclosure pertain to magnetic carbon nanoribbon compositions that were formed in accordance with the methods of the present disclosure.
摘要翻译：本公开的各种实施方案涉及制备磁性碳纳米带的方法。这些方法通常包括：（1）通过分解碳纳米材料形成碳纳米带; 和（2）将石墨烯纳米带与磁性材料，磁性材料的前体或其组合相关联。本公开的另外的实施方案还包括将磁性材料的前体还原成磁性材料的步骤。在各种实施方案中，缔合发生在碳纳米材料分裂之前，期间或之后。在一些实施方案中，本公开的方法还包括（3）用官能化试剂官能化碳纳米带的步骤。在更具体的实施方案中，官能化在碳纳米材料分裂过程中就地发生。在另外的实施方案中，碳纳米带是边缘官能化的。本公开的另外的实施方案涉及根据本公开的方法形成的磁性碳纳米纤维组合物。

3. 发明申请

WO2009070380A3 WATER-SOLUBLE CARBON NANOTUBE COMPOSITIONS FOR DRUG DELIVERY AND MEDICAL APPLICATIONS 审中-公开
标题翻译：水溶性碳纳米管组合物用于药物递送和医疗应用
公开(公告)号：WO2009070380A3
公开(公告)日：2009-10-29
申请号：PCT/US2008078776
申请日：2008-10-03
申请人： UNIV RICE WILLIAM M , TOUR JAMES M , LUCENTE-SCHULTZ REBECCA , LEONARD ASHLEY , KOSYNKIN DMITRY V , PRICE BRANDI KATHERINE , HUDSON JARED L , CONYERS JODIE L , MOORE VALERIE C , CASSCELLS S WARD , MYERS JEFFREY N , MILAS ZVONIMIR L , MASON KATHY A , MILAS LUKA
发明人： TOUR JAMES M , LUCENTE-SCHULTZ REBECCA , LEONARD ASHLEY , KOSYNKIN DMITRY V , PRICE BRANDI KATHERINE , HUDSON JARED L , CONYERS JODIE L , MOORE VALERIE C , CASSCELLS S WARD , MYERS JEFFREY N , MILAS ZVONIMIR L , MASON KATHY A , MILAS LUKA
IPC分类号： A61K9/00
CPC分类号： B82Y5/00 , A61K47/60 , A61K47/6925 , A61K47/6929
摘要： Compositions comprising a plurality of functionalized carbon nanotubes and at least one type of payload molecule are provided herein. The compositions are soluble in water and PBS in some embodiments. In certain embodiments, the payload molecules are insoluble in water. Methods are described for making the compositions and administering the compositions. An extended release formulation for paclitaxel utilizing functionalized carbon nanotubes is also described.
摘要翻译：本文提供了包含多个官能化碳纳米管和至少一种类型的有效负载分子的组合物。在一些实施方案中，组合物可溶于水和PBS。在某些实施例中，有效负载分子不溶于水。描述了制备组合物和施用组合物的方法。还描述了利用官能化碳纳米管的紫杉醇的缓释制剂。

4. 发明申请

WO2008054836A2 SHORT, FUNCTIONALIZED, SOLUBLE CARBON NANOTUBES, METHODS OF MAKING SAME, AND POLYMER COMPOSITES MADE THEREFROM 审中-公开
标题翻译：短功能化，可溶性碳纳米管，其制备方法及其制备的聚合物复合材料
公开(公告)号：WO2008054836A2
公开(公告)日：2008-05-08
申请号：PCT/US2007062570
申请日：2007-02-22
申请人： UNIV RICE WILLIAM M , HWANG WEN-FANG , CHEN ZHEYI , TOUR JAMES M
发明人： HWANG WEN-FANG , CHEN ZHEYI , TOUR JAMES M
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/176 , C01B2202/02 , C01B2202/28
摘要： In some embodiments, the present invention relates to new processes to simultaneously shorten and functionalize raw or purified carbon nanotubes to improve their dispersity and processibility, and the short functionalized nanotubes that may be made by the processes. This present invention also relates to new compositions of matter using short functionalized carbon nanotubes with thermoset, thermoplastic polymers, high temperature polymers, and other materials; the processes for making such composite materials; and the products of said processes.
摘要翻译：在一些实施方案中，本发明涉及同时缩短和官能化原始或纯化的碳纳米管以提高其分散性和可加工性的新方法，以及可通过该方法制备的短官能化纳米管。本发明还涉及使用具有热固性，热塑性聚合物，高温聚合物和其它材料的短官能化碳纳米管的物质的新组合物; 制造这种复合材料的方法; 和所述方法的产品。

