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11. 发明申请

US20140050995A1 METAL-FREE OXYGEN REDUCTION ELECTROCATALYSTS 审中-公开
标题翻译：无金属氧化还原电解质
公开(公告)号：US20140050995A1
公开(公告)日：2014-02-20
申请号：US14002590
申请日：2012-03-01
申请人： Liming Dai
发明人： Liming Dai
IPC分类号： H01M4/90
CPC分类号： H01M4/9008 , H01M4/8605 , H01M4/8652 , H01M4/90 , H01M8/1007
摘要： An electrocatalyst material comprising a functionalized catalytic substrate, the catalytic substrate comprising an electron-accepting material adsorbed thereto. In one embodiment, the catalytic substrate comprises carbon nanotubes or graphene sheets having a nitrogen-containing or nitrogen-free polyelectrolyte, e.g., poly(diallyldimethylammonium chloride) (PDDA), adsorbed thereto. The electrocatalyst material exhibits excellent catalytic activity, as well as broad fuel selectivity, resistance to poisoning effects, and durability. The electrocatalyst can be used as part of an electrode structure, e.g., a cathode, that can be used in a wide range of electrochemical devices.
摘要翻译：一种电催化剂材料，其包含官能化的催化底物，所述催化底物包含吸附于其上的电子接受材料。在一个实施方案中，催化底物包含具有吸附于其上的含氮或无氮聚电解质（例如聚（二烯丙基二甲基氯化铵）（PDDA））的碳纳米管或石墨烯片。电催化剂材料表现出优异的催化活性，以及广泛的燃料选择性，耐中毒效果和耐久性。电催化剂可以用作电极结构的一部分，例如阴极，其可用于宽范围的电化学装置。

12. 发明申请

US20100183950A1 METAL-FREE VERTICALLY-ALIGNED NITROGEN-DOPED CARBON NANOTUBE CATALYST FOR FUEL CELL CATHODES 有权
标题翻译：用于燃料电池阴极的无金属垂直对准的氮化碳纳米管催化剂
公开(公告)号：US20100183950A1
公开(公告)日：2010-07-22
申请号：US12642059
申请日：2009-12-18
申请人： Liming Dai
发明人： Liming Dai
IPC分类号： H01M8/02 , H01M4/02 , C23F1/00
CPC分类号： H01B1/24 , H01M4/8605 , H01M4/8668 , H01M4/96 , H01M8/1007
摘要： Metal-free fuel cell cathodes having a catalytic layer of vertically-aligned, nitrogen-doped carbon nanotubes (VA-NCNTs) are provided. The fuel cell cathodes comprise a cathode body, a binder layer attached to an outer surface of the cathode body, and the catalytic layer, which is supported by the binder layer. The binder layer may comprise a composite of a conductive polymer and doped or undoped nonaligned carbon nanotubes. In a method for forming the fuel cell cathodes, the VA-NCNTs may be formed by pyrolysis of a metalorganic compound and integration of the nanotubes with nitrogen. The binder layer is applied, and the resulting supported nanotube array may be attached to the cathode body. Fuel cells comprising the fuel cell cathodes are provided. The fuel cell cathodes comprising VA-NCNTs demonstrate superior oxygen-reduction reaction performance, including for electrocatalytic activity, operational stability, tolerance to crossover effects, and resistance to CO poisoning.
摘要翻译：提供了具有垂直排列的氮掺杂碳纳米管（VA-NCNT）的催化层的无金属燃料电池阴极。燃料电池阴极包括阴极体，附着到阴极体的外表面的粘合剂层和由粘合剂层支撑的催化剂层。粘合剂层可以包括导电聚合物和掺杂或未掺杂的非对准碳纳米管的复合材料。在形成燃料电池阴极的方法中，可以通过金属有机化合物的热分解和纳米管与氮的整合来形成VA-NCNT。施加粘合剂层，并且所得的负载型纳米管阵列可以附着到阴极体。提供了包括燃料电池阴极的燃料电池。包括VA-NCNT的燃料电池阴极表现出优异的氧还原反应性能，包括电催化活性，操作稳定性，对交叉效应的耐受性和对CO中毒的抗性。

