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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
101	Process for Production of Modified Poly-(Methylene Sulphide)	GB3038669	1966-11-07	GB1171453A	1969-11-19
1,171,453. After-treatment of polythiomethylenes. STAUFFER CHEMICAL CO. 7 Nov., 1966 [15 Nov., 1965], No. 30386/69. Divided out of 1,171,452. Heading C3P. Mercapto-terminated polythiomethylene is reacted with an acyl halide, anhydride or a hydrocarbyl halide with elimination of hydrogen halide or organic acid. Termination results from reaction with monofunctional reagents, while coupling to increase molecular weight occurs with difunctional reagents, the use of phthalyl chloride being mentioned. In the examples polythiomethylenes are stabilized by reaction with acetic anhydride in the presence of sodium acetate or benzoyl chloride, chlorobenzene, or p-dibromobenzene in dimethylacetamide and in the presence of pyridine or potassium hydroxide (presumably as hydrogen halide absorbers).
102	Polymers containing gem dithioether and gem diether and/or ether groups and process for the preparation thereof	GB3825466	1966-08-25	GB1086977A	1967-10-11
Polymers having in their backbone consecutively alternate gem dithioether, gem diether and/or ether groups each separated one from another by divalent organic groups are prepared by reacting a mercaptoalcohol and a carbonyl compound in the ratio of mercaptan to carbonyl groups of 2:1 to 1:1 in the presence of a strong non-oxidizing acid having a pka of 2.5 or less and in the substantial absence of added water and separating out the polymeric reaction product formed thereby by removal of the water by-product. The reaction proceeds by first forming a dihydroxy gem dithioether which then reacts with excess carbonyl compound to form a polymer containing alternate gem dithioether/gem diether groups which is then isolated by cautious removal of water and any solvent present or alternatively molecules of dihydroxy gem dithioether compound and/or the hydroxyl containing alternating gem dithioether-gem diether linked polymer may be joined together by forcible removal both of the water of reaction formed in the first step and the water formed by etherification of hydroxyl groups, at elevated temperature and in the presence of a strong non-oxidizing acid. Suitable carbonyl compounds have the formula wherein R and R1 may be hydrogen or hydrocarbon groups containing 1 to 25 carbon atoms and are preferably formaldehyde, acetaldehyde, benzaldehyde, acetone or methyl ethyl ketone. Preferred mercaptoalcohols are mercaptocyclobutanol, 3,6-dimercaptopentamethylene glycol mercaptopropanol, 1,2-dihydroxy 3-mercaptopropane and especially 2-mercaptoethanol. Useful strong acids are sulphuric, hydrochloric, p-toluene chlorosulphonic and trichloroacetic acids. Solvents which may be used are nonane, decane, benzene and toluene. The hydroxyl group containing polymers obtained above may be reacted with polyisocyanates in an NCO/H ratio of 0.75:1 to 3.1 in order to produce polyurethane prepolymers or rubbers. Conventional polyisocyanates may be used.
103		NL6616008	1966-11-14	NL6616008A	1967-05-16
Poly (methylene sulphide) having repeating CH2S units is prepared by reacting hydrogen sulphide and formaldehyde in the presence of a catalytic amount of a water soluble metal salt of trithiocarbonic acid. Poly (methylene sulphide) containing repeating CH2S units, in the form of a free flowing white powder with a m.p. generally above 220 deg.C. The thermal stability may be improved by reacting with agents which either give terminal ethylsulphonyl, acyl, or hydrocarbyl groups, or give polymers in which the CH2S units are interrupted by these groups. The modified polymers are suitable for the prodn. of fibres, extrudates, and mouldings.