5. 发明申请

WO2005114708A3 CARBON NANOTUBE-SILICON COMPOSITE STRUCTURES AND METHODS FOR MAKING SAME 审中-公开
标题翻译：碳纳米管 - 硅复合结构及其制备方法
公开(公告)号：WO2005114708A3
公开(公告)日：2006-07-20
申请号：PCT/US2005016102
申请日：2005-05-06
申请人： UNIV RICE WILLIAM M , TOUR JAMES M , DYKE CHRISTOPHER A , MAYA FRANCISCO , STEWART MICHAEL , CHEN BO , FLATT AUSTEN K
发明人： TOUR JAMES M , DYKE CHRISTOPHER A , MAYA FRANCISCO , STEWART MICHAEL , CHEN BO , FLATT AUSTEN K
IPC分类号： H01L51/30 , C01B31/02 , H01L21/00
CPC分类号： B82Y30/00 , B82Y10/00 , H01L51/0048 , Y10S977/847 , Y10S977/892
摘要： The present invention is directed toward methods of attaching or grafting carbon nanotubes (CNTs) to silicon , wherein such attaching or grafting occurs via functional groups on either or both of the CNTs and silicon surface. The present invention is also directed to the novel compositions produced by such methods. In some embodiments, the present invention is directed to afford the covalent attachment of individualized (unroped) SWNTs to Si surfaces.
摘要翻译：本发明涉及将碳纳米管（CNT）附着或接枝到硅上的方法，其中通过碳纳米管和硅表面中的任一个或两者上的官能团进行这种附着或接枝。本发明还涉及通过这些方法制备的新型组合物。在一些实施方案中，本发明旨在提供个体化（未经处理的）SWNT与Si表面的共价连接。

6. 发明申请

WO2016133571A3 LASER INDUCED GRAPHENE HYBRID MATERIALS FOR ELECTRONIC DEVICES 审中-公开
标题翻译：用于电子设备的激光诱导石墨混合材料
公开(公告)号：WO2016133571A3
公开(公告)日：2016-10-13
申请号：PCT/US2015062832
申请日：2015-11-27
申请人： UNIV RICE WILLIAM M
发明人： TOUR JAMES M , LI LEI , PENG ZHIWEI , ZHANG JIBO
IPC分类号： B32B9/00 , B32B3/00
CPC分类号： H01G11/36 , C01B32/184 , C01B32/194 , C01B32/20 , C01B2204/04 , C01B2204/22 , C01B2204/32 , H01M4/587 , H01M4/625 , Y02E60/13
摘要： In some embodiments, the present disclosure pertains to methods of producing a graphene hybrid material by exposing a graphene precursor material to a laser source to form a laser-induced graphene, where the laser-induced graphene is derived from the graphene precursor material. The methods of the present disclosure also include a step of associating a pseudocapacitive material (e.g., a conducting polymer or a metal oxide) with the laser-induced graphene to form the graphene hybrid material. The formed graphene hybrid material can become embedded with or separated from the graphene precursor material. The graphene hybrid materials can also be utilized as components of an electronic device, such as electrodes in a microsupercapacitor. Additional embodiments of the present disclosure pertain to the aforementioned graphene hybrid materials and electronic devices.
摘要翻译：在一些实施方案中，本公开内容涉及通过将石墨烯前体材料暴露于激光源以形成激光诱导的石墨烯来生产石墨烯混合材料的方法，其中所述激光诱导的石墨烯衍生自所述石墨烯前体材料。本公开的方法还包括将假电容材料（例如，导电聚合物或金属氧化物）与激光诱导的石墨烯缔合以形成石墨烯混合材料的步骤。形成的石墨烯混合材料可以与石墨烯前体材料嵌入或分离。石墨烯混合材料也可以用作电子器件的组件，例如微型电容器中的电极。本公开的另外的实施方案涉及上述石墨烯混合材料和电子装置。

