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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
21	用于制备巯基封端的液体聚合物的方法	CN201580009412.4	2015-02-23	CN106029745B	2018-04-17	M·门策尔; O·克洛贝斯; V·伯克哈特
本发明涉及用于制备巯基封端的液体聚合物的方法，该方法包括以下步骤：a)使(低聚)甲醛与卤代醇反应以形成包含双(2‑二卤代烷基)缩甲醛的反应混合物，以及b)使步骤a)的反应混合物与(i)多硫化钠或(ii)氢硫化钠和硫的组合反应，其中在选自二醛及其相应的缩醛和半缩醛的支化剂的存在下进行所述方法。
22	一种聚芳硫醚酮的制备方法	CN201710625267.3	2017-07-27	CN107337799A	2017-11-10	刘洪; 范永志; 李玉凤; 陈云
本发明公开一种聚芳硫醚酮的制备方法，包括以下步骤：(1)将N-甲基吡咯烷酮、含水硫化钠、氢氧化钠、复合催化剂投入脱水釜中，脱水，得到脱水物料；(2)将脱水物料转移至聚合釜，将采用N-甲基吡咯烷酮作为溶剂配制的4,4’-二氯二苯甲酮溶液滴加至聚合釜中，预聚合反应1～3小时，得到预聚合物；(3)将预聚合物降温至140～160℃，恒压滴加1,2,4-三氯苯，滴加完毕后，升温至250～290℃，恒温缩聚反应2～6h，得到含有聚芳硫醚酮的固液混合物；(4)将固液混合物经洗涤、干燥后得到聚芳硫醚酮产品。采用预聚合和再聚合的方法，通过扩链聚合，在较低压力下可达到较高的聚合度，制备得到的聚芳硫醚酮树脂分子量更高，能够大大缩短合成周期，节约能耗，有利于工业化放大生产。
23	用于制备巯基封端的液体聚合物的方法	CN201580009412.4	2015-02-23	CN106029745A	2016-10-12	M·门策尔; O·克洛贝斯; V·伯克哈特
本发明涉及用于制备巯基封端的液体聚合物的方法，该方法包括以下步骤：a)使(低聚)甲醛与卤代醇反应以形成包含双(2‑二卤代烷基)缩甲醛的反应混合物，以及b)使步骤a)的反应混合物与(i)多硫化钠或(ii)氢硫化钠和硫的组合反应，其中在选自二醛及其相应的缩醛和半缩醛的支化剂的存在下进行所述方法。
24	端位改性的双官能含硫聚合物、其组合物和使用方法	CN201280020603.7	2012-03-16	CN103534295B	2016-08-24	S·J·霍布斯; G·J·麦克拉姆; L·G·安德森; R·林
公开了端位改性双官能含硫聚合物，其为含硫二醇、醛或酮和含有官能团的化合物的反应产物。公开了组合物，其包含可用于密封剂的端位改性双官能含硫聚合物。
25	一种复合溶剂法制备高分子量聚芳硫醚酮的方法	CN201410588634.3	2014-10-28	CN104371104A	2015-02-25	杨杰; 李志敏; 张刚; 李艳; 龙盛如; 王孝军
本发明公开了一种复合溶剂法制备高分子量聚芳硫醚酮的方法，其特点是将含水硫化钠6.5-14.2份，催化剂0.3-5.2份，脱水剂2.1-7.8份，加入到装有80份的复合有机溶剂的三口烧瓶中，升温通氮气，在温度180-240℃下脱水，降温至80-120℃，将4,4’-二氟二苯甲酮10.7-23.5份加入到反应瓶中，常压下补加溶剂、分段升温聚合，于温度130-210℃反应1-5h，向反应体系中补加10-90份有机高沸点溶剂以提高复合溶剂的共沸点，最后于温度200-260℃反应2-6h完成反应；将上述聚合物冷却至常温得到松软固体混合物，将该混合物用丙酮抽提10-72h以除去部分有机溶剂，再经热水洗涤三次，在温度80-150℃干燥6-20h，得到纯化聚芳硫醚酮树脂。
26	离子导电无规共聚物	CN200480040156.7	2004-11-12	CN100558793C	2009-11-11	S·曹; K·H·南
本发明涉及可用于形成燃料电池用聚合物电解质膜的离子导电无规共聚物。
27	聚亚芳基硫醚树脂组合物及其制造方法	CN200580044045.8	2005-12-15	CN101084274A	2007-12-05	近藤秀水; 铃木孝一; 佐藤浩幸
本发明提供一种聚亚芳基硫醚树脂组合物及其制造方法。本发明的聚亚芳基硫醚树脂组合物，是相对于实质上为线状的直链型聚亚芳基硫醚树脂100重量份，含有在温度330℃、剪切速度2秒－1下测定的熔融粘度为11.0×104－27.0×104Pa·s、平均粒径为50－2000μm、且在温度310℃、角速度1弧度/秒下测定的熔融粘弹性tanδ为0.10－0.30的支链型聚亚芳基硫醚树脂1－50重量份、及无机填充剂1－400重量份的聚亚芳基硫醚树脂组合物。
28	水回り部品用樹脂組成物及び流体用配管	JP2015025264	2015-02-12	JP6590181B2	2019-10-16	渡辺創; 古沢高志; 小川智; 高田十志和