104	Thermoset resins and intermediates therefor	GB667364	1964-02-18	GB1027056A	1966-04-20
Glycol formthionals where X is O or S, n is an integer and the unit has an average molecular weight of 77-107 and a sulphur content of 43-65%, are prepared by saturating formalin with H2S at pH 3-9 below 15 DEG C. A preferred mixture contains largely HOCH2SCH2OCH2OH and HOCH2SCH2SCH2OH in approximately 3 : 1 mole ratio. Water-soluble resins may be obtained by heating together substantially equimolar amounts of urea and glycol-formthional at pH 4-6 below 60 DEG C. until traces of solid appear. These polymers contain units apparently fewer than 100, probably fewer than 10 per molecule, on average.ALSO:A thermosetting resin comprises 40-100 weight per cent of a glycol-formthional/urea resin having repeating units where X = O or S, n is an integer, and the unit has an average molecular weight of 77-107 and a sulphur content of 43-65%, and 0-60% complementally of a natural polyacetal of recurring unit and/or an aminoplast resin as filler, and/or an epoxy compound or epoxy resin as stabilizer and/or a polybasic acid anhydride as hardener. The glycol-formthionals are prepared by saturating formalin with H2S at pH 3-9, below 15 DEG C. Water-soluble, A-stage, glycol-formthional/urea resins are obtained by heating substantially equimolar amounts of urea and glycol-formthional at pH 4-6, below 60 DEG C., until traces of solids appear. The pH of the solution may be stabilized by addition of phenolic antioxidants, e.g. 2,6-di-t-butyl-4-methyl-(or -methoxy-) phenol. These polymers apparently contain less than 100, probably less than 10, units as above. Solutions of these resins may be used with or without modifiers to laminate coat or impregnate substrates, and may be thinned with organic solvents, e.g. alcohols, ketones, ethers. They may be mixed with reactive fillers, e.g. starch, cellulose, melamine/formaldehyde, guanidine/formaldehyde, benzoguanidine/formaldehyde, biguanide/formaldehyde, guanylurea/formaldehyde, biuret/formaldehyde or urea/formaldehyde. a -Cellulose is preferred, amounting to up to 55% by weight of the resin/filler mixture, and may be precoated with a melamine/formaldehyde or benzoguanidine/formaldehyde which is cured before the filler and the resin are mixed. Non-reacting fillers also may be added, e.g. carbon black, glass, asbestos, silica, cadmium red, cadmium yellow, TiO2, or phthalocyanine green, and lubricants, e.g. MoS2, polytetrafluorethylene or glycerol monostearate. A water-insoluble B-stage resin still capable of being shaped may be obtained by heating the A-stage resin mixture at pH 3-6, below 60 DEG C., losing volatiles until less than 3 weight per cent of water remains. This resin may then be milled and stabilized by treatment with epoxy compounds or resins, e.g. glycidyl ethers, or low molecular weight condensates thereof with phenols or polyols, which may be applied by spraying, followed by an acetone solution of a volatile organic acid. Hardeners, e.g. maleic, pyromellitic or phthalic anhydride, may similarly be added at this stage. Solid C-stage resins are obtained by heating the B-stage resins at 60-180 DEG C. under pressures up to 15,000 p.s.i. In examples A-stage resins are used to laminate paper and birch veneers. B-stage mixtures are made, using as filler a -cellulose impregnated with a melamine/formaldehyde precondensate, and incorporating minor amounts of glyceryl monostearate and TiO2; these are dried and ground and sprayed with nonylphenol glycidyl ether in hexane, formic acid in acetone, and phthalic anhydride is finally added. Cure is at 140 DEG C. and 3000 p.s.i. A cup and saucer are made from this powder.
105		DES0090135	1964-03-20	DE1212074B	1966-03-10	BAPSERES PIERRE; AUDOUZE BERNARD; SIGNOURET JEAN; OURGAUD JANINE
The invention comprises liquid oligopolythioformaldehydes corresponding to the formula HS(CH2S)nH, in which the mean value of the number n can vary from 2 to 8, which are liquid at ambient temperature and contain more than 69.5% by weight of sulphur. They may be obtained by reacting gaseous hydrogen sulphide with an aqueous solution of formaldehyde, preferably to give a solution having a concentration of formaldehyde between 1% and 50%, at a temperature between 70 DEG and 90 DEG C., preferably as close as possible to 80 DEG C., the hydrogen sulphide being injected into the said solution until it is completely saturated and until the polythioformaldehyde which has formed remains liquid after the solution has been cooled to normal temperature. The preferred polythioformaldehydes have a molecular weight in the range from 170 to 230 and do not contain more than 0.16% by weight of oxygen. In one embodiment water is first saturated with H2S and then the formaldehyde is introduced along with sufficient H2S to maintain the saturation of the solution until the required product is obtained.
106		NL6413162	1964-11-12	NL6413162A	1965-05-13
Polythioformaldehyde/ketone condensation products are prepared by mixing the ketone with a polythioformaldehyde and a catalytic amount of an acid and reacting the mixture of -20 DEG to 100 DEG C. until the polymer is formed. The polythioformaldehyde has the formula HS(CH2S)nH wherein n is preferably 2 to 7 or more, preferably 3 or 4. Suitable ketones are acetone, ethylmethylketone, diethylketone, methylisobutylketone, hexanones, heptanones, octanones, benzophenone, acetophenone, acetonylacetone, acetophenoneacetone, acetylacetone, fluorenone, phenylacetophenones, cyclopentanone, cyclohexanone and methylcyclohexanone. Suitable acid catalysts are hydrochloric, phosphoric or sulphuric acids, alone or in admixture with zinc chloride. If desired the reaction may be carried out in the presence of a solvent such as benzene, ethylbenzene, toluene or xylene from which the product may be separated by distillation or the addition of a non-solvent such as methanol.