13. 发明申请

US20090010822A1 APPARATUS FOR THE PRODUCTION OF CARBON NANOTUBES 失效
标题翻译：用于生产碳纳米管的装置
公开(公告)号：US20090010822A1
公开(公告)日：2009-01-08
申请号：US11487510
申请日：2006-07-17
申请人： Liming Dai , Shaoming Huang , Oddvar Johansen , Albert Mau , Ernst Hammel , Xinhe Tang
发明人： Liming Dai , Shaoming Huang , Oddvar Johansen , Albert Mau , Ernst Hammel , Xinhe Tang
IPC分类号： B01J19/00
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B2202/08 , C01B2202/34 , C23C16/0281 , C23C16/26 , C23C16/46 , C30B25/02 , C30B29/02 , C30B29/605 , D01F9/127 , D01F9/133 , Y10T428/30
摘要： A reactor for preparing carbon nanotubes comprising a reaction chamber, at least one support means located within said reaction chamber capable of supporting a substrate, said substrate being capable of supporting carbon nanotube growth, at least one heating element located within said reaction chamber capable of providing localized heating to said substrate within said reaction chamber, and means for passing a gaseous carbonaceous material into said reaction chamber such that is passes over the contacts said substrate.
摘要翻译：一种用于制备碳纳米管的反应器，包括反应室，位于所述反应室内的能够支撑基底的至少一个支撑装置，所述基底能够支撑碳纳米管生长，位于所述反应室内的至少一个加热元件能够提供对所述反应室内的所述衬底进行局部加热，以及用于使气态含碳材料通入所述反应室的装置，以便通过所述衬底上的触点。

14. 发明申请

US20060057362A1 Coatings containing nanotubes, methods of applying the same and transparencies incorporating the same 审中-公开
标题翻译：含有纳米管的涂料，其使用方法和包含纳米管的透明胶片
公开(公告)号：US20060057362A1
公开(公告)日：2006-03-16
申请号：US11087525
申请日：2005-03-23
申请人： Renhe Lin , Liming Dai , Wei Chen
发明人： Renhe Lin , Liming Dai , Wei Chen
IPC分类号： B32B5/16 , B32B27/40 , B32B27/30
CPC分类号： C08J3/215 , B64C1/1476 , B82Y10/00 , B82Y30/00 , C08G18/38 , C08K3/041 , C08K2201/011 , C09D5/24 , C09D133/08 , C09D175/04 , C09D179/02 , C09D183/04 , H01B1/128 , H01B1/24 , Y10T428/25 , Y10T428/31551 , Y10T428/31663 , Y10T428/31935 , C08L2666/20
摘要： A coating on a transparency is provided. In an exemplary embodiment the coating is conductive and transparent. Furthermore, a method for forming a transparency with such a coating is provided.
摘要翻译：提供透明度上的涂层。在示例性实施方案中，涂层是导电的和透明的。此外，提供了用这种涂层形成透明体的方法。

15. 发明授权

US06808746B1 Multilayer carbon nanotube films and method of making the same 失效
标题翻译：多层碳纳米管薄膜及其制造方法
公开(公告)号：US06808746B1
公开(公告)日：2004-10-26
申请号：US09958906
申请日：2002-01-11
申请人： Liming Dai , Shaoming Huang
发明人： Liming Dai , Shaoming Huang
IPC分类号： D01F9127
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/08 , D01F9/127 , Y10S427/102 , Y10S977/778 , Y10S977/842 , Y10S977/896
摘要： This invention relates to a process for the preparation of a substrate-free aligned nanotube film, comprising: (a) synthesizing a layer of aligned carbon nanotubes on a quartz glass substrate by pyrolysis of a carbon-containing material, in the presence of a suitable catalyst for nanotube formation; and (b) etching the quartz glass substrate at the nanotube/substrate interface to release the layer of aligned nanotubes from the substrate. The invention also provides a process for the preparation of a multilayer carbon nanotube film comprising depositing a substrate-free carbon nanotube film onto another nanotube film. Further, the invention provides a process for the preparation of a “hetero-structured” multilayer carbon nanotube film which includes one or more carbon nanotube layers together with layers of other materials, such as metal, semiconductor and polymer.
摘要翻译：本发明涉及一种制备无底物取向纳米管薄膜的方法，包括：（a）在合适的条件下，通过热解含碳材料，在石英玻璃基板上合成排列的碳纳米管层纳米管形成催化剂; 和（b）在纳米管/衬底界面处蚀刻石英玻璃衬底以从衬底释放取向的纳米管层。本发明还提供了一种制备多层碳纳米管膜的方法，包括将无底物的碳纳米管膜沉积到另一纳米管膜上。此外，本发明提供了制备“异质结构”的多层碳纳米管膜的方法，其包括一个或多个碳纳米管层以及诸如金属，半导体和聚合物的其它材料层。