29	表面改質材、表面改質用スルホンイミド化合物、及び燃料電池	JP2012042527	2012-02-28	JP5741486B2	2015-07-01	篠原朗大; 長谷川直樹

30	Surface modified material, sulfonimide compound for surface modification, and fuel cell	JP2012042527	2012-02-28	JP2012214020A	2012-11-08	SHINOHARA AKIHIRO; HASEGAWA NAOKI
PROBLEM TO BE SOLVED: To provide a surface modified material modified by sulfonimide compound group whose surface has high oxygen permeation and high proton conductivity, a fuel cell whose catalyst layer uses the surface modified material, and sulfonimide compound for manufacturing the surface modified material.SOLUTION: The surface modified material includes base material and one or more kinds of sulfonimide compound groups bonded onto the surface of the base material via one or more linking groups -A-Y'- (A is a direct bond or organic group, and Y' is a bonding site with the base material) while the sulfonimide compound group has one or more linking groups -A-Y'- and two or more sulfonimide groups in a molecular structure. The fuel cell uses it for a catalyst layer. The sulfonimide compound for surface modified includes one or more reactive end groups -A-Y (A is a direct bond or organic group, and Y is a reactive functional group) and two or more sulfonimide groups.
31	Sulfur-containing organic silicon compound, and a method of manufacturing the same	JP2000360069	2000-11-27	JP4663868B2	2011-04-06	丈章 ▲斎▼木; 亮岩井

32	Sulfide containing polythiol	JP2005508549	2003-12-03	JP4431539B2	2010-03-17	ロバートエー．スミス，; ニーナボジェコバ，
The present invention relates to a sulfur-containing polyureaurethane and a method of preparing said polyureaurethane. The sulfur-containing polyureaurethane is adapted to have a refractive index of at least 1.57,an Abbe number of at least 32 and a density of less than 1.3 g/cm 3 , when at least partially cured.
33	ポリチオエーテルスルフィドを調製するための方法	JP2016530508	2014-07-30	JP2016527361A	2016-09-08	トビス，ジャン; クロベ，オラフ; ゾンネンベルグ，グンター
式HS−R−(Sy−R)t−SH[式中、各Rは、分枝アルカンジイルまたは分枝アレーンジイル基および構造−(CH2)p−O−(CH2)q−O−(CH2)r−を有する基から独立に選択され、ポリマー中のR基の数の0〜20%は分枝アルカンジイルまたは分枝アレーンジイル基であり、ポリマー中のR基の数の80〜100%は構造−(CH2)p−O−(CH2)q−O−(CH2)r−を有し、tは1〜60の範囲内の値を有し、yは1.0〜1.5の範囲内の平均値であり、qは1から8の範囲内の整数であり、pおよびrは1〜10の範囲内の整数である]を有する液体メルカプト末端ポリマーを生成するための方法。得られるポリマーは、変形圧縮力からの解放後にその元の形状を回復する能力が改良され、それらの力の印加中に回復する傾向が改良されている。
34	Sulfide-containing polythiol	JP2009108405	2009-04-27	JP2009167212A	2009-07-30	BOJKOVA NINA; SMITH ROBERT A
PROBLEM TO BE SOLVED: To provide sulfide-containing polythiols and methods for preparation of the same. SOLUTION: The sulfide-containing polythiols can have a variety of uses and applications. The sulfide-containing polythiols can be especially useful in polyurethane compositions for the manufacture of ophthalmic lenses. In non-limited embodiments, the sulfide-containing polythiols can comprise 1,3-dithiolane and 1,3-dithian. The sulfide-containing polythiols comprising 1,3-dithiolane or 1,3-dithian can be obtained by reacting an asymmetric dichloroacetone with a polymercaptan and then reacting the reaction product with a polymercaptoalkylsulfide, a polymercaptan or their mixture. COPYRIGHT: (C)2009,JPO&INPIT
35	Sulfide containing polythiol	JP2005508549	2003-12-03	JP2006512414A	2006-04-13	ロバートエー．スミス，; ニーナボジェコバ，
本発明は、スルフィド含有ポリチオールおよびこれらの調製方法に関する。スルフィド含有ポリチオールは、種々の用途および適用を有し得る。本発明のスルフィド含有ポリチオールは、眼科用レンズの製造のためのポリウレタン組成物において特に有用である。非限定的な実施形態において、本発明のスルフィド含有ポリチオールは、１，３−ジチオランおよび１，３−ジチアンを含有し得る。１，３−ジチオランまたは１，３−ジチアンを含有するスルフィド含有ポリチオールは、非対称ジクロロアセトンとポリメルカプタンとを反応させ、次いで、ポリメルカプトアルキルスルフィド、ポリメルカプタン、またはこれらの混合物と上記の反応生成物を反応させることによって調製され得る。
36	SULFUR-CONTAINING ORGANOSILICON COMPOUND, AND METHOD FOR PRODUCING THE SAME	JP2000360069	2000-11-27	JP2001226383A	2001-08-21	SAIKI TAKEAKI; IWAI AKIRA
PROBLEM TO BE SOLVED: To obtain a new sulfur-containing organosilicon compound useful as a modifier of the processability and rubber properties of an organic rubber composition, and further to provide a method for efficiently producing the compound under a comparatively mild condition. SOLUTION: This sulfur-containing organosilicon compound is represented by the general formula [R1 is a 1-4C alkyl group; R2 is a 1-4C alkyl group; R3 is a 2-15C divalent hydrocarbon group; R4 is a hydrogen atom or a 1-4C alkyl group; (a) is an integer of 1-3; x is an integer of 1-6; m is an integer of >=0; and p is an integer of >=0]. The method for producing the sulfur- containing organosilicon compound is characterized in that an organosilicon compound represented by the general formula R4-CH=CH-CH2-R3-Si(OR1)aR2(3-a) is reacted with sulfur in an amount of 0.5-4 mol sulfur atom based on 1 mol organosilicon compound at a temperature from room temperature to 200 deg.C.
37		JP21775187	1987-08-31	JPH0618878B2	1994-03-16	ROJAA GURANTO GOOGYAN