7. 发明申请

WO2015175060A3 LASER INDUCED GRAPHENE MATERIALS AND THEIR USE IN ELECTRONIC DEVICES 审中-公开
标题翻译：激光诱导的石墨材料及其在电子设备中的应用
公开(公告)号：WO2015175060A3
公开(公告)日：2016-02-25
申请号：PCT/US2015016165
申请日：2015-02-17
申请人： UNIV RICE WILLIAM M
发明人： TOUR JAMES M , LIN JIAN , PENG ZHIWEI , KITTRELL CARTER
IPC分类号： C01B31/04
CPC分类号： H01M4/587 , C01B32/184 , C01B2204/04 , C01P2006/40 , C08G73/10 , H01G11/06 , H01G11/36 , H01G11/68 , H01G11/70 , H01M4/366 , H01M4/625 , H01M4/663 , H01M10/0525 , H01M10/054 , Y02E60/13
摘要： In some embodiments, the present disclosure pertains to methods of producing a graphene material by exposing a polymer to a laser source. In some embodiments, the exposing results in formation of a graphene from the polymer. In some embodiments, the methods of the present disclosure also include a step of separating the formed graphene from the polymer to form an isolated graphene. In some embodiments, the methods of the present disclosure also include a step of incorporating the graphene material or the isolated graphene into an electronic device, such as an energy storage device. In some embodiments, the graphene is utilized as at least one of an electrode, current collector or additive in the electronic device. Additional embodiments of the present disclosure pertain to the graphene materials, isolated graphenes, and electronic devices that are formed by the methods of the present disclosure.
摘要翻译：在一些实施方案中，本公开涉及通过将聚合物暴露于激光源来生产石墨烯材料的方法。在一些实施方案中，曝光导致从聚合物形成石墨烯。在一些实施方案中，本公开的方法还包括将形成的石墨烯与聚合物分离以形成分离的石墨烯的步骤。在一些实施例中，本公开的方法还包括将石墨烯材料或分离的石墨烯结合到诸如能量存储装置的电子装置中的步骤。在一些实施例中，石墨烯被用作电子设备中的电极，集电器或添加剂中的至少一个。本公开的另外的实施方案涉及通过本公开的方法形成的石墨烯材料，分离的石墨烯和电子器件。

8. 发明申请

WO2014089214A3 CARBON NANOPARTICLE ADDITIVES FOR WELLBORE FLUID CONDUCTIVITY 审中-公开
标题翻译：碳纳米管添加剂用于井筒流体电导率
公开(公告)号：WO2014089214A3
公开(公告)日：2014-09-04
申请号：PCT/US2013073123
申请日：2013-12-04
申请人： UNIV RICE WILLIAM M , MI LLC
发明人： TOUR JAMES M , CERIOTTI GABRIEL , SLESAREV ALEXANDER , YE RUQUAN , PRICE-HOELSCHER KATHERINE , BOVET CARA , FRIEDHEIM JIM , YOUNG STEVE
IPC分类号： B82Y30/00 , C09K8/34 , E21B7/15
CPC分类号： C09K8/32 , C09K8/03 , C09K2208/10 , E21B47/12 , G01V3/18 , G01V3/24 , Y02A90/342
摘要： Various embodiments of the present disclosure provide methods of making wellbore fluids with enhanced electrical conductivities. In some embodiments, such methods comprise: (1) pre-treating a carbon material with an acid; and (2) adding the carbon material to the wellbore fluid. Further embodiments of the present disclosure pertain to wellbore fluids formed by the methods of the present disclosure. Additional embodiments of the present disclosure pertain to methods for logging a subterranean well by utilizing the aforementioned wellbore fluids.
摘要翻译：本公开的各种实施方案提供了制造具有增强的电导率的井筒流体的方法。在一些实施方案中，这些方法包括：（1）用酸预处理碳材料; 和（2）将碳材料加入到井筒流体中。本公开的另外的实施例涉及通过本公开的方法形成的井眼流体。本公开的另外的实施例涉及通过利用上述井眼流体测井地下井的方法。