107		FR928770	1963-03-21	FR1362500A	1964-06-05	BAPSERES PIERRE; AUDOUZE BERNARD; SIGNOURET JEAN; OURGAUD JANINE
The invention comprises liquid oligopolythioformaldehydes corresponding to the formula HS(CH2S)nH, in which the mean value of the number n can vary from 2 to 8, which are liquid at ambient temperature and contain more than 69.5% by weight of sulphur. They may be obtained by reacting gaseous hydrogen sulphide with an aqueous solution of formaldehyde, preferably to give a solution having a concentration of formaldehyde between 1% and 50%, at a temperature between 70 DEG and 90 DEG C., preferably as close as possible to 80 DEG C., the hydrogen sulphide being injected into the said solution until it is completely saturated and until the polythioformaldehyde which has formed remains liquid after the solution has been cooled to normal temperature. The preferred polythioformaldehydes have a molecular weight in the range from 170 to 230 and do not contain more than 0.16% by weight of oxygen. In one embodiment water is first saturated with H2S and then the formaldehyde is introduced along with sufficient H2S to maintain the saturation of the solution until the required product is obtained.
108	Improvements in or relating to the manufacture of artificial resins	GB2678035	1935-09-27	GB463433A	1937-03-30
A synthetic resin is prepared by condensing urea with formaldehyde in the presence of sulphur, preferably in alkaline solution. Moulding powders may be formed from the resin together with acid accelerators, pigments, plasticizers, and fillers such as wood flour, cellulose or ground wood pulp, and asbestos. In an example, urea is condensed with aqueous formaldehyde solution, with sodium carbonate, in the presence of flowers of sulphur, and then refluxed with an aqueous solution of urea. The resulting solution is filtered and mixed with ground wood pulp, the paste dried in vacuo and ground with sodium bisulphate, pigments, and plasticizers.
109		FR46437D	1935-07-05	FR46437E	1936-06-03	LICHTENBERGER JEAN

110		FR43947D	1933-06-13	FR43947E	1934-09-19

111	PROCESS FOR THE PREPARATION OF A MERCAPTO-TERMINATED LIQUID POLYMER	EP15706018.7	2015-02-23	EP3110875B1	2017-12-27	MENZEL, Manfred; KLOBES, Olaf; BURKHARDT, Volker

112	HIGH IMPACT POLY(URETHANE UREA) POLYSULFIDES	EP11001941.1	2003-12-03	EP2325234B1	2017-03-29	Bojkova, Nina V.; McDonald, William H.; Graham, Marvin J.; Okoroafor, Michael O.; Rao, Chandra Bhushan; Smith, Robert A.; Herold, Robert D.; Nagpal, Vidhu J.; Yu, Phillip C.; Sawant, Suresh
The present invention relates to a sulfur-containing polyureaurethane and a method of preparing said polyureaurethane. The sulfur-containing polyureaurethane is adapted to have a refractive index of at least 1.57, an Abbe number of at least 32 and a density of less than 1.3 g/cm 3 , when at least partially cured.
113	POLYARYLENE SULFIDE RESIN COMPOSITION AND METHOD FOR PRODUCING SAME	EP05819877.1	2005-12-15	EP1849834B1	2012-08-22	KONDO, Hidemi, c/o Polyplastics Co., Ltd.; SUZUKI, Koichi; SATO, Hiroyuki, c/o Research Center, Kureha Corp.
Disclosed is a polyarylene sulfide resin composition containing 1-50 parts by weight of a branched-chain polyarylene sulfide resin, which has a melt viscosity measured at 330˚C and a shear rate of 2 sec-1 of from 11.0 × 104 to 27.0 × 104 Pa·s, an average particle diameter of 50-2000 μm and a melt viscoelasticity tan δ measured at 310˚C and an angular speed of 1 rad/sec of 0.10-0.30, and 1-400 parts by weight of an inorganic filler, per 100 parts by weight of a substantially linear straight-chain polyarylene sulfide resin. Also disclosed is a method for producing such a polyarylene sulfide resin composition.