16. 发明授权

US08221937B2 Metal-free vertically-aligned nitrogen-doped carbon nanotube catalyst for fuel cell cathodes 有权
标题翻译：用于燃料电池阴极的无金属垂直排列的氮掺杂碳纳米管催化剂
公开(公告)号：US08221937B2
公开(公告)日：2012-07-17
申请号：US12642059
申请日：2009-12-18
申请人： Liming Dai
发明人： Liming Dai
IPC分类号： H01M4/90 , H01M8/00
CPC分类号： H01B1/24 , H01M4/8605 , H01M4/8668 , H01M4/96 , H01M8/1007
摘要： Metal-free fuel cell cathodes having a catalytic layer of vertically-aligned, nitrogen-doped carbon nanotubes (VA-NCNTs) are provided. The fuel cell cathodes comprise a cathode body, a binder layer attached to an outer surface of the cathode body, and the catalytic layer, which is supported by the binder layer. The binder layer may comprise a composite of a conductive polymer and doped or undoped nonaligned carbon nanotubes. In a method for forming the fuel cell cathodes, the VA-NCNTs may be formed by pyrolysis of a metalorganic compound and integration of the nanotubes with nitrogen. The binder layer is applied, and the resulting supported nanotube array may be attached to the cathode body. Fuel cells comprising the fuel cell cathodes are provided. The fuel cell cathodes comprising VA-NCNTs demonstrate superior oxygen-reduction reaction performance, including for electrocatalytic activity, operational stability, tolerance to crossover effects, and resistance to CO poisoning.
摘要翻译：提供了具有垂直排列的氮掺杂碳纳米管（VA-NCNT）的催化层的无金属燃料电池阴极。燃料电池阴极包括阴极体，附着到阴极体的外表面的粘合剂层和由粘合剂层支撑的催化剂层。粘合剂层可以包括导电聚合物和掺杂或未掺杂的非对准碳纳米管的复合材料。在形成燃料电池阴极的方法中，可以通过金属有机化合物的热分解和纳米管与氮的整合来形成VA-NCNT。施加粘合剂层，并且所得的负载型纳米管阵列可以附着到阴极体。提供了包括燃料电池阴极的燃料电池。包括VA-NCNT的燃料电池阴极表现出优异的氧还原反应性能，包括电催化活性，操作稳定性，对交叉效应的耐受性和对CO中毒的抗性。

17. 发明授权

US08183164B2 Method for preferential growth of semiconducting vertically aligned single walled carbon nanotubes 失效
标题翻译：半导体垂直排列的单壁碳纳米管的优先生长方法
公开(公告)号：US08183164B2
公开(公告)日：2012-05-22
申请号：US12511517
申请日：2009-07-29
申请人： Liangti Qu , Liming Dai
发明人： Liangti Qu , Liming Dai
IPC分类号： H01L21/00
CPC分类号： H01L51/0558 , B82Y10/00 , H01L29/0665 , H01L51/0048
摘要： A method and system for the preferential growth of semiconducting vertically-aligned single-walled carbon nanotubes (VA-SWNTs) is provided. The method combines the use of plasma-enhanced chemical vapor deposition at low pressure with rapid heating. The method provides a high yield of up to approximately 96% semiconducting SWNTs in the VA-SWNT array. The as-synthesized semiconducting SWNTs can be used directly for fabricating field effect transistor (FET) devices without the need for any post-synthesis purification or separation.
摘要翻译：提供了半导体垂直排列的单壁碳纳米管（VA-SWNT）优先生长的方法和系统。该方法结合了在低压下使用等离子体增强化学气相沉积和快速加热。该方法在VA-SWNT阵列中提供高达约96％的半导体SWNT的高产率。合成后的半导体SWNT可以直接用于制造场效应晶体管（FET）器件，而不需要任何后合成的纯化或分离。