9. 发明申请

WO2005030858A3 POLYMERIZATION INITIATED AT THE SIDEWALLS OF CARBON NANOTUBES 审中-公开
标题翻译：碳纳米管的开发聚合
公开(公告)号：WO2005030858A3
公开(公告)日：2005-06-23
申请号：PCT/US2004019769
申请日：2004-06-21
申请人： UNIV RICE WILLIAM M , UNIV HOUSTON , TOUR JAMES M , HUDSON JARED L , KRISHNAMOORTI RAMANAN , YURELKI KORAY , MITCHELL CYNTHIA A
发明人： TOUR JAMES M , HUDSON JARED L , KRISHNAMOORTI RAMANAN , YURELKI KORAY , MITCHELL CYNTHIA A
IPC分类号： C01B31/02 , C08F292/00 , C08K3/04 , C08K7/06 , C08K7/24
CPC分类号： C08F4/484 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C08F2/00 , C08F112/08 , C08F292/00 , C08K3/041 , C08K9/04 , C08L67/04
摘要： The present invention is directed to aryl halide (such as aryl bromide) functionalized carbon nanotubes can be utilized in anionic polymerization processes to form polymer-carbon nanotube materials with improved dispersion ability in polymer matrices. In this process the aryl halide is reacted with an alkyllithium species or is reacted with a metal to replace the aryl-bromine bond with an aryl-lithium or aryl-metal bond, respectively. It has further been discovered that other functionalized carbon nanotubes, after deprotonation with a deprotonation agent, can similarly be utilized in anionic polymerization processes to form polymer-carbon nanotube materials. Additionally or alternatively, a ring opening polymerization process can be performed. The resultant materials can be used by themselves due to their enhanced strength and reinforcement ability when compared to their unbound polymer analogs. Additionally, these materials can also be blended with pre-formed polymers to establish compatibility and enhanced dispersion of nanotubes in otherwise hard to disperse matrices resulting in significantly improved material properties. The resultant polymer-carbon nanotube materials can also be used in drug delivery processes due to their improved dispersion ability and biodegradability, and can also be used for scaffolding to promote cellular growth of tissue.
摘要翻译：本发明涉及芳基卤化物（例如芳基溴化物）官能化碳纳米管可以用于阴离子聚合方法以形成具有改进的聚合物基质分散能力的聚合物 - 碳纳米管材料。在该方法中，芳基卤化物与烷基锂物质反应，或与金属反应，分别用芳基 - 锂或芳基 - 金属键代替芳基 - 溴键。还已经发现，其它官能化碳纳米管在去质子化脱质子化之后，可以类似地用于阴离子聚合方法中以形成聚合物 - 碳纳米管材料。另外或者可选地，可以进行开环聚合方法。所得材料由于与未结合的聚合物类似物相比具有增强的强度和增强能力，可以自己使用。另外，这些材料也可以与预先形成的聚合物混合以建立纳米管在其它难分散的基质中的相容性和增强的分散，导致显着改善的材料性质。所得聚合物 - 碳纳米管材料由于其分散能力和生物降解性的改善而可用于药物递送过程中，并且也可用于支架以促进组织的细胞生长。

10. 发明申请

WO2004068497A3 SELF-ASSEMBLY OF MOLECULES AND NANOTUBES AND/OR NANOWIRES IN NANOCELL COMPUTING DEVICES, AND METHODS FOR PROGRAMMING SAME 审中-公开
标题翻译： NANOCELL计算设备中的分子和纳米体系和/或纳米单体的自组装及其编程方法
公开(公告)号：WO2004068497A3
公开(公告)日：2004-12-29
申请号：PCT/US2004002266
申请日：2004-01-28
申请人： UNIV RICE WILLIAM M , TOUR JAMES M , CHENG LONG , FRANZON PAUL D , NACKASHI DAVID
发明人： TOUR JAMES M , CHENG LONG , FRANZON PAUL D , NACKASHI DAVID
IPC分类号： G11C13/02 , H01L27/28 , H01L51/00 , H01L51/30 , G11C11/00 , G11C27/00 , H01L29/00 , H01L35/40
CPC分类号： G11C13/025 , B82Y10/00 , G11C13/0014 , H01L27/28 , H01L51/0048 , H01L51/005 , H01L51/0052 , H01L51/0595
摘要： An assembly of a NanoCell comprising a disordered array of metallic islands interlinked with molecules between metallic input/output leads and with disordered arrays of molecules and Au islands is disclosed. The NanoCell may function both as a memory device that is programmable post-fabrication. The assembled NanoCells exhibit reproducible switching behavior and at least two types of memory effects at room temperature. The switch-type memory is characteristic of a destructive read while the conductivity-type memory features a nondestructive read. Both types of s memory effects are stable for more than a week at room temperature and bit level ratios (0:1) of the conductivity-type memory have been observed to be as high as 10 :1 and reaching 10 :1 upon ozone treatment which likely destroys extraneous leakage pathways. The invention demonstrates the efficacy of a disordered nano-scale array for high-yielding switching and memory while mitigating the arduous task of nano-scale patterning.
摘要翻译：公开了包含与金属输入/输出引线之间的分子互连并且具有无序的分子阵列和Au岛的金属岛的无序阵列的纳米晶体组件。 NanoCell可以兼作可编程后期制作的存储器件。组装的NanoCells在室温下表现出可重现的切换行为和至少两种记忆效应。开关型存储器是具有破坏性读取的特征，而导电型存储器具有非破坏性读取。两种类型的记忆效应在室温下稳定超过一周，并且观察到导电型存储器的位电平比（0：1）高达10 4：1并达到10 <6 > 1：臭氧处理可能会破坏外部泄漏通道。本发明证明了无序纳米尺度阵列在高产量切换和记忆方面的功效，同时减轻了纳米尺度图案的艰巨任务。

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