38	PRODUCTION OF POLYARYLENE SULFIDE KETONE	JP10604691	1991-05-10	JPH04335029A	1992-11-24	KARASAWA HIROO; KIMURA MICHIO; KOBAYASHI KAZUHIKO
PURPOSE:To produce a polyarylene sulfide ketone having a high melt stability and a high heat resistance in a short time at a high yield by reacting a specific dihalogenated aryl ketone with an alkali metal sulfide in the presence of a quinone. CONSTITUTION:1mol of a dihalogenated aryl ketone of the formula (wherein R1, R2, R3, and R4 are each a 1-12C alkyl group, an arom. group, an alicyclic group, or a hydrogen atom; and X is a halogen atom) is reacted with 0.95-1.05-mol (in terms of total sulfur content) of an alkali metal sulfide in the presence of a quinone.
39	High impact poly(urethane urea) polysulfide	JP2008046887	2008-02-27	JP2008195946A	2008-08-28	BOJKOVA NINA; SMITH ROBERT A; HEROLD ROBERT D; RAO CHANDRA; MCDONALD WILLIAM H; NAGPAL VIDHU J; GRAHAM MARVIN J; YU PHILLIP C; SAWANT SURESH; OKOROAFOR MICHAEL O
<P>PROBLEM TO BE SOLVED: To provide a sulfur-containing polyurea-urethane and to provide a method for preparing the polyurea-urethane. <P>SOLUTION: In an embodiment, the sulfur-containing polyurea-urethane is adapted to have a refractive index of at least 1.57, an Abbe number of at least 32 and a density of less than 1.3 g/cm<SP>3</SP>when at least partially cured. The sulfur-containing polyurea-urethane as set forth in claim 1 that is prepared by the reaction of a component (a) and a component (b) as given below is provided wherein the component (a) is a sulfur-containing polyurethane prepolymer; and the component (b) is an amine-containing curing agent. <P>COPYRIGHT: (C)2008,JPO&INPIT
40	Method for producing slurry containing alkali metal sulfide and method for producing polyarylene sulfide by using the same	JP2005194666	2005-07-04	JP2007009128A	2007-01-18	HIGASHIHARA TAKESHI; HORIUCHI SHUNSUKE; ISHIO ATSUSHI
<P>PROBLEM TO BE SOLVED: To provide a simple and economical method for producing slurry containing an alkali metal sulfide having high fluidity and provide a method for efficiently producing a polyarylene sulfide by using the slurry. <P>SOLUTION: The method for producing an alkali metal sulfide having high fluidity is characterized by the addition of (a) an organic polar solvent to an alkali metal sulfide free from water or having low water content. The invention further provides a method for producing a polyarylene sulfide by using the product. <P>COPYRIGHT: (C)2007,JPO&INPIT

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