114	High impact poly(urethane urea) polysulfides	EP11001940.3	2003-12-03	EP2325233A3	2011-06-15	Bojkova, Nina V.; McDonald, William H.; Graham, Marvin J.; Okoroafor, Michael O.; Rao, Chandra Bhushan; Smith, Robert A.; Herold, Robert D.; Nagpal, Vidhu J.; Yu, Phillip C.; Sawant, Suresh
The present invention relates to a sulfur-containing polyureaurethane and a method of preparing said polyureaurethane. The sulfur-containing polyureaurethane is adapted to have a refractive index of at least 1.57,an Abbe number of at least 32 and a density of less than 1.3 g/cm³, when at least partially cured.
115	Polymer compositions including a poly(ether sulfone) blend and articles made therefrom	US15780194	2016-11-25	US11225574B2	2022-01-18	Maryam Momtaz
Described herein are polymer compositions having a poly(ether sulfone) polymer and (i) a polysulfone polymer or (ii) a poly(phenyl sulfone) polymer. In some embodiments, the polymer compositions can optionally include one or more additives. It has been surprisingly found that the aforementioned polymer compositions have outstanding anti-stick properties with respect to proteins.
116	Poly(thioethers) for metal ion sequestration	US16094844	2017-04-24	US10669378B2	2020-06-02	Agostino Pietrangelo; Anshuman Mangalum
The invention provides a polymer comprising two or more residues of formula III or IV or salts thereof: wherein dash line, X, Y, Q, L, M, n, R1, R2, Ra, Rb, Rc and Rd have any of the values defined in the specification, as well as synthetic intermediates and synthetic methods useful for preparing the compounds. The polymer is useful to treat contaminated water by chelating metal.
117	MULTIFUNCTIONAL SULFUR-CONTAINING POLYMERS, COMPOSITIONS THEREOF AND METHODS OF USE	US14794855	2015-07-09	US20150344631A1	2015-12-03	STEVEN J. HOBBS; GREGORY J. MCCOLLUM; JUEXIAO CAI; MARFI ITO; LAWRENCE G. ANDERSON; RENHE LIN
Disclosed are multifunctional sulfur-containing polymers that are the reaction products of a sulfur-containing diol, a polyol containing at least three hydroxyl groups per polyol molecule, and an aldehyde, a ketone, or a combination thereof. Sealant compositions comprising the multifunctional sulfur-containing polymers are also disclosed.
118	POLYMER, ORGANIC THIN-FILM SOLAR CELL USING THE SAME, AND ELECTRONIC PRODUCT COMPRISING THE CELL	US14701263	2015-04-30	US20150236288A1	2015-08-20	Yoshihiko Nakano; Takeshi Gotanda; Rumiko Hayase; Yuki Kudo
[Object] To provide a polymer excellent enough in photoelectric conversion efficiency and in light resistance to be suitable for solar cells, also to provide a solar cell using the polymer, and further to provide an electronic product comprising the cell.[Means] Embodiments of the present disclosure provide a polymer comprising a repeating unit of the following formula (M1). (In the formula, R1 is a substituent group selected from the group consisting of alkyl groups, and alkoxy groups; each R2 is independently a substituent group selected from the group consisting of hydrogen, halogen, alkyl groups, alkoxy groups, and aryl groups; and each X is independently an atom selected from the group consisting of O, S and Se. The embodiments also provide a solar cell having an active layer containing the above polymer and further an electronic product comprising that cell.
119	Multifunctional sulfur-containing polymers, compositions thereof and methods of use	US14656743	2015-03-13	US09109089B2	2015-08-18	Steven J. Hobbs; Gregory J. McCollum; Juexiao Cai; Marfi Ito; Lawrence G. Anderson; Renhe Lin
Disclosed are multifunctional sulfur-containing polymers that are the reaction products of a sulfur-containing diol, a polyol containing at least three hydroxyl groups per polyol molecule, and an aldehyde, a ketone, or a combination thereof. Sealant compositions comprising the multifunctional sulfur-containing polymers are also disclosed.
120	Multifunctional sulfur-containing polymers, compositions thereof and methods of use	US14177596	2014-02-11	US08877887B2	2014-11-04	Steven J. Hobbs; Gregory J. McCollum; Juexiao Cai; Marfi Ito; Lawrence G. Anderson; Renhe Lin
Disclosed are multifunctional sulfur-containing polymers that are the reaction products of a sulfur-containing diol, a polyol containing at least three hydroxyl groups per polyol molecule, and an aldehyde, a ketone, or a combination thereof. Sealant compositions comprising the multifunctional sulfur-containing polymers are also disclosed.

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