18. 发明授权

US08133465B2 Polymer-carbon nanotube composite for use as a sensor 有权
标题翻译：用作传感器的聚合物 - 碳纳米管复合物
公开(公告)号：US08133465B2
公开(公告)日：2012-03-13
申请号：US11518832
申请日：2006-09-11
申请人： Liming Dai , Wei Chen
发明人： Liming Dai , Wei Chen
IPC分类号： H01L21/00
CPC分类号： G01N27/127 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/06 , C01B2202/08 , C01B2202/34 , C01B2202/36 , C08K3/04 , C08K7/24 , C08K2201/011 , Y10S977/707 , Y10S977/742 , Y10S977/783 , Y10S977/842 , Y10S977/932 , Y10S977/953 , Y10T428/2964 , C08L9/00
摘要： A polymer-carbon nanotube composite film is provided for use as a sensor for detecting chemical vapors. The composite film is formed by coating perpendicularly-aligned carbon nanotubes with a polymer selected from poly(vinyl acetate), poly(isoprene), or blends thereof. The sensor may be formed by attaching at least two electrodes to the polymer-carbon nanotube composite film. The sensor may be used in any applications where the sensor is capable of detecting a change in conductivity in the composite.
摘要翻译：提供聚合物 - 碳纳米管复合膜用作检测化学蒸气的传感器。通过用选自聚（乙酸乙烯酯），聚（异戊二烯）或其共混物的聚合物涂覆垂直排列的碳纳米管来形成复合膜。传感器可以通过将至少两个电极附接到聚合物 - 碳纳米管复合膜而形成。传感器可用于传感器能够检测复合材料中导电率变化的任何应用。

19. 发明申请

US20120037306A1 POLYMER-CARBON NANOTUBE COMPOSITE FOR USE AS A SENSOR 有权
标题翻译：聚合碳纳米复合材料作为传感器使用
公开(公告)号：US20120037306A1
公开(公告)日：2012-02-16
申请号：US11518832
申请日：2006-09-11
申请人： Liming Dai , Wei Chen
发明人： Liming Dai , Wei Chen
IPC分类号： B32B38/10 , B32B9/00 , B32B37/14 , G01N7/00 , B82Y40/00 , B82Y30/00 , B82Y99/00
CPC分类号： G01N27/127 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/06 , C01B2202/08 , C01B2202/34 , C01B2202/36 , C08K3/04 , C08K7/24 , C08K2201/011 , Y10S977/707 , Y10S977/742 , Y10S977/783 , Y10S977/842 , Y10S977/932 , Y10S977/953 , Y10T428/2964 , C08L9/00
摘要： A polymer-carbon nanotube composite film is provided for use as a sensor for detecting chemical vapors. The composite film is formed by coating perpendicularly-aligned carbon nanotubes with a polymer selected from poly(vinyl acetate), poly(isoprene), or blends thereof. The sensor may be formed by attaching at least two electrodes to the polymer-carbon nanotube composite film. The sensor may be used in any applications where the sensor is capable of detecting a change in conductivity in the composite.
摘要翻译：提供聚合物 - 碳纳米管复合膜用作检测化学蒸气的传感器。通过用选自聚（乙酸乙烯酯），聚（异戊二烯）或其共混物的聚合物涂覆垂直排列的碳纳米管来形成复合膜。传感器可以通过将至少两个电极附接到聚合物 - 碳纳米管复合膜而形成。传感器可用于传感器能够检测复合材料中导电率变化的任何应用。

20. 发明申请

US20110024717A1 METHOD FOR PREFERENTIAL GROWTH OF SEMICONDUCTING VERTICALLY ALIGNED SINGLE WALLED CARBON NANOTUBES 失效
标题翻译：半导体垂直对准单壁碳纳米管的优选生长方法
公开(公告)号：US20110024717A1
公开(公告)日：2011-02-03
申请号：US12511517
申请日：2009-07-29
申请人： Liangti Qu , Liming Dai
发明人： Liangti Qu , Liming Dai
IPC分类号： H01L29/16 , H01L21/04
CPC分类号： H01L51/0558 , B82Y10/00 , H01L29/0665 , H01L51/0048
摘要： A method and system for the preferential growth of semiconducting vertically-aligned single-walled carbon nanotubes (VA-SWNTs) is provided. The method combines the use of plasma-enhanced chemical vapor deposition at low pressure with rapid heating. The method provides a high yield of up to approximately 96% semiconducting SWNTs in the VA-SWNT array. The as-synthesized semiconducting SWNTs can be used directly for fabricating field effect transistor (FET) devices without the need for any post-synthesis purification or separation.
摘要翻译：提供了半导体垂直排列的单壁碳纳米管（VA-SWNT）优先生长的方法和系统。该方法结合了在低压下使用等离子体增强化学气相沉积和快速加热。该方法在VA-SWNT阵列中提供高达约96％的半导体SWNT的高产率。合成后的半导体SWNT可以直接用于制造场效应晶体管（FET）器件，而不需要任何后合成的纯化或分离